Oxygenated solvents for improved production of oil and gas

Patent metadata

Field	Value
Publication number	US-12031087-B2
Application number	US-202017441223-A
Country	US
Kind code	B2
Filing date	Mar 20, 2020
Priority date	Mar 21, 2019
Publication date	Jul 9, 2024
Grant date	Jul 9, 2024

Abstract

Described herein are techniques, methods, and systems for producing hydrocarbons from a reservoir and, particularly, from subterranean formations. The disclosed techniques employ oxygenated solvents, such as ketones, to improve or enhance oil or hydrocarbon production from subterranean formations. In some cases, ketones can be used in combination with surfactants to improve or enhance oil or hydrocarbon from subterranean formations.

First claim

What is claimed is:

1. A method of producing hydrocarbons from a subterranean formation, the method comprising:
developing a model for the subterranean formation, wherein the model uses ketone aqueous- and oil-phase partitioning characteristics, and wherein the subterranean formation comprises a shale formation or a carbonate formation;
using the model to determine injection characteristics for injecting a fluid comprising one or more ketones and a carrier fluid into the subterranean formation,
wherein the one or more ketones are selected from the group consisting of 3-pentanone, 2-hexanone, 3-hexanone, 2-heptanone, 3-heptanone, 4-heptanone, 2-octanone, 3-octanone, and 4-octanone;

injecting the fluid into the subterranean formation according to the determined injection characteristics;
wherein the one or more ketones in the fluid injected into the subterranean formation modify a wettability of rock in the subterranean formation to a more water-wet condition, and
wherein the one or more ketones in the fluid injected into the subterranean formation partition into an aqueous phase liquid;

using the model to determine production characteristics for producing the hydrocarbons from the subterranean formation; and
producing hydrocarbons from the subterranean formation according to the determined production characteristics.

2. The method of claim 1 , wherein the one or more ketones in the fluid injected into the subterranean formation reduce a viscosity or a density of the hydrocarbons in the subterranean formation.

3. The method of claim 1 , wherein the one or more ketones in the fluid injected into the subterranean formation results in swelling of the hydrocarbons.

4. The method of claim 1 , wherein the one or more ketones in the fluid injected into the subterranean formation reduce an interfacial tension between an aqueous phase liquid in the subterranean formation and an oil phase liquid in the subterranean formation.

5. The method of claim 1 , wherein the fluid further comprises a surfactant.

6. The method of claim 5 , wherein the surfactant comprises at least one of 2-ethylhexanol (EH)-4 propylene oxide (PO)-15 ethylene oxide (EO), 2-EH-4PO-20EO, 2-EH-4PO-25EO, and 2-EH-7PO-20EO.

7. The method of claim 1 , wherein the step of developing the model for the subterranean formation further uses:
ketone physical properties, subterranean formation characteristics, and hydrocarbon physical properties.

8. The method of claim 1 , wherein the carrier fluid is a gas.

9. The method of claim 8 , wherein the gas comprises CO 2 , N 2 , a hydrocarbon gas, or any combination of these.

10. The method of claim 1 , wherein the carrier fluid comprises supercritical CO 2 .

11. The method of claim 1 , wherein the carrier fluid comprises water.

12. The method of claim 1 , wherein a concentration of the one or more ketones in the fluid is less than an aqueous solubility limit of the one or more ketones.

13. The method of claim 1 , wherein the one or more ketones comprises at least a symmetrical linear ketone having at least 4 carbons.

14. A system for producing hydrocarbons from a subterranean formation, the system comprising:
a source of a fluid, wherein the fluid comprises one or more ketones and a carrier fluid,
wherein the one or more ketones are selected from the group consisting of 3-pentanone, 2-hexanone, 3-hexanone, 2-heptanone, 3-heptanone, 4-heptanone, 2-octanone, 3-octanone, and 4-octanone;

an injection system in fluid communication with the source, the injection system further in fluid communication with the subterranean formation;
a hydrocarbon production system in fluid communication with the subterranean formation;
a processor; and
a non-transitory computer-readable storage medium in data communication with the processor, the non-transitory computer-readable storage medium storing processor executable instructions that, when executed by the processor, cause the processor to execute operations of a model for the subterranean formation, wherein the model uses ketone aqueous- and oil-phase partitioning characteristics, wherein the non-transitory computer-readable storage medium storing processor executable instructions that, when executed by the processor, cause the processor to perform operations including:
determining injection characteristics for the injection system;
generating, based on the injection characteristics, a control signal to the injection system, wherein the control signal controls the injection system for injecting the fluid into the subterranean formation based on the determined injection characteristics;
wherein the one or more ketones in the fluid injected into the subterranean formation modify a wettability of rock in the subterranean formation to a more water-wet condition, and
wherein the one or more ketones in the fluid injected into the subterranean formation partition into an aqueous phase liquid;
determining production characteristics for producing the hydrocarbons from the subterranean formation; and
generating, based on the production characteristics, a control signal for the hydrocarbon production system, wherein the control signal controls the hydrocarbon production system, causing the production hydrocarbon system to produce hydrocarbons from the subterranean formation according to the determined production characteristics, wherein the subterranean formation is a shale formation or a carbonate formation.

15. The system of claim 14 , wherein the fluid consists of the one or more ketones and the carrier fluid.

16. The system of claim 14 , wherein the carrier fluid is a gas-phase fluid.

17. The system of claim 14 , wherein the carrier fluid comprises a gas-phase hydrocarbon, methane, ethane, natural gas, carbon dioxide, nitrogen, or any combination of these from any sources.

18. The system of claim 14 , wherein the one or more ketones are present in the fluid in the gas-phase.

19. The system of claim 14 , wherein the fluid comprises a liquid-phase fluid, and wherein the liquid-phase fluid does not comprise or include a surfactant.

20. The system of claim 14 , wherein the one or more ketones are present in the fluid in the liquid-phase.

21. The system of claim 14 , wherein the carrier fluid comprises water.

Assignees

• Univ Texas

Inventors

• Okuno Ryosuke
• Abeykoon Gayan Aruna

Classifications

• E21B43/24

  using heat, e.g. steam injection · CPC title

• E21B43/168

  Injecting a gaseous medium · CPC title

• E21B43/164

  Injecting CO2 or carbonated water (in combination with organic material C09K8/594) · CPC title

• C09K8/594 Primary

  Compositions used in combination with injected gas {, e.g. CO2 orcarbonated gas}(C09K8/592 takes precedence) · CPC title

• C09K8/86

  containing organic compounds · CPC title