Anti-counterfeiting lyocell fiber, preparation method thereof and anti-counterfeiting method

Patent metadata

Field	Value
Publication number	US-12024798-B2
Application number	US-202117615447-A
Country	US
Kind code	B2
Filing date	May 20, 2021
Priority date	Nov 11, 2020
Publication date	Jul 2, 2024
Grant date	Jul 2, 2024

Abstract

The present invention provides a preparation method of an anti-counterfeiting lyocell fiber, including the following steps: dissolving at least one amino acid metal chelate and a cellulose pulp in an aqueous solution of a cellosolve to obtain a spinning solution, and then performing wet spinning using the spinning solution to obtain an anti-counterfeiting lyocell fiber, wherein the amino acid metal chelate account for 0.2% to 0.6% of the total mass of the anti-counterfeiting lyocell fiber. The anti-counterfeiting lyocell fiber of the present invention uses an amino acid metal chelate for encryption, and the process is simple. The prepared product can be provided with one or two passwords based on the ratio of metal ions and the amino acids, so that the product prepared from this fiber has the advantages of memory tracking properties, identification function and high anti-counterfeiting capability grade.

First claim

What is claimed is:

1. A preparation method of an anti-counterfeiting lyocell fiber, comprising steps of:
dissolving at least one amino acid metal chelate and a cellulose pulp in an aqueous solution of a cellosolve to obtain a spinning solution, and then performing wet spinning using the spinning solution to obtain the anti-counterfeiting lyocell fiber, wherein the amino acid metal chelate accounts for 0.2% to 0.6% of the total mass of the anti-counterfeiting lyocell fiber.

2. The preparation method according to claim 1 , wherein the amino acid metal chelate is prepared from a metal compound and a ligand amino acid, the molar ratio of the metal compound and the ligand amino acid being 1-2: 1-3.

3. The preparation method according to claim 2 , wherein the ligand amino acid is selected from the group consisting of lysine, tryptophan, phenylalanine, leucine, isoleucine, threonine, methionine, valine, aspartic acid, glutamic acid and glycine.

4. The preparation method according to claim 2 , wherein the metal compound is selected from the group consisting of metal compounds of calcium, zinc, magnesium, potassium and manganese ions.

5. The preparation method according to claim 1 , wherein the cellosolve is N-methylmorpholine-N-oxide; and the mass fraction of the cellosolve in the aqueous solution is 45% to 55%.

6. The preparation method according to claim 1 , wherein the bath ratio of the mass of the cellulose pulp to the volume of the aqueous solution of the cellosolve is 1 g: 15-20 mL.

7. The preparation method according to claim 1 , wherein a raw material of the cellulose pulp comprises one or more of cotton, hemp and bamboo.

8. An anti-counterfeiting lyocell fiber prepared by the method of claim 1 , comprising a lyocell fiber and the at least one amino acid metal chelate, wherein the amino acid metal chelate accounts for 0.2% to 0.6% of the anti-counterfeiting lyocell fiber.

9. An anti-counterfeiting method of the anti-counterfeiting lyocell fiber of claim 8 , comprising:
an encryption step comprising encoding the anti-counterfeiting lyocell fiber according to the type and amount of the at least one amino acid metal chelate, and sending encryption information; and
a decryption and identification step comprising receiving the encryption information, and detecting the types and amounts of amino acids and metal ions in the lyocell fiber; and comparing them with the received encryption information, to identify the authenticity of the lyocell fiber.

Assignees

• Univ Soochow

Inventors

• Liu Yuqing
• He Yu
• Wan Chengwei
• Chen Kaiyi
• Wang Zhong
• Wang Guohe
• Pan Zhijuan

Classifications

• D10B2505/00

  Industrial · CPC title

• D10B2401/063

  high strength · CPC title

• D10B2201/24

  Viscose · CPC title

• D01F1/10

  Other agents for modifying properties · CPC title

• D01D5/06

  Wet spinning methods {(D01D5/0046 takes precedence)} · CPC title