Thermoplastic resin composition and molded article thereby

Patent metadata

Field	Value
Publication number	US-12031024-B2
Application number	US-202017764633-A
Country	US
Kind code	B2
Filing date	Dec 18, 2020
Priority date	Jul 23, 2020
Publication date	Jul 9, 2024
Grant date	Jul 9, 2024

Abstract

A thermoplastic resin composition and a molded article including the same can include 100 parts by weight of a base resin including 10 to 50% by weight of an acrylate-aromatic vinyl compound-vinyl cyanide compound graft copolymer (A-1) containing acrylate rubber having an average particle diameter of 0.3 to 0.5 μm, 5 to 40% by weight of an acrylate-aromatic vinyl compound-vinyl cyanide compound graft copolymer (A-2) containing acrylate rubber having an average particle diameter of 0.05 μm or more and less than 0.3 μm, and 20 to 65% by weight of an aromatic vinyl polymer (B), and 0.5 to 12 parts by weight of a polyamide (C). The thermoplastic resin composition can have a solvent resistance of 15 days or more.

First claim

The invention claimed is:

1. A thermoplastic resin composition, comprising:
100 parts by weight of a base resin comprising from 10 to 50% by weight of an acrylate-aromatic vinyl compound-vinyl cyanide compound graft copolymer (A-1) containing a first acrylate rubber having an average particle diameter of from 0.3 to 0.5 μm, from 5 to 40% by weight of an acrylate-aromatic vinyl compound-vinyl cyanide compound graft copolymer (A-2) containing a second acrylate rubber having an average particle diameter of 0.05 μm or more and less than 0.3 μm, and from 20 to 65% by weight of an aromatic vinyl polymer (B); and
from 0.5 to 12 parts by weight of a polyamide (C),
wherein the thermoplastic resin composition has a solvent resistance of 15 days or more, wherein the solvent resistance is measured as time when a crack occurs in a presence of a solvent consisting of 98% by weight of water, 1% by weight of citric acid, and 1% by weight of malic acid.

2. The thermoplastic resin composition according to claim 1 , wherein the acrylate-aromatic vinyl compound-vinyl cyanide compound graft copolymers (A-1) and (A-2) each comprises
from 40 to 60% by weight of the first and second acrylate rubbers, respectively,
from 20 to 40% by weight of an aromatic vinyl compound, and
from 10 to 20% by weight of a vinyl cyanide compound.

3. The thermoplastic resin composition according to claim 1 , wherein the aromatic vinyl polymer (B) comprises one or more selected from the group consisting of an aromatic vinyl compound-vinyl cyanide compound copolymer, a heat-resistant styrene-based resin, and a methacrylate-aromatic vinyl compound-vinyl cyanide compound copolymer.

4. The thermoplastic resin composition according to claim 3 , wherein the aromatic vinyl compound-vinyl cyanide compound copolymer comprises
from 65 to 80% by weight of an aromatic vinyl compound and
from 20 to 35% by weight of a vinyl cyanide compound.

5. The thermoplastic resin composition according to claim 3 , wherein the aromatic vinyl compound-vinyl cyanide compound copolymer comprises one or more selected from the group consisting of an aromatic vinyl compound-vinyl cyanide compound copolymer having a weight average molecular weight of from 100,000 to 150,000 g/mol and an aromatic vinyl compound-vinyl cyanide compound copolymer having a weight average molecular weight of greater than 150,000 g/mol and 200,000 g/mol or less.

6. The thermoplastic resin composition according to claim 3 , wherein the heat-resistant styrene-based resin is an α-methylstyrene-vinyl cyanide compound copolymer.

7. The thermoplastic resin composition according to claim 6 , wherein the heat-resistant styrene-based resin has a weight average molecular weight of from 150,000 to 250,000 g/mol.

8. The thermoplastic resin composition according to claim 3 , wherein the methacrylate-aromatic vinyl compound-vinyl cyanide compound copolymer comprises from 60 to 85% by weight of methacrylate, from 5 to 30% by weight of an aromatic vinyl compound, and from 5 to 30% by weight of a vinyl cyanide compound.

9. The thermoplastic resin composition according to claim 8 , wherein the methacrylate-aromatic vinyl compound-vinyl cyanide compound copolymer has a weight average molecular weight of from 80,000 to 200,000 g/mol.

10. The thermoplastic resin composition according to claim 1 , wherein the polyamide (C) comprises nylon6 and nylon66.

11. The thermoplastic resin composition according to claim 10 , wherein a weight ratio of the nylon6 to the nylon66 (nylon6:nylon66) is 1:1.1 to 10.

12. The thermoplastic resin composition according to claim 1 , wherein the thermoplastic resin composition has a chemical resistance of 15 days or more, and the chemical resistance is measured as time when a crack occurs in a presence of a permethrin-containing emulsion solution in which 0.25 g of permethrin (cis:trans isomer ratio: 25:75) as an insecticidal active ingredient per 100 ml is dissolved.

13. The thermoplastic resin composition according to claim 1 , wherein the thermoplastic resin composition has an injection gloss of 30 or less as measured at 45° using a VG7000 gloss meter.

14. A molded article, comprising the thermoplastic resin composition according to claim 1 .

15. The molded article according to claim 14 , wherein the molded article is an unpainted coated pipe including the thermoplastic resin composition and a steel pipe.

16. A method of manufacturing an unpainted coated pipe, the method comprising:
feeding 100 parts by weight of a base resin comprising from 10 to 50% by weight of an acrylate-aromatic vinyl compound-vinyl cyanide compound graft copolymer (A-1) containing acrylate rubber having an average particle diameter of from 0.3 to 0.5 μm, from 5 to 40% by weight of an acrylate-aromatic vinyl compound-vinyl cyanide compound graft copolymer (A-2) containing acrylate rubber having an average particle diameter of from 0.05 μm or more and less than 0.3 μm, and from 20 to 65% by weight of an aromatic vinyl polymer (B), and from 0.5 to 12 parts by weight of a polyamide (C) into an extruder to prepare pellets; and
coextruding the prepared pellets and a steel pipe to manufacture the unpainted coated pipe,
wherein the unpainted coated pipe has a solvent resistance of 15 days or more, wherein the solvent resistance is measured as time when a crack occurs in a presence of a solvent consisting of 98% by weight of water, 1% by weight of citric acid, and 1% by weight of malic acid.

Assignees

• Lg Chemical Ltd

Inventors

• Park Chun Ho
• Kim Tae Hoon
• Sung Daeun
• An Yong Hee
• Joe Wangrae
• Kim Ho Hoon
• Jang Jeongmin

Classifications

• Y10T428/1393

  Multilayer [continuous layer] · CPC title

• B32B27/08

  of synthetic resin · CPC title

• Y10T428/1386

  Natural or synthetic rubber or rubber-like compound containing · CPC title

• Y10T428/1355

  Elemental metal containing [e.g., substrate, foil, film, coating, etc.] · CPC title

• B32B1/08

  Tubular products · CPC title