Water based dispersion to make coatings with increased MVTR barrier properties

Patent metadata

Field	Value
Publication number	US-12031004-B2
Application number	US-202117343868-A
Country	US
Kind code	B2
Filing date	Jun 10, 2021
Priority date	Dec 14, 2018
Publication date	Jul 9, 2024
Grant date	Jul 9, 2024

Abstract

The present invention relates to an aqueous dispersion, comprising or consisting of A) at least one cyclic olefin copolymer, B) at least one surfactant; optionally C) at least one adhesion promoter; optionally D) at least one film-forming resin; optionally E) at least one additive; and F) water. Additionally, the invention relates to methods of manufacturing the aqueous dispersion, to an article, which comprises at least one substrate and at least one coating layer obtained from the aqueous dispersion and applied onto the substrate; and to methods of improving MVTR of a substrate.

First claim

What is claimed is:

1. An aqueous dispersion, comprising components:
A) at least one cyclic olefin copolymer;
B) at least one surfactant, different from A);
C) at least one adhesion promoter, different from A) and B), present in an amount of 0.5 to 20 wt-%, based on solid content of the aqueous dispersion. and selected from resins comprising hydroxyl groups, carboxylic, phosphonic, phosphoric acid groups and combinations thereof;
D) optionally at least one film forming resin, different from A), B) and C);
E) optionally at least one additive, different from A), B), C) and D); and
F) water.

2. The aqueous dispersion according to claim 1 , wherein Component A) the at least one cyclic olefin copolymer comprises a C5 to C12 cycloalkene copolymerized with at least one C2 to C10 alkylene, the copolymer being present in an amount of 5 to 99 wt .- %, based on solid content of the aqueous dispersion and having an average particle size as a D50 value of 50 to 500 nm measured via dynamic light scattering.

3. The aqueous dispersion according to claim 2 , wherein Component B) the at least one surfactant is an anionic or non-ionic surfactant or a mixture thereof present in an amount of 0.01 to 10 wt .- %, based on the solid content of the aqueous dispersion.

4. The aqueous dispersion according to claim 3 , wherein Component B) the at least one surfactant comprises at least one of an alkyl sulfate, a fatty alcohol alkoxylate, and a copolymer of at least one olefinic monomer and at least one comonomer selected from a α,β-unsaturated carboxylic acids.

5. The aqueous dispersion according to claim 1 , wherein Component C) the at least one adhesion promoter is present in an amount of 1 to 7 wt .- % based on the solid content of the aqueous dispersion, and comprises at least one polyester resin, which has an acid number of 5 to 75 mg KOH/g and a glass transition temperature Tg of from 0 to 35° C.

6. The aqueous dispersion according to claim 1 , wherein Component D) the at least one film forming resin is present in 0.5 to 40 wt .- % based on the solid content of the aqueous dispersion, and comprises one or more of:
i) a homopolymer of an olefinic monomer having not more than 8 carbon atoms;
ii) a copolymer of at least two olefinic monomers having not more than 8 carbon atoms;
iii) copolymers obtained by polymerizing isobutylene with conjugated dienes;
iv) copolymers obtained by polymerizing at least one olefinic monomer having not more than 5 carbon atoms, with at least one co-monomer selected from α,β-unsaturated carboxylic acids, wherein the copolymer has an acid value below 60 mg KOH/g and at least 5 mg KOH/g.

7. The aqueous dispersion according to claim 1 , wherein the optional Component E) the at least one additive has been added to the aqueous dispersion in an amount of 0,0001 to 20 wt .- % based on total weight of the aqueous dispersion, and is selected from a biocide, an organic solvent, a plasticizer, a slip agent, an antiblocking agent, a pH adjusting agent, a dye, a pigment, a natural oil, a synthetic oil, a wax, an organic filler, an inorganic filler and combinations thereof.

8. An aqueous dispersion. comprising components:
A) at least one cyclic olefin copolymer:
B) at least one surfactant, different from A);
C) optionally at least one adhesion promoter, different from A) and B);
D) optionally at least one film forming resin. different from A), B) and C);
E) optionally at least one additive, different from A), B), C) and D); and
F) water;

wherein Component A) the at least one cyclic olefin copolymer is a C5 to C12 cycloalkene copolymerized with at least one of ethylene, propylene, butylene, hexylene and octylene and present in an amount of 50-95 wt .- %, Component B) the at least one surfactant is present in an amount of 2-7 wt .- %, and comprises a mixture of an anionic surfactant and a non-ionic emulsifier; and Component C) the at least one adhesion promoter is present in an amount of 1- 7 wt .- % and comprises at least one polyester resin; all amounts being based on solid content of the aqueous dispersion.

