Aqueous polyorganosiloxane hybrid resin dispersion

Patent metadata

Field	Value
Publication number	US-12018149-B2
Application number	US-202016834781-A
Country	US
Kind code	B2
Filing date	Mar 30, 2020
Priority date	Apr 1, 2019
Publication date	Jun 25, 2024
Grant date	Jun 25, 2024

Abstract

An aqueous polyorganosiloxane hybrid resin dispersion includes at least one polyorganosiloxane hybrid resin and at least one emulsifier based on partly hydrolysed polyvinylacetates. The dispersion has a solids content of 30.0% by weight-70.0% by weight, preferably 45.0% by weight-55.0% by weight, based on the polyorganosiloxane hybrid resin dispersion, and the residual solvent content is <6.0% by weight, preferably <2.5% by weight, more preferably <1.0% by weight, based on the polyorganosiloxane hybrid resin dispersion.

First claim

The invention claimed is:

1. An aqueous polyorganosiloxane hybrid resin dispersion, comprising:
at least one polyorganosiloxane hybrid resin which comprises a reaction product of a composition, comprising:
component A) 5 to 95 parts by weight of one or more polyorganosiloxanes of the general formula:
R a Si(OR′) b O (4−a−b/2)   formula (I)

wherein 0<a<2, 0<b<2 and a+b<4,
component B) 1-20 parts by weight of one or more linear and/or branched polyorganosiloxanes of the formula
R″O—[R′″ 2 Si—O] n —  formula (II)

where R″ and R″′ are each independently an alkyl radical having 1 to 8 carbon atoms or an aromatic radical having 6 to 20 carbon atoms and n is a number in the range from 4 to 250, and
component C) 5 to 95 parts by weight of an organic polymer containing hydroxyl groups selected from the group consisting of polyepoxides, polyesters, polyacrylates and/or methacrylates and copolymers thereof, polyurethanes, cellulose derivatives, polysulfones, polyether sulfones, polyphenylene sulfides and oxides, polyamides, polyamide imide, polyimides, polyethers, aromatic and aliphatic glycidyl-functional polymers, and oligomers thereof, phenoxy resins, polycarbonates, ketone-formaldehyde resins, polyvinyl resins, phenolic resins, fluoropolymers, alkyd resins, and mixtures thereof,
wherein R and R′ are each independently an alkyl radical having 1 to 8 carbon atoms or an aromatic radical having 6 to 20 carbon atoms, and
at least one emulsifier comprising a partly hydrolysed polyvinylacetate,
wherein the aqueous polyorganosiloxane hybrid resin dispersion has a solids content of 30.0%-70.0% by weight, based on the aqueous polyorganosiloxane hybrid resin dispersion, and a residual solvent content of <6.0% by weight, based on the aqueous polyorganosiloxane hybrid resin dispersion,
said reaction product is a reaction of said polyorganosiloxane A) with hydroxyl groups of said organic polymer C) containing hydroxyl groups, and
a weight ratio of said polyorganosiloxane hybrid resin to emulsifier is between 5-50:1.

2. The aqueous polyorganosiloxane hybrid resin dispersion according to claim 1 , wherein the organic polymer contains acidic hydrogen.

3. The aqueous polyorganosiloxane hybrid resin dispersion according to claim 1 , wherein the partly hydrolysed polyvinylacetate has an alcoholysis level between 10%-99% (mol/mol).

4. The aqueous polyorganosiloxane hybrid resin dispersion according to claim 1 , wherein the partly hydrolysed polyvinylacetate has a viscosity, measured in a 4% aqueous polyvinylacetate solution at 20° C. to DIN 53015, of 1-50 mPa s.

5. The aqueous polyorganosiloxane hybrid resin dispersion according to claim 1 , wherein the aqueous polyorganosiloxane hybrid resin dispersion further comprises an additional emulsifier selected from the group consisting of the anionic, cationic, zwitterionic, nonionic emulsifiers, and mixtures thereof.

6. The aqueous polyorganosiloxane hybrid resin dispersion according to claim 1 , wherein the flashpoint of the aqueous polyorganosiloxane hybrid resin dispersion is >30.0° C.

7. The aqueous polyorganosiloxane hybrid resin dispersion according to claim 1 , wherein the aqueous polyorganosiloxane hybrid resin dispersion further comprises an additive selected from the group consisting of defoamers, deaerating agents, rheology additives, preservatives, substrate wetting agents, crosslinkers, drying aids, catalysts, antioxidants, anti-skinning agents, anti-settling agents, thickeners, coalescing agents, film-forming aids, fillers, pigments, dispersants, and mixtures thereof.

8. The aqueous polyorganosiloxane hybrid resin dispersion according to claim 7 , wherein the additive is a preservative selected from the group consisting of fungicides, bactericides, pesticides, algicides, herbicides, and mixtures thereof.

9. The aqueous polyorganosiloxane hybrid resin dispersion according to claim 1 , wherein said polyorganosiloxane hybrid resin is presented as particles in said dispersion having an average volume-weighted diameter measured according to ISO 13320:2009, of between 0.1-10.0 μm.

10. A coating material, a coating, paint, substrate coating, semifinished product, adhesive, ink, sealant, compounding matrix, or size, comprising:
the polyorganosiloxane hybrid resin dispersion according to claim 1 .

11. A substrate, coated with a composition comprising the aqueous polyorganosiloxane hybrid resin dispersion according to claim 1 .

12. The aqueous polyorganosiloxane hybrid resin dispersion according to claim 1 , wherein said organic polymer is at least one polyvinyl resin selected from the group consisting of polyvinyl alcohol, polyglycerols, polyvinylacetate, and (partial) hydrolysates and derivatives thereof.

13. The aqueous polyorganosiloxane hybrid resin dispersion according to claim 1 , wherein component C) is an organic polymer selected from the group consisting of polyepoxides, polyesters, polyacrylates and/or methacrylates and copolymers thereof, polyurethanes, cellulose derivatives, polysulfones, polyether sulfones, polyphenylene sulfides and oxides, polyamides, polyamide imide, polyimides, polyethers, aromatic and aliphatic glycidyl-functional polymers, and oligomers thereof, phenoxy resins, polycarbonates, ketone-formaldehyde resins, phenolic resins, fluoropolymers, alkyd resins, and mixtures thereof.

Assignees

• Evonik Operations Gmbh

Inventors

• Seyfried Mona
• Silber Stefan
• De Gans Berend-Jan
• Fiedel Michael
• Hallack Markus

Classifications

• C09D183/04

  Polysiloxanes · CPC title

• C09D167/025

  containing polyether sequences · CPC title

• C08L2205/035

  containing four or more polymers in a blend · CPC title

• C08L2205/025

  containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure · CPC title

• C08L2201/54

  Aqueous solutions or dispersions · CPC title