Electrically heated dehydrogenation process

Patent metadata

Field	Value
Publication number	US-12017983-B2
Application number	US-202318169086-A
Country	US
Kind code	B2
Filing date	Feb 14, 2023
Priority date	Jun 22, 2020
Publication date	Jun 25, 2024
Grant date	Jun 25, 2024

Abstract

Systems and processes for dehydrogenating one or more alkanes using electrically heated dehydrogenation reactors. The source of electric energy or power can be a power grid, solar panel, windmill, hydropower, nuclear power, fuel cell, gas turbines, steam turbines, portable generator or the like. The systems and processes provided herein result in a simpler dehydrogenation process which is particularly beneficial at a small scale and at remote locations, including the well site.

First claim

What is claimed is:

1. A process for dehydrogenating natural gas liquids (NGLs), comprising:
providing a hydrocarbon feed stream comprising one or more natural gas liquids (NGLs) C 2+ ; and
dehydrogenating at least a portion of the one or more natural gas liquids (NGLs) into one or more C 2+ olefinic hydrocarbons within an electrically heated reactor.

2. The process of claim 1 , wherein electrical energy for the electrically heated reactor comes from a power grid.

3. The process of claim 1 , wherein electrical energy for the electrically heated reactor comes from one or more fuel cells.

4. The process of claim 3 , wherein at least one of the one or more fuel cells is a hydrogen cell.

5. The process of claim 4 , wherein hydrogen to the hydrogen fuel cell is one of the products from the dehydrogenation process.

6. The process of claim 1 , wherein electrical energy for the electrically heated reactor comes from a power grid and one or more fuel cells.

7. The process of claim 1 , wherein electrical energy for the electrically heated reactor comes from a power grid and one or more steam turbines that recover work from other heat streams in the process.

8. The process of claim 1 , wherein electrical energy for the electrically heated reactor comes from one or more fuel cells and one or more steam turbines that recover work from heat streams in the process.

9. The process of claim 1 , wherein electrical energy for the electrically heated reactor comes from a power grid, one or more steam turbines that recover work from heat streams in the process, and one or more fuel cells.

10. The process of claim 1 wherein the hydrocarbon feed stream is a sweet and dry shale gas mixture.

11. The process claim 1 , wherein the flowrate of the hydrocarbon feed stream is equal to or less than 200 MMSCFD, less than 50 MMSCFD or less than 20 MMSCFD.

12. The process of claim 1 , wherein electrical energy for the electrically heated reactor is provided from one or more power grids, solar panels, windmills, hydropower, nuclear power, fuel cells, gas turbines, steam turbines, portable generators or combinations thereof.

13. The process of claim 1 , wherein the hydrocarbon feed stream consists essentially of one or more natural gas liquids (NGLs).

14. The process of claim 1 , further comprising:
obtaining a raw shale gas from a downhole formation;
separating methane from the raw shale gas to provide the hydrocarbon feed stream comprising one or more natural gas liquids (NGLs).

15. The process of claim 1 , further comprising:
obtaining a raw natural gas from a downhole formation;
separating methane from the raw natural gas to provide the hydrocarbon feed stream comprising one or more natural gas liquids (NGLs).

16. A process for alkane dehydrogenation, comprising:
providing a hydrocarbon feed stream comprising one or more alkanes that are C 2+ hydrocarbons; and
dehydrogenating at least a portion of the one or more alkanes that are C2+ hydrocarbons into one or more C 2+ olefinic hydrocarbons within an electrically heated reactor, wherein the electrically heated reactor is a tube reactor comprising one or more internally located electrically heated elements to provide direct heat transfer from the heated element to the hydrocarbon feed stream.

17. The process of claim 16 , wherein the heating element is a metal alloy strip.

18. The process of claim 16 , wherein the tube reactor comprises one or more parallel sheets as heating elements.

19. The process of claim 16 , wherein the tube reactor comprises one or more spiral wounds.

20. The process of claim 16 , wherein multiple wires of the heating element are enclosed in the reactor tube.

21. The process of claim 16 , wherein the heating elements are thin tubes and are enclosed within the tube reactor.

22. The process of claim 16 , wherein the tube reactor is a heating element.

23. The process of claim 16 , wherein the heating element is an alloy comprising any combination of Fe, Cr, Ni, and Al.

Assignees

• Purdue Research Foundation

Inventors

• Agrawal Rakesh
• Chen Zewei
• Oladipupo Peter

Classifications

• B01J19/2415

  Tubular reactors · CPC title

• B01J2219/00081

  Tubes · CPC title

• B01J2219/00132

  using electric heating or cooling elements · CPC title

• B01J2219/00085

  Plates; Jackets; Cylinders · CPC title

• B01J19/0013

  Controlling the temperature of the process · CPC title