Processes for forming carbon-containing aramid bicomponent filament yarns

Patent metadata

Field	Value
Publication number	US-12018407-B2
Application number	US-202117207143-A
Country	US
Kind code	B2
Filing date	Apr 5, 2021
Priority date	Sep 1, 2016
Publication date	Jun 25, 2024
Grant date	Jun 25, 2024

Abstract

Processes for forming a yarn comprising a plurality of bicomponent filaments having a first region comprising a first polymer composition and a second region comprising a second polymer composition; the regions being distinct and present in the bicomponent filaments in a sheath-core structure or a side-by-side structure; wherein the first polymer composition comprises aramid polymer comprising 5 to 10 weight percent homogeneously dispersed discrete carbon particles and the second polymer composition comprises aramid polymer being free of discrete carbon particles and having at least one homogeneously dispersed masking pigment, the yarn having a total content of 0.5 to 5 weight percent discrete carbon particles.

First claim

What is claimed is:

1. A process for forming a yarn comprising bicomponent filaments, each of the filaments comprising a distinct core of a first aramid polymer comprising 5 to 10 weight percent carbon particles homogeneously dispersed therein, and a distinct sheath of a second aramid polymer being free of discrete carbon particles and having 10 to 20 weight percent of at least one masking pigment homogeneously dispersed therein, with the sheath surrounding the core, the yarn having a total content of 0.5 to 5 weight percent discrete carbon particles; the process comprising the steps of:
a) forming a first polymer solution containing the first aramid polymer in a solvent, the aramid polymer further comprising discrete carbon particles, and forming a second aramid polymer solution of the second aramid polymer being free of carbon particles and having at least one masking pigment in the same or different solvent;
b) providing a spinneret assembly having separate inlets for the first aramid polymer solution and the second aramid polymer solution and a plurality of exit capillaries for spinning dope filaments;
c) forming a plurality of dope filaments having a sheath of the second aramid polymer solution and a core of the first aramid polymer solution by extruding through the exit capillaries a plurality of conjoined streams of the first and the second aramid solutions into a spin cell, and
d) extracting solvent from the plurality of dope filaments to make a yarn of polymer filaments.

2. The process of claim 1 wherein the step d) of extracting solvent from the plurality of dope filaments to make a yarn includes the steps of:
i) contacting the dope filaments with heated gas in the spin cell to remove solvent from the dope filaments to form reduced solvent filaments;
ii) quenching the reduced solvent filaments with an aqueous liquid to cool the filaments, forming a yarn of polymer filaments; and
iii) further extracting solvent from the yarn of polymer filaments.

3. The process of claim 1 wherein the aramid polymer is poly(metaphenylene isophthalamide).

Assignees

• Dupont Safety & Construction Inc

Inventors

• Andersen Mark William
• Aronson Mark T
• Newton Christopher William
• Steinruck Thomas Wayne
• Wiseman B Lynne
• Zhu Reiyao

Classifications

• D02G3/22

  Yarns or threads characterised by constructional features {, e.g. blending, filament/fibre (piecing of yarns or threads D01H15/00)} · CPC title

• A41D13/008

  protecting against electric shocks or static electricity · CPC title

• D10B2501/04

  Outerwear; Protective garments · CPC title

• D02G3/443

  Heat-resistant, fireproof or flame-retardant yarns or threads (fire- or flame-proof filaments D01F1/07; woven fabrics using heat-resistant or fireproof threads D03D15/513) · CPC title

• D02G3/047

  including aramid fibres · CPC title