Mitigation of transient gels in cements

Patent metadata

Field	Value
Publication number	US-12018207-B2
Application number	US-202217892787-A
Country	US
Kind code	B2
Filing date	Aug 22, 2022
Priority date	Aug 22, 2022
Publication date	Jun 25, 2024
Grant date	Jun 25, 2024

Abstract

A cement slurry including graphene, a cement, and water; the graphene comprises bioderived renewable graphene (BRG). The cement slurry has reduced transient gel formation relative to a same cement slurry absent the graphene. Methods of mitigating transient gels in cement are also provided.

First claim

What is claimed is:

1. A method of making a cement slurry, the method comprising:
combining graphene with water to provide a mix water, wherein the graphene comprises bioderived renewable graphene (BRG), wherein the BRG comprises nanosheets comprising greater than 90 weight percent carbon, and wherein the nanosheets have a surface area of at least 2000 m 2 /g and up to 2496 m 2 /g, a pore volume of at least 3 cc/g and up to 5.0 cc/g, or a combination thereof;
combining the mix water with a cement to provide the cement slurry,

wherein the cement slurry has reduced transient gel formation relative to a same cement slurry absent the graphene; and
pumping the cement slurry into a workspace, wherein the workspace comprises a wellbore penetrating a subterranean formation.

2. The method of claim 1 , wherein the cement slurry comprises from about 0.01 to about 20 percent BRG by weight of cement (% BRG bwoc).

3. The method of claim 1 , wherein the BRG comprises graphene derived from a plant.

4. The method of claim 1 , wherein the BRG comprises graphene with a fused sheet-like morphology.

5. The method of claim 1 , wherein the cement comprises a cement selected from the group consisting of Type I, IA, II, IIA, III, IIIA, IV, V, VI, VII Portland cements, and combinations thereof.

6. The method of claim 1 , wherein the cement comprises a construction grade cement, wherein a construction grade cement is a cement comprising greater than about 1 weight percent (wt %) calcium aluminate (C3A).

7. The method of claim 1 , wherein a yield point of the cement slurry, when unset, as measured according to API 10B-2 is reduced by at least 10% relative to a same cement slurry, when unset, absent the graphene.

8. The method of claim 1 , wherein a thixotropic rate of the cement slurry, when unset, measured as the ten minute yield point divided by ten, is less than a thixotropic rate of a same cement slurry, when unset, absent the graphene.

9. The method of claim 1 , wherein an apparent viscosity at 100 RPM (AVIS 100 ) of the cement slurry, when unset, as measured according to API 10B-2 is reduced by at least 10% relative to a same cement slurry, when unset, absent the graphene.

10. A method comprising:
providing a cement slurry comprising: graphene; a cement; and water, wherein the graphene comprises bioderived renewable graphene (BRG), wherein the BRG comprises nanosheets comprising greater than 90 weight percent carbon, and wherein the nanosheets have a surface area of at least 2000 m 2 /g and up to 2496 m 2 /g, a pore volume of at least 3 cc/g and up to 5.0 cc/g, or a combination thereof, and wherein the cement slurry has reduced transient gel formation relative to a same cement slurry absent the graphene;
placing the cement slurry in a workspace, wherein the workspace comprises a wellbore penetrating a subterranean formation; and
allowing the cement slurry to set to provide a hardened cement.

11. A method of making a cement slurry, the method comprising:
combining graphene with water to provide a mix water, wherein the graphene comprises bioderived renewable graphene (BRG), wherein the BRG is produced by:
combining a renewable carbohydrate material with a dehydration solvent to aid hydrolysis;
removing glycosidic linkages and water via chemical and/or thermal activation to provide an intermediate fused carbon material;
thermochemically activating the intermediate fused carbon material to exfoliate intercalated carbon layers of the intermediate fused carbon material and to initiate chemical bonding of carbon atoms to form the BRG, wherein the BRG comprises a network of high surface area and pore volume sp2 bonded carbon nanosheets, wherein the nanosheets have a surface area of at least 2000 m 2 /g and up to 2496 m 2 /g, a pore volume of at least 3 cc/g and up to 5.0 cc/g, or a combination thereof:
combining the mix water with a cement to provide the cement slurry,

wherein the cement slurry has reduced transient gel formation relative to a same cement slurry absent the graphene; and
pumping the cement slurry into a workspace, wherein the workspace comprises a wellbore penetrating a subterranean formation.

12. The method of claim 11 , wherein the dehydration solvent comprises water, ethylene glycol, ethanol, or a combination thereof.

13. The method of claim 11 , wherein the chemical activation comprises activation with sodium hydroxide, hydrochloric acid, phosphoric acid, phosphorous acid, nitric acid, or a combination thereof.

14. The method of claim 11 , wherein removing glycosidic linkages is effected in the presence of a catalyst selected from yeast, aluminum-nickel alloy, cobalt, B 2 H 6 , zinc, copper, or a combination thereof.

15. The method of claim 11 , wherein removing glycosidic linkages comprises exposing a mixture of the carbonaceous material, a chemical, and optionally a catalyst to a temperature in a range of from about 45° C. to about 1050° C., in air or inert atmosphere to aid formation of the intermediate fused carbon material, wherein the intermediate fused carbon material comprises a fused carbon network with a sheet-like morphology.

16. The method of claim 11 , wherein the thermochemically activating comprising heating to a temperature in a range of from about 500 to about 1500° C., in an inert gas containing hydrogen gas.

17. The method of claim 16 , wherein the thermochemically activating further comprises treating the intermediate fused carbon product with a chemical selected from hydrazine, LiAlH 4 , B 2 H 6 , and/or NaBH 4 , or a combination thereof.

18. The method of claim 11 , wherein thermochemically activating comprises direct heating of the intermediate fused carbon material to exfoliate and remove water from the intermediate fused carbon material to form the BRG.

Assignees

• Halliburton Energy Services Inc

Inventors

• Pisklak Thomas Jason
• Lewis Samuel J
• Pineda Claudia

Classifications

• C04B14/024

  Graphite · CPC title

• C09K8/467 Primary

  containing additives for specific purposes · CPC title

• E21B33/13

  Methods or devices for cementing, for plugging holes, crevices or the like · CPC title

• C01B32/182

  Graphene · CPC title

• C04B28/02

  containing hydraulic cements other than calcium sulfates · CPC title