9. A method of manufacturing an aqueous dispersion according to claim 1 comprising steps of:
(i) dissolving A), the at least one cyclic olefin copolymer in solvent, optionally adding one or more of B), C), D), or E), forming a solution;
(ii) providing an aqueous phase and, if B) was not added in step (i), mixing B) the at least one surfactant into the aqueous phase at temperatures between 50 and 100° C.;
(iii) mixing the solution of step (i) and the aqueous phase of (ii), under high shear for 0.1 to 10 minutes; and
(iv) distilling off the solvent.

10. A method of manufacturing an aqueous dispersion according to claim 1 comprising steps of:
(i) feeding an extruder with A) the at least one cyclic olefin copolymer, and optionally with one or more of B), C), D), or E);
(ii) adding water, which is optionally mixed with one or more of B), C), D), or E) that were not added in step (i), into the extruder during the extrusion process; and
(iii) diverting the aqueous dispersion resulting from step (ii) from the extruder.

11. A method of manufacturing an aqueous dispersion according to claim 1 comprising steps:
(i) melting A) the at least one cyclic olefin copolymer and B) the at least one surfactant; optionally with one or more of C), D), or E), forming a mixture;
(ii) transferring the mixture of step (i) to a reaction chamber, optionally under pressure of 10 to 900 bar;
(iii) simultaneously with step (ii), transferring water having a temperature greater than 100° C. , but less than 200° C. , to the reaction chamber, optionally under pressure of 10 to 900 bar;
(iv) delivering the mixture of step (ii) and the water of step (iii) simultaneously into a carrier gas in the reaction chamber, with a jet velocity up to 300 m/s; and
(v) diverting the mixture resulting from step (iv) from the reaction chamber.

12. An article of manufacture comprising at least one substrate and at least one coating layer deposited on the at least one substrate by applying the aqueous dispersion according to claim 1 onto the at least one substrate, optionally via a film coater under vacuum; and then drying the aqueous dispersion, optionally by heating thereby forming the at least one coating layer with adhesion to the at least one substrate and providing the article with a moisture vapor transmission rate (“MVTR”) at 38° C. and 90% RH of 7 to 60 g/(m 2 ·day).

13. The article according to claim 12 , wherein the at least one substrate is polyethylene terephthalate or oriented polypropylene, the at least one coating layer has a thickness of 0.1 to 15 g/m 2 and the article has a moisture vapor transmission rate (“MVTR”) at 38° C. and 90% RH of 12 to 50 g/(m 2 ·day).

14. A method of improving moisture vapor transmission rate (“MVTR”) of a polyethylene terephthalate or polyolefinic substrate, comprising:
a. applying the aqueous dispersion according to claim 1 onto a polyethylene terephthalate or polyolefinic substrate, optionally a flexible film substrate, under vacuum as a homogenous film; and
b. drying the homogenous film on the polyethylene terephthalate or polyolefinic substrate by heating to form a coating layer having a thickness of 5 to 10 g/m 2 and an MVTR of 12 to 50 g/(m 2 ·day) at 38° C. and 90% RH.

Assignees

• Henkel Ag & Co Kgaa

Inventors

• De Zeeuw Ard
• Tomé Jorge Maria
• Krug Robin Leif
• Moeller Thomas
• Stodt Juergen

Classifications

• C09D125/02

  Homopolymers or copolymers of hydrocarbons · CPC title

• C08J2325/02

  Homopolymers or copolymers of hydrocarbons · CPC title

• C08J7/043

  Improving the adhesiveness of the coatings per se, e.g. forming primers (adhesives in the form of films or foils characterised by the primer layers between the polymer carriers and the adhesives C09J7/50) · CPC title

• C08J7/052

  Forming heat-sealable coatings · CPC title

• C08J2467/04

  Polyesters derived from hydroxy carboxylic acids, e.g. lactones (C08J2467/06 takes precedence) · CPC title