Electrode architecture for fast charging

Patent metadata

Field	Value
Publication number	US-12021221-B2
Application number	US-202017097483-A
Country	US
Kind code	B2
Filing date	Nov 13, 2020
Priority date	Nov 13, 2020
Publication date	Jun 25, 2024
Grant date	Jun 25, 2024

Abstract

An electrode for an electrochemical cell is provided. The electrode includes a carbon membrane having a first face and an opposing second face, wherein at least a portion of the carbon membrane is modified to include an elevated number of nucleation sites for lithium relative to the carbon membrane when unmodified.

First claim

What is claimed is:

1. An electrode for an electrochemical cell, the electrode comprising:
a single layered carbon membrane having a first face and an opposing second face, the carbon membrane comprising greater than or equal to 95% carbon,
wherein a first portion of the carbon membrane extending between the first face and the opposing second face is modified such that the first portion of the carbon membrane extending between the first face and the opposing second face includes an elevated number of nucleation sites for lithium relative to a second portion of the carbon membrane extending between the first face and the opposing second face that is unmodified, wherein the first portion of the carbon membrane that is modified defines the electrode and the second portion of the carbon membrane that is unmodified defines a current collector.

2. The electrode according to claim 1 , wherein the carbon membrane comprises carbon nanotubes, carbon nanofibers, carbon paper, graphene paper, or combinations thereof.

3. The electrode according to claim 1 , wherein the first portion of the carbon membrane comprises greater than or equal to about 80% of the volume of the carbon membrane extending between the first face and the opposing second face.

4. The electrode according to claim 1 , wherein the carbon membrane is substantially free of molecules covalently bonded to the carbon membrane.

5. The electrode according to claim 1 , wherein the carbon membrane comprises a first surface portion extending along the first face and between the first face and the opposing second face, a second surface portion extending along the opposing second face and between the first face and the opposing second face, and a center portion extending between the first surface portion and the second surface portion and between the first face and the opposing second face, wherein the first portion of the carbon membrane comprises the first surface portion and the second surface portion, and the second portion of the carbon membrane comprises the center portion.

6. The electrode according to claim 5 , further comprising lithium, wherein the lithium is incorporated into at least one of the first surface portion or the second surface portion of the carbon membrane.

7. The electrode according to claim 1 , wherein the elevated number of nucleation sites for lithium are defined by defects in the first portion, and wherein the first portion of the carbon membrane extending between the first face and the opposing second face is modified by laser ablation, contact with oxygen plasma, wet chemistry oxidation, or a combination thereof.

8. The electrode according to claim 1 , wherein the carbon membrane has a thickness defined between the first face and the opposing second face of greater than or equal to about 10 micrometers to less than or equal to about 100 micrometers, and wherein the carbon membrane has a porosity of greater than or equal to about 30% to less than or equal to about 90%.

9. The electrode according to claim 1 , wherein the first portion of the carbon membrane is modified by laser ablation or wet chemistry oxidation.

10. The electrode according to claim 1 , wherein the carbon membrane defines a carbon matrix extending between the first face and the opposing second face, and wherein the carbon matrix is defined by an intermingled web of carbon nanotubes, carbon nanofibers, carbon paper, graphene paper, or a combination thereof.

11. The electrode according to claim 1 , wherein the first face and the opposing second face of the carbon membrane have a complex three-dimensional microstructure with a relatively high surface area as compared to the surface area of the carbon membrane when unmodified.

12. The electrode according to claim 1 , further comprising a plurality of solid-state electrolyte particles disposed at nucleation sites within the first portion of the carbon membrane extending between the first face and the opposing second face.

13. The electrode according to claim 1 , wherein the carbon membrane consists of carbon.

14. An electrode for an electrochemical cell, the electrode comprising:
a single layered carbon material having a first face and an opposing second face, the carbon material comprising greater than or equal to 95% carbon and being defined by carbon nanotubes, carbon nanofibers, carbon paper, graphene paper, or combinations thereof,
wherein a first portion of the carbon material extending between the first face and the opposing second face is modified such that the first portion of the carbon material extending between the first face and the opposing second face includes an elevated number of nucleation sites for lithium relative to a second portion of the carbon material when unmodified,
wherein the first portion of the carbon material extending between the first face and the opposing second face is physically and/or chemically modified by laser ablation, contact with oxygen plasma, wet chemistry oxidation, or a combination thereof, and
wherein the first portion of the carbon material that is modified defines the electrode and the second portion of the carbon material that is unmodified defines a current collector.

15. The electrode according to claim 14 , wherein the electrode exhibits a state of charge (SOC) of greater than or equal to about 75% after 15 minutes of charging, and wherein the electrode exhibits a volume change of less than or equal to about 20% during lithium plating and stripping.

16. A method of fabricating an electrode, the method comprising:
obtaining a single layered carbon material having a first face and an opposing second face, the carbon material comprising greater than or equal to 95% carbon and being defined by carbon nanotubes, carbon nanofibers, carbon paper, graphene paper, or combinations thereof, and
modifying a first portion of the carbon material extending between the first face and the opposing second face such that the first portion of the carbon material extending between the first face and the opposing second face includes an elevated number of nucleation sites for lithium relative to a second portion of the carbon material that is unmodified,
wherein the first portion of the carbon material that is modified defines the electrode and the second portion of the carbon material that is unmodified defines a current collector.

17. The method according to claim 16 , wherein modifying the first portion of the carbon material induces defects into the carbon material and is performed by laser ablation, contact with oxygen plasma, wet chemistry oxidation, or a combination thereof.

18. The method according to claim 16 , wherein the carbon material comprises a first surface portion extending along the first face, a second surface portion extending along the opposing second face, and a center portion extending between the first surface portion and the second surface portion and between the first face and the opposing second face, and wherein modifying the first portion of the carbon material comprises modifying the first surface portion and the second surface portion without modifying the center portion.

19. The method according to claim 16 , further comprising:
incorporating lithium into the first portion of the carbon material extending between the first face and the opposing second face by vacuum infiltration, electrochemical plating, thermal evaporation, lithium foil lamination, or combinations thereof.

Assignees

• Gm Global Tech Operations Llc

Inventors

• Xiao Xingcheng
• Wang Hongliang
• Dadheech Gayatri V
• Cai Mei

Classifications

• H01M4/366

  as layered products · CPC title

• H01M4/62

  Selection of inactive substances as ingredients for active masses, e.g. binders, fillers · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M4/663 Primary

  containing carbon or carbonaceous materials as conductive part, e.g. graphite, carbon fibres · CPC title

• H01M2004/027

  Negative electrodes · CPC title