Amorphous carbon material, prepared by subjecting mixture of carbonaceous material and aqueous solution to phase separation and drying, preparation method and use thereof

Patent metadata

Field	Value
Publication number	US-12017916-B2
Application number	US-201817055843-A
Country	US
Kind code	B2
Filing date	Aug 13, 2018
Priority date	May 18, 2018
Publication date	Jun 25, 2024
Grant date	Jun 25, 2024

Abstract

The present disclosure relates to the field of carbon materials, in particular to an amorphous carbon material and a preparation method and an application thereof. The amorphous carbon material has the following characteristics: (1) a true density ρ of the amorphous carbon material and a interlayer spacing d 002 obtained by powder X-Ray Diffraction (XRD) spectrum analysis satisfy the following relational formula: 100×ρ×d 002 ≥70; (2) the interlayer spacing d 002 , L a and L c of the amorphous carbon material obtained by powder XRD spectrum analysis satisfy the following relational formula: L c ×d 002 ≤0.58, and 100×(L c /L a 2 )×d 002 3 ≤0.425 wherein ρ is denoted by the unit of g/cm 3 , each of d 002 , L c and L a is denoted by the unit of nm. The amorphous carbon material prepared by the present disclosure has desirable heat transfer performance and can provide high battery capacity.

First claim

The invention claimed is:

1. An amorphous carbon material, wherein
(1) a true density ρ of the amorphous carbon material is 1.98-2.20 g/cm 3 ;
(2) an interlayer spacing d 002 obtained by powder X-Ray Diffraction (XRD) spectrum analysis is 0.355-0.390 nm;
(3) the amorphous carbon material has a L a value obtained by powder XRD spectrum analysis within a range of 3-6 nm;
(4) the amorphous carbon material has a L c value obtained by powder XRD spectrum analysis within a range of 0.9-2.0 nm; and
wherein the amorphous carbon material is in the form of powder having a particle size D 50 within a range of 2-50 μm.

2. The amorphous carbon material of claim 1 , wherein the amorphous carbon material has a thermal diffusion coefficient larger than or equal to 0.09 mm 2 ·s −1 .

3. A material for mechanical parts comprising the amorphous carbon material of claim 1 .

4. A battery electrode material comprising the amorphous carbon material of claim 1 .

5. A heat conduction material comprising the amorphous carbon material of claim 1 .

6. A method for preparing the amorphous carbon material of claim 1 comprising the following steps:
(1) providing a carbonaceous material powder having a carbon element content larger than 70%;
(2) mixing the carbonaceous material powder with an aqueous solution containing a surfactant, then subjecting the mixture to a phase separation, and drying the obtained solid to obtain a dried powder; and
(3) subjecting the dried powder to carbonization under vacuum or an inert atmosphere;
wherein the surfactant is an anionic surfactant and/or a cationic surfactant;
wherein the anionic surfactant is at least one selected from the group consisting of arabic gum, sodium carboxymethylcellulose, C 8 -C 12 fatty acid salts, C 12 -C 20 alkyl sulfonate salts, alkyl benzene sulfonate salts, and C 12 -C 18 fatty alcohol sulfate salts; and
wherein the cationic surfactant is at least one selected from the group consisting of the C 10 -C 22 alkyltrimethylammonium type cationic surfactants, the di-(C 10 -C 22 ) alkyldimethylammonium type cationic surfactants, and the C 10 -C 22 alkyldimethylbenzylammonium type cationic surfactants;
wherein the carbonaceous material powder has an average particle diameter D 50 within a range of 1-100 μm.

7. The method of claim 6 , wherein the surfactant-containing aqueous solution has a concentration of surfactant within a range of 0.001-50 wt %;
wherein the surfactant is used in an amount of 0.005-250 parts by weight, relative to 100 parts by weight of the carbonaceous material powder.

8. The method of claim 6 , wherein the carbonization in step (3) is conducted at a temperature within a range of 900-1,600° C. for a time within a range of 1-20 hours.

9. The method of claim 8 , wherein the method further comprises: pre-firing the dried powder under vacuum or an inert atmosphere before the carbonization treatment in the step (3), wherein the pre-firing is conducted at a temperature within a range of 400-800° C. for a time within a range of 1-12 hours.

10. The method of claim 6 , wherein the method further comprises: a step of ball milling carried out at any stage between step (1) and step (3) such that the powder entering the carbonization process has an average particle diameter D 50 within a range of 1-50 μm.

11. The method of claim 6 , wherein the carbonaceous material selected from the group consisting of pitch, coal, coke, and a combination thereof.

Assignees

• China Energy Investment Corp Ltd
• Nat Inst Clean & Low Carbon Energy

Inventors

• Pan Guanghong
• Liang Wenbin
• Tang Kun
• Tian Yajun
• Kang Danmiao
• Duan Chunting
• Kang Libin
• Wei Chang

Classifications

• Y02E60/10

  Energy storage using batteries · CPC title

• C01P2006/10

  Solid density · CPC title

• C01P2004/61

  Micrometer sized, i.e. from 1-100 micrometer · CPC title

• C01P2002/82

  by IR- or Raman-data · CPC title

• C01P2002/76

  by a space-group or by other symmetry indications · CPC title