Method for recovering valuable metals from waste lithium ion batteries

Patent metadata

Field	Value
Publication number	US-12027681-B2
Application number	US-201917258772-A
Country	US
Kind code	B2
Filing date	Jul 11, 2019
Priority date	Jul 12, 2018
Publication date	Jul 2, 2024
Grant date	Jul 2, 2024

Abstract

Provided is a more efficient dry refining process for improving the recovery rate of phosphorus-free valuable metals from waste lithium ion batteries. The present invention provides a method for recovering valuable metals from waste lithium ion batteries, said method comprises a melting step S4 for melting the waste lithium ion batteries and obtaining a molten substance and a slag separation step S5 for separating slag from the molten substance and recovering an alloy containing valuable metals, wherein in the melting step, flux containing a calcium compound is added to the waste lithium ion batteries such that the mass ratio between silicon dioxide and calcium oxide in the slag becomes 0.50 or less and the mass ratio between calcium oxide and aluminum oxide falls in the range of 0.30 to 2.00.

First claim

The invention claimed is:

1. A method for recovering valuable metals from a waste lithium ion battery, the method comprising:
a pre-heating step of heating the waste lithium ion battery at a temperature equal to or greater than 700° C. under presence of an oxidant;
a melting step of melting the waste lithium ion battery after being heated so as to obtain a molten material; and
a slag separation step of separating slag from the molten material so as to recover an alloy including the valuable metals,
wherein in the melting step, a reducing agent including a carbon atom is added, a flux containing a calcium compound is used under presence of the reducing agent, the flux is added to the waste lithium ion battery such that a mass ratio of silicon dioxide to calcium oxide in the slag is equal to or less than 0.50 and that a mass ratio of calcium oxide to aluminum oxide is equal to or greater than 0.30 and equal to or less than 2.00 and the melting is performed.

2. The method for recovering valuable metals according to claim 1 , wherein the valuable metals are one or more types selected from the group consisting of cobalt, nickel, and copper.

3. The method for recovering valuable metals according to claim 2 , wherein a heating temperature in the melting step is equal to or greater than 1300° C. and equal to or less than 1500° C.

4. The method for recovering valuable metals according to claim 3 , wherein a phosphorus grade in the alloy recovered in the slag separation step is less than 0.1% by mass.

5. The method for recovering valuable metals according to claim 4 , wherein calcium carbonate is used as the calcium compound.

6. The method for recovering valuable metals according to claim 3 , wherein calcium carbonate is used as the calcium compound.

7. The method for recovering valuable metals according to claim 2 , wherein a phosphorus grade in the alloy recovered in the slag separation step is less than 0.1% by mass.

8. The method for recovering valuable metals according to claim 7 , wherein calcium carbonate is used as the calcium compound.

9. The method for recovering valuable metals according to claim 2 , wherein calcium carbonate is used as the calcium compound.

10. The method for recovering valuable metals according to claim 1 , wherein a heating temperature in the melting step is equal to or greater than 1300° C. and equal to or less than 1500° C.

11. The method for recovering valuable metals according to claim 10 , wherein a phosphorus grade in the alloy recovered in the slag separation step is less than 0.1% by mass.

12. The method for recovering valuable metals according to claim 11 , wherein calcium carbonate is used as the calcium compound.

13. The method for recovering valuable metals according to claim 10 , wherein calcium carbonate is used as the calcium compound.

14. The method for recovering valuable metals according to claim 1 , wherein a phosphorus grade in the alloy recovered in the slag separation step is less than 0.1% by mass.

15. The method for recovering valuable metals according to claim 14 , wherein calcium carbonate is used as the calcium compound.

16. The method for recovering valuable metals according to claim 1 , wherein calcium carbonate is used as the calcium compound.

Assignees

• Sumitomo Metal Mining Co

Inventors

• Yamashita Yu
• Togashi Ryo

Classifications

• B09B3/40

  involving thermal treatment, e.g. evaporation (processes using mineral binders involving a melting or softening step B09B3/29; involving radiation B09B3/50) · CPC title

• B09B3/35

  Shredding, crushing or cutting · CPC title

• B09B3/70

  Chemical treatment, e.g. pH adjustment or oxidation (involving an extraction step B09B3/80) · CPC title

• C22B9/106

  the refining being obtained by intimately mixing the molten metal with a molten salt or slag · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title