Co-cured fluoroelastomers with improved chemical resistance

Patent metadata

Field	Value
Publication number	US-12024575-B2
Application number	US-202218054881-A
Country	US
Kind code	B2
Filing date	Nov 11, 2022
Priority date	Feb 19, 2020
Publication date	Jul 2, 2024
Grant date	Jul 2, 2024

Abstract

Co-cured blends of fluoroelastomers of tetrafluoroethylene-propylene copolymer with cure site monomer and terpolymers of Vinylidene fluoride (VDF), Hexafluoropropylene (HFP) and Tetrafluoroethylene (TFE) with peroxide as initiator and coagent TAIC as crosslinker show improved curing performance, improved mechanical properties and improved compression set as well. The co-cured fluoroelastomers show improved chemical resistance to the solvent aging systems and better retention of mechanical properties after aging at high temperature in the solvents system.

First claim

What is claimed is:

1. A co-cured elastomeric blend comprising:
about 25-75 parts fluoropolymer A;
about 25-75 parts fluoropolymer C,
carbon black at about 45 parts per 100 parts of polymers;
a peroxide initiator, and
a triazine co-crosslinking agent, wherein:
fluoropolymer A comprises a polymer of tetrafluoroethylene (TFE), propylene (PP), and cure site monomer (CSM), wherein the fluoropolymer A comprises about 35-55% propylene (PP), wherein the fluoropolymer A has a fluorine content about 57 wt %;
fluoropolymer C comprises a polymer of vinylidene fluoride (VDF), tetrafluoroethylene (TFE), and a perfluorinated methyl vinyl ether (PMVE), wherein the fluoropolymer C has a fluorine content about 70 wt %; and
fluoropolymer A and fluoropolymer C are crosslinked with the peroxide initiator, and the triazine co-crosslinking agent, wherein the co-cured elastomeric blend exhibits a synergistic effect and improvement in compression set, having a reduced compression set of about 18% when using a composition of 25 wt % fluoropolymer A of the reaction product from a compression set about 37% when using 100% fluoropolymer A, swelling percentage of co-cured fluoroelastomers from 50 parts fluoropolymer A and 50 parts fluoropolymer C after 168-hour aging at 200° C. with hydrocarbon solvents is 18.6% as compared to calculated 21.3%.

2. The blend of claim 1 , wherein the peroxide initiator is 2,5-dimethyl-2,5-di(t-butylperoxy)hexane (DBPH).

3. The blend of claim 2 , wherein the peroxide initiator 2,5-dimethyl-2,5-di(t-butylperoxy)hexane (DBPH) is present at 1 to 5 parts per 100 parts of polymers.

4. The blend of claim 1 , wherein the peroxide initiator is di(t-butylperoxyisopropyl)benzene.

5. The blend of claim 4 , wherein the peroxide initiator di(t-butylperoxyisopropyl)benzene is present at about 1 to 5 parts per 100 parts of polymers.

6. The blend of claim 1 , wherein the triazine cross linking agent is triallyl isocyanurade (TAIC).

7. The blend of claim 6 , wherein TAIC is present at about 1 to 7 parts per 100 parts of polymers.

8. The blend of claim 1 , wherein the CSM is selected from the group consisting of iodine atom and bromine atom.

9. A co-cured elastomeric blend comprising about 25-75 parts fluoropolymer A fluoropolymer C wherein:
and about 25-75 parts fluoropolymer A comprises a polymer of tetrafluoroethylene (TFE), propylene (PP), and cure site monomer (CSM), wherein the fluoropolymer A comprises about 35-55% propylene (PP), wherein the fluoropolymer A has a fluorine content about 57 wt %;
fluoropolymer C comprises at least one monomer unit of a perfluorinated methyl vinyl ether (PMVE)), wherein the fluoropolymer C has a fluorine content about 70 wt %; and
carbon black at about 45 parts per 100 parts of polymers;
wherein fluoropolymer A and fluoropolymer C are crosslinked with a peroxide initiator, and a triazine co-crosslinking agent, wherein the co-cured elastomeric blend exhibits a synergistic effect and improvement in compression set, having a reduced compression set of about 18% when using a composition of 25 wt % fluoropolymer A of the co-cured elastomeric blend from a compression set about 37% when using 100% fluoropolymer A, swelling percentage of co-cured fluoroelastomers from 50 parts fluoropolymer A and 50 parts fluoropolymer C after 168-hour aging at 200° C. with hydrocarbon solvents is 18.6% as compared to calculated 21.3%.

10. The blend of claim 9 , wherein the CSM is selected from the group consisting of iodine atom and bromine atom.

11. The blend of claim 9 , wherein the peroxide initiator comprises di(t-butylperoxyisopropyl)benzene and di(t-butylperoxyisopropyl)benzene is present at about 1 to 5 parts per 100 parts of polymer.

12. The blend of claim 9 , wherein the CSM comprises an iodine atom.

13. A co-cured elastomeric blend comprising about 25-75 parts fluoropolymer A and about 25-75 parts fluoropolymer C wherein:
fluoropolymer A comprises monomer units and cure site monomer (CSM), wherein the fluoropolymer A comprises about 35-55% propylene (PP), wherein the fluoropolymer A has a fluorine content about 57 wt %;
fluoropolymer C comprises at least one monomer unit of a perfluorinated methyl vinyl ether (PMVE)), wherein the fluoropolymer C has a fluorine content about 70 wt %; and
carbon black at about 45 parts per 100 parts of polymers;
wherein fluoropolymer A and fluoropolymer C are crosslinked with a peroxide initiator, and a triazine co-crosslinking agent, wherein the co-cured elastomeric blend exhibits a synergistic effect and improvement in compression set, having a reduced compression set of about 18% when using a composition of 25 wt % fluoropolymer A of the co-cured elastomeric blend from a compression set about 37% when using 100% fluoropolymer A, swelling percentage of co-cured fluoroelastomers from 50 parts fluoropolymer A and 50 parts fluoropolymer C after 168-hour aging at 200° C. with hydrocarbon solvents is 18.6% as compared to calculated 21.3%.

14. The blend of claim 13 , wherein the CSM is selected from the group consisting of iodine atom and bromine atom.

Assignees

• Cnpc Usa Corp
• Beijing Huamei Inc
• Beijing Huamel Inc
• China Nat Petroleum Corp

Inventors

• Xing Peixiang
• Ren Jiaxiang
• Cheng Peng
• Liu Yu
• Wang Yonghong

Classifications

• C08F214/282

  with fluorinated vinyl ethers · CPC title

• C08K5/3492

  Triazines · CPC title

• C08K5/14

  Peroxides · CPC title

• C08L27/16

  Homopolymers or copolymers or vinylidene fluoride · CPC title

• C08F214/222

  with fluorinated vinyl ethers · CPC title