Separator, method of manufacturing separator, and electrochemical device including separator

Patent metadata

Field	Value
Publication number	US-12015170-B2
Application number	US-202318331272-A
Country	US
Kind code	B2
Filing date	Jun 8, 2023
Priority date	Jun 9, 2022
Publication date	Jun 18, 2024
Grant date	Jun 18, 2024

Abstract

A separator, a method of manufacturing the separator, and an electrochemical device including the separator. The separator includes: a porous substrate; and an inorganic particle layer formed on at least one surface of the porous substrate, wherein a release rate of the inorganic particle layer is 70% or more when measured by immersing the separator in a water tank at room temperature and then subjecting the separator to sonication under conditions of a frequency of 40 kHz, an output of 1,000 W, and an application time of 60 seconds.

First claim

What is claimed is:

1. A method of manufacturing a separator, the method comprising:
(a1) preparing an acid aqueous solution including a silane compound represented by Chemical Formula 1 and an acid component;
(a2) preparing an inorganic slurry by stirring inorganic particles, an acid component, and water;
(a3) preparing a coating slurry by mixing the inorganic slurry and the acid aqueous solution; and
(b) applying the prepared coating slurry on at least one surface of a porous substrate and drying the coating slurry to provide an inorganic particle layer:
A a Si(OR) b   Chemical Formula 1

wherein A is hydrogen, a polar functional group, or a C1-C10 alkyl group having a polar functional group, R is independently hydrogen or a C1-C5 alkyl group, a is 0 to 2, b is 2 to 4, and a+b is 4, and
wherein the polar functional group of the silane compound includes one or two or more selected from an amino group, an epoxy group, a carboxyl group, a hydroxyl group, an amide group, a thiol group, a ketone group, an ester group, and an aldehyde group.

2. The method of claim 1 , wherein the process (a3) is performed in a weakly acidic atmosphere of more than pH 4 and pH 7 or less.

3. The method of claim 1 , wherein an absolute value of a difference in pH of the inorganic slurry prepared in the process (a2) and pH of the acid aqueous solution prepared in the process (a1) is 1 or less.

4. The method of claim 1 , wherein in the process (a2), the inorganic slurry is prepared by stirring the inorganic particles, acid component, and water at 50 to 500 rpm for 1 hour or longer.

5. The method of claim 1 , wherein the processes in (a1) to (a3) are performed in a weakly acidic environment of more than pH 4 and pH 7 or less.

6. The method of claim 1 , wherein the acid component is carbon dioxide, or an organic acid including one or two selected from acetic acid and lactic acid.

7. The method of claim 1 , wherein a weight ratio of the silane compound of Chemical Formula 1 to the inorganic particles in the coating slurry is 0.1 to 30:99.9 to 70.

8. The method of claim 1 , further comprising, after the process (b), (c) aging the porous substrate on which the inorganic particle layer is provided.

9. The method of claim 1 , wherein a surface of the porous substrate is subjected to a hydrophilic surface treatment.

10. The method of claim 9 , wherein the hydrophilic surface treatment includes one or more of a corona discharge treatment and a plasma discharge treatment.

Assignees

• Sk Innovation Co Ltd
• Sk Ie Tech Co Ltd

Inventors

• Kim Yun Bong
• Cho Kyu Young
• Kwon Tae Wook
• Bae Heung Taek

Classifications

• H01M10/052

  Li-accumulators · CPC title

• H01M50/449

  having a layered structure · CPC title

• H01M50/403 Primary

  Manufacturing processes of separators, membranes or diaphragms · CPC title

• H01M50/446

  Composite material consisting of a mixture of organic and inorganic materials · CPC title

• H01M50/443

  Particulate material · CPC title