Tire having a composition comprising an ethylene-rich elastomer, a peroxide and a specific acrylate derivative

Patent metadata

Field	Value
Publication number	US-12017480-B2
Application number	US-201917270786-A
Country	US
Kind code	B2
Filing date	Aug 13, 2019
Priority date	Aug 23, 2018
Publication date	Jun 25, 2024
Grant date	Jun 25, 2024

Abstract

A tire comprises a rubber composition based on at least one elastomeric matrix mainly comprising a random copolymer comprising ethylene units and conjugated diene units, the mole fraction of the ethylene units in the copolymer being within a range extending from 50% to 95%; a peroxide; and a specific polyfunctional acrylate derivative.

First claim

The invention claimed is:

1. A tire comprising a rubber composition based on:
an elastomeric matrix comprising predominantly a random copolymer comprising ethylene units and conjugated diene units, the mole fraction of the ethylene units in the copolymer being within a range extending from 50% to 95%;
at least one peroxide; and
at least one polyfunctional acrylate derivative of formula (I):
[ X ] p A   (I)

in which:
A represents a linear, branched or cyclic C 4 -C 30 hydrocarbon group, interrupted and/or substituted by one or more heteroatoms, A comprising p free valences, p having a value ranging from 2 to 6, and
[X]p corresponds to a radical of formula (II):

in which
 R 1 , R 2 and R 3 independently represent a hydrogen atom or a C 1 -C 8 hydrocarbon group selected from the group consisting of linear, branched or cyclic alkyl groups, alkylaryl groups, aryl groups and aralkyls, and which are optionally interrupted by one or more heteroatoms, it being possible for R 2 and R 3 together to form a non-aromatic ring, and
 (*) represents the point of attachment of the radical of formula (II) to A, it being understood that the 2 to 6× radicals are identical or different.

2. The tire according to claim 1 , wherein the conjugated diene units are selected from the group consisting of butadiene units, isoprene units and mixtures thereof.

3. The tire according to claim 1 , wherein the mole fraction of the ethylene units in the random copolymer comprising ethylene units and conjugated diene units is within a range extending from 60% to 90%.

4. The tire according to claim 1 , wherein R 1 , R 2 and R 3 each represent a hydrogen atom.

5. The tire according to claim 1 , wherein the heteroatom(s) of A are selected from the group consisting of oxygen, sulfur, nitrogen, silicon and phosphorus atoms, and combinations thereof.

6. The tire according to claim 1 , wherein A represents a linear, branched or cyclic C 4 -C 30 hydrocarbon group, interrupted and/or substituted by one or more oxygen and/or sulfur atoms.

7. The tire according to claim 1 , wherein A represents a linear, branched or cyclic C 4 -C 30 hydrocarbon group, interrupted by one or more oxygen and/or sulfur atoms.

8. The tire according to claim 1 , wherein the at least one polyfunctional acrylate derivative of formula (I) is selected from the group consisting of dipentaerythritol penta(meth)acrylate, dipentaerythritol hexa(meth)acrylate, diethylene glycol di(meth)acrylate, dipropylene glycol di(meth)acrylate, ethoxylated hexanediol di(meth)acrylate, propoxylated hexanediol di(meth)acrylate, ethoxylated trimethylpropane tri(meth)acrylate, propoxylated trimethylpropane tri(meth)acrylate, ethoxylated pentaerythritol tetra(meth)acrylate, propoxylated pentaerythritol tetra(meth)acrylate, ethoxylated bisphenol A di(meth)acrylate, propoxylated bisphenol A di(meth)acrylate, ethoxylated hexanediol glycol di(meth)acrylate glycol, propoxylated hexanediol glycol di(meth)acrylate, ethoxylated neopentyl glycol di(meth)acrylate, propoxylated neopentyl glycol di(meth)acrylate, ethoxylated glyceryl tri(meth)acrylate, propoxylated glyceryl tri(meth)acrylate, ethoxylated trimethylolpropane tri(meth)acrylate, propoxylated trimethylolpropane tri(meth)acrylate, ester diol di(meth)acrylate, tri(2-hydroxyethyl) isocyanurate tri(meth)acrylate, hydroxypivalyl hydroxypivalate bis[6-(acryloyloxy)hexanoate, and mixtures thereof.

9. The tire according to claim 1 , wherein the amount of the at least one polyfunctional acrylate derivative of formula (I) in the rubber composition is within a range extending from 5 to 50 parts by weight per hundred parts by weight of elastomer, phr.

10. The tire according to claim 1 , wherein the at least one peroxide in the rubber composition is an organic peroxide.

11. The tire according to claim 1 , wherein the amount of the at least one peroxide in the rubber composition is within a range extending from 0.1 to 10 phr.

12. The tire according to claim 1 , wherein the rubber composition comprises from 5 to 65 phr of reinforcing filler.

13. The tire according to claim 12 , wherein the reinforcing filler comprises a carbon black, a silica, or a mixture thereof.

14. The tire according to claim 12 , wherein the reinforcing filler mainly comprises carbon black.

15. The tire according to claim 1 , wherein the rubber composition is present in the tread, in at least one internal layer, or in both the tread and at least one internal layer of the tire.

16. The tire according to claim 15 , wherein the at least one internal layer is selected from the group consisting of carcass plies, crown plies, bead-wire fillings, crown feet, decoupling layers, edge rubbers, padding rubbers, the tread underlayer and combinations thereof.

Assignees

• Michelin & Cie

Inventors

• Pibre Guillaume
• Messina Andrea
• Gornard Benjamin

Classifications

• C08L23/083

  with aliphatic polyenes, i.e. containing two or more carbon-to-carbon double bonds · CPC title

• C08K5/14

  Peroxides · CPC title

• C08K3/36

  Silica · CPC title

• C08K3/04

  Carbon · CPC title

• B60C1/0041

  Compositions of the carcass layers · CPC title