Low-E glass plate, protective sheet for low-E glass plate and use thereof

Patent metadata

Field	Value
Publication number	US-12017950-B2
Application number	US-202017596663-A
Country	US
Kind code	B2
Filing date	Jun 23, 2020
Priority date	Jun 27, 2019
Publication date	Jun 25, 2024
Grant date	Jun 25, 2024

Abstract

Provided is a Low-E glass plate protection method capable of preventing or inhibiting alteration and erosion of Low-E layers. The protection method includes a step of applying a protective sheet to a surface of a Low-E glass plate having a Low-E layer comprising a tin component. Here, the Low-E layer comprises a tin component. The protective sheet has a PSA layer. The PSA layer comprises a phosphorus compound having a P—OR group. Here, R is a hydrogen atom or an organic group.

First claim

The invention claimed is:

1. A method for protecting a Low-E glass plate, the method comprising a step of applying a protective sheet to a surface of a Low-E glass plate including a Low-E layer, wherein
the Low-E layer comprises a tin component,
the protective sheet comprises a pressure-sensitive adhesive layer, and
the pressure-sensitive adhesive layer comprises a phosphorous compound having a P-OR group, wherein R is a hydrogen atom or an organic group.

2. The method according to claim 1 , wherein after the protective sheet is applied to the Low-E glass plate, a film is newly formed on/in the Low-E layer and the film comprises P and Sn as its constituent elements.

3. The method according to claim 2 , wherein the film exists on an outer surface of the Low-E layer.

4. The method according to claim 2 , wherein the film exists internal to the Low-E layer.

5. The method according to claim 2 , wherein the film is formed within 24 hours after the protective sheet is applied to the surface of the Low-E glass plate.

6. The method according to claim 2 , wherein the film has a thickness of 1 nm or greater and 20 nm or less.

7. The method according to claim 1 , wherein the phosphorous compound is selected between a phosphate and a phosphite.

8. The method according to claim 1 , wherein the tin component of the Low-E layer is contained in a tin-containing layer.

9. The method according to claim 8 , wherein the tin component in the tin-containing layer is a tin oxide.

10. The method according to claim 1 , the method further comprising a step of removing the protective sheet from the Low-E glass plate; and between the application and removal of the protective sheet to and from the Low-E glass plate, a step of subjecting the Low-E glass plate having the protective sheet applied thereon to at least one process selected from the group consisting of transportation, storage, processing, washing and handling.

11. The method according to claim 1 , wherein
the Low-E glass plate has a width of 1 m or greater,
the application of the protective sheet to the Low-E glass plate comprises a step of entirely covering one face of the Low-E glass plate with at least one said protective sheet.

12. The method according to claim 1 , wherein the protective sheet is adhered to the Low-E glass plate with a 180° peel strength of 5 N/20 mm or less.

Assignees

• Nitto Denko Corp

Inventors

• Shimazaki Yuta
• Yonezaki Kosuke
• Horiguchi Hakaru
• Mishima Kunimasa

Classifications

• C03C17/38

  at least one coating being a coating of an organic material · CPC title

• C03C17/36 Primary

  at least one coating being a metal · CPC title

• C03C2218/355

  Temporary coating · CPC title

• C03C2218/154

  by sputtering · CPC title

• C03C2217/734

  comprising an alternation of high and low refractive indexes · CPC title