Preparation process and LED application of copper nanoclusters fluorescent nanoflowers with high quantum yield

Patent metadata

Field	Value
Publication number	US-12021165-B2
Application number	US-202117456558-A
Country	US
Kind code	B2
Filing date	Nov 24, 2021
Priority date	Mar 15, 2021
Publication date	Jun 25, 2024
Grant date	Jun 25, 2024

Abstract

A preparation process and LED application of copper nanoclusters (Cu NCs) fluorescent nanoflowers with high quantum yield by dissolving Cu 4 I 4 into dimethyl sulfoxide (DMSO) and then adding glycerol, it self-assembles into Cu NCs s fluorescent nanoflowers. The Cu 4 I 4 fluorescent nanoflowers prepared by the invention have outstanding optical properties, a quantum yield up to 64.5%, and can be made into a series of different luminous colors and excellent stability LED only with commercial blue phosphor, such as yellow-green, sky blue, white, wherein according to the mass ratio of 4:5 ratio mix can be prepared white light emission LED. Fluorescent Cu NCs can successfully replace traditional light conversion materials and prepare environmentally friendly LEDs.

First claim

What is claimed is:

1. A process for preparing LED comprising the following steps: Cu NCs fluorescent nanoflowers are grounded evenly, and mixed with phosphor of different colors, then deposited on a LED chip by gluing and curing that yields various light-emitting color LEDs; wherein the Cu NCs fluorescent nanoflowers comprise flakes with a chemical composition of Cu 4 I 4 , which is quad-core Cu NCs with Cu as nucleus and triphenylphosphine as a ligand; each of the Cu NCs fluorescent nanoflowers has a diameter of 30-50 μm, each of the flakes has a length of 15-20 μm and a width of 5-8 μm.

2. The process according to claim 1 , wherein a fluorescent spectra of the Cu NCs fluorescent nanoflowers shows excitation wavelength between 290-400 nm and emission wavelength between 450-620 nm.

3. The process according to claim 1 , wherein the Cu NCs fluorescent nanoflowers are prepared by the following steps: Cu 4 I 4 is dissolved in DMSO with ultrasound, glycerol is added to the dissolved Cu 4 I 4 , vortex is applied to the dissolved Cu 4 I 4 , static is applied to the dissolved Cu 4 I 4 , centrifugal force is applied to the dissolved Cu 4 I 4 , the dissolved Cu 4 L 4 is washed and then dried; wherein the ratio of the DMSO and glycerol is 1:(1-3) by volume.

4. The process according to claim 3 , wherein Cu 4 I 4 has a molar concentration of 0.06-0.07 mmol·L −1 in the dissolved Cu 4 I 4 ; vortex is applied to the dissolved Cu 4 I 4 for 20-30 seconds and the dissolved Cu 4 I 4 is incubated for 5-48 hours; then, the dissolved Cu 4 I 4 is centrifuged at 6000-8000 r/min for 10-20 min.

5. The process according to claim 2 , wherein the Cu 4 I 4 is prepared by dispersing CuI in dichloromethane solution, stirring evenly, then adding triphenylphosphine, stirring fully at room temperature, filtering to obtain a white powdered solid; then, adding the white powdered solids to an acetylene solution, performing ultrasound, filtrating, washing with acetylene to obtain a pure white powdered solid; dissolving the pure white solid powder in DMSO solution, adding to a diffusion glass tube, a upper layer is diffused by methanol solution, and yielding Cu 4 I 4 powders in three days.

6. The process according to claim 1 , wherein the Cu NCs fluorescent nanoflowers and blue phosphor are mixed by a mass ratio of 1:(0.7-0.8);
high-fold LED patch silicone A and B glue are utilized for deposition, with a quality ratio of 1:4 for A glue and B glue; the LED chip has an excitation wavelength of 365 nm and a light effect of 0.9 lm/W;
curing at temperature of 60° C. for 3 hours.

Assignees

• Univ Shandong
• Shan Dong Univ

Inventors

• Xin Xia
• Zhou Shujin
• Sun Di
• Zhang Shanshan
• Feng Ning

Classifications

• H10H20/8512

  Wavelength conversion materials · CPC title

• H10H20/812

  within the light-emitting regions, e.g. having quantum confinement structures · CPC title

• H10H20/01 Primary

  Manufacture or treatment · CPC title

• H10H20/0361

  of wavelength conversion means · CPC title

• H10H20/8514

  characterised by their shape, e.g. plate or foil · CPC title