Bonded multilayer article

Patent metadata

Field	Value
Publication number	US-12025258-B2
Application number	US-201917414708-A
Country	US
Kind code	B2
Filing date	Dec 18, 2019
Priority date	Dec 19, 2018
Publication date	Jul 2, 2024
Grant date	Jul 2, 2024

Abstract

A bonded multilayer article including: (a) at least one first layer of a silicone-containing rubber substrate material bonded to (b) at least one second layer of a substrate material bondable to the first layer; wherein at least a portion of the surface of the first layer is activated for adhesion to increase the bond strength of the first layer to a second layer such that the bond strength of the first layer bonded to the second layer is increased; and a process for producing the above bonded multilayer article.

First claim

What is claimed is:

1. A bonded multilayer article comprising:
(a) at least one first layer of a silicone-containing rubber substrate material bonded to
(b) at least one second layer of a substrate material bondable to the first layer, the at least one second layer of a substrate being a glass syntactic polyurethane;
wherein the at least one first layer of a silicone-containing rubber substrate material comprises a high consistency silicone rubber having a gum with a Williams plasticity of from 30 mm/100 to 300 mm/100 as measured in accordance with ASTM D-926-08;
wherein the first layer has at least a portion of the surface of the first layer activated by a flame treatment for adhering (bonding) the first layer to the second layer and for increasing the bond strength of the first layer to the second layer; and
wherein the activated surface of the first layer, activated by a flame treatment, is bonded to the surface of the second layer, wherein the bond strength of the first layer bonded to the second layer is from 0.57 N/mm to 10.07 N/mm.

2. A bonded multilayer article according to claim 1 , wherein the high consistency silicone rubber is an uncured high consistency silicone rubber.

3. The article of claim 1 , wherein the high consistency silicone rubber has at least 15 weight percent of a silicone gum present with a vinyl content of from equal to or greater than 0.15 weight percent to 0.3 weight percent.

4. The article of claim 1 , wherein first layer has a thermal stability of greater than 160° C. in water.

5. The article of claim 1 , wherein the second layer is a cured substrate material or an uncured substrate material.

6. The article of claim 1 , including further hollow glass microspheres.

7. The article of claim 1 comprising a multilayer thermal insulation coating for a metal pipeline.

8. A bonded multilayer article according to claim 1 , wherein the high consistency silicone rubber is a cured high consistency silicone rubber.

9. A process for producing a bonded multilayer article comprising the steps of:
(a) applying at least one first layer of a cured silicone-containing rubber substrate material to at least one second layer of an uncured substrate material bondable to the first layer; wherein the at least one first layer of a silicone-containing rubber substrate material comprises a cured high consistency silicone rubber having a gum with a Williams plasticity of from 30 mm/100 to 300 mm/100 as measured in accordance with ASTM D-926-08;
(b) flame treating at least a portion of the surface of the cured first layer to activate the surface of the cured first layer for bonding the first layer to the second layer and for increasing the bond strength of the first layer to the second layer, the second layer comprising a glass syntactic polyurethane; and
(c) heating the multilayer article of step (b) at a temperature sufficient to cure the uncured second layer and sufficient to bond the first layer to the second layer to form a bonded multilayer article, wherein the bond strength of the first layer bonded to the second layer is from 0.57 N/mm to 10.07 N/mm.

10. A process for producing a bonded multilayer article comprising the steps of:
(a) applying at least one first layer of an uncured silicone-containing rubber substrate material to at least one second layer of an uncured substrate material bondable to the first layer, the at least one second layer of a substrate material being a glass syntactic polyurethane; wherein the at least one first layer of a silicone-containing rubber substrate material comprises an uncured high consistency silicone rubber having a gum with a Williams plasticity of from 30 mm/100 to 300 mm/100 as measured in accordance with ASTM D-926-08;
(b) flame treating at least a portion of the surface of the uncured first layer to activate the surface of the uncured first layer for adhering (bonding) the first layer to the second layer and for increasing the bond strength of the first layer to the second layer; and
(c) heating the multilayer article of step (b) at a temperature sufficient to cure the uncured first layer and the uncured second layer and sufficient to bond the first layer to the second layer to form a bonded multilayer article, wherein the bond strength of the first layer bonded to the second layer is from 0.57 N/mm to 10.07 N/mm.

Assignees

• Dow Global Technologies Llc
• Dow Silicones Corp

Inventors

• Yan Ni
• Kumar Bhawesh
• Swanton Brian J
• Tonge Lauren
• Laroche Christophe R
• Brown Ii Mark

Classifications

• B32B2597/00

  Tubular articles, e.g. hoses, pipes · CPC title

• B32B2307/748

  Releasability · CPC title

• B32B2307/308

  Heat stability · CPC title

• B32B2307/304

  Insulating · CPC title

• B32B38/0008 Primary

  Electrical discharge treatment, e.g. corona, plasma treatment; wave energy or particle radiation (heat treatment B32B38/0036) · CPC title