Method for the manufacture of a colored polymer composition

Patent metadata

Field	Value
Publication number	US-12012496-B2
Application number	US-201917059651-A
Country	US
Kind code	B2
Filing date	May 24, 2019
Priority date	Jun 5, 2018
Publication date	Jun 18, 2024
Grant date	Jun 18, 2024

Abstract

Method for the manufacture of a colored polymer composition comprising a polymer, a release agent and a colorant, the method comprising the steps of feeding a solid form of a release agent composition comprising said release agent and said colorant to a feed section of a melt mixing device, feeding said polymer to said melt mixing device and mixing said release agent composition and said polymer in said melt mixing device at a temperature above the melting temperature of said polymer, wherein—said colorant is a pigment, or a dye which is soluble in said release agent, —said polymer comprises or consists of polycarbonate, —the release agent is selected from the group consisting of penta-erythritol tetra stearate, glycerol monostearate, glycerol tristearate and mixtures thereof.

First claim

The invention claimed is:

1. A method for the manufacture of a colored polymer composition comprising a polymer, a release agent and a colorant, the method comprising the steps of
feeding a solid form of a release agent composition comprising said release agent and said colorant to a feed section of a melt mixing device, and
separately feeding said polymer to said melt mixing device and mixing said release agent composition and said polymer in said melt mixing device at a temperature above the melting temperature of said polymer, wherein
said colorant is a pigment, or a dye which is soluble in said release agent,
said polymer composition comprises polycarbonate, and
the release agent consists of penta-erythritol tetra stearate, glycerol monostearate, glycerol tristearate or a mixture thereof,

wherein the composition does not comprise carbon based pigments,
wherein the release agent composition comprises
 60 to 99 wt. % of the release agent based on the weight of the release agent composition;
0.001 to 0.1 wt. % of the colorant based on the weight of the release agent composition; and
0 to 40 wt. % of a UV stabilizer based on the weight of the release agent composition; and

wherein the polymer comprises 90 to 100 wt. % of a polycarbonate or a mixture of at least two aromatic polycarbonates based on the weight of the polymer.

2. The method of claim 1 wherein the solid form of the release agent composition consists of one or more of pellets, powder, flakes or beads.

3. The method of claim 1 wherein the release agent composition further comprises one or more functional additives, wherein the one or more functional additives comprises anti-oxidants, UV stabilisers, hydrolytical stabilisers, flame retardants, catalyst quenchers, anti-static agents or a mixture thereof.

4. The method of claim 1 wherein the polymer consists of an aromatic polycarbonate or a mixture of at least two aromatic polycarbonates.

5. The method of claim 1 wherein the melt mixing device is an extruder.

6. The method of claim 1 further comprising a step of preparing said release agent composition by mixing said release agent and said colorant and optionally one or more functional additives, wherein the one or more functional additives comprises anti-oxidants, UV stabilisers, hydrolytical stabilisers, flame retardants, catalyst quenchers or anti-static agents at a temperature above the melting temperature of said release agent.

7. A method for the manufacture of a batch of semi-finished or finished articles comprising converting the colored polymer composition obtained by the method of claim 1 into said articles by means of injection moulding, blow moulding, rotation moulding, compression moulding, sheet extrusion or profile extrusion.

8. The method of claim 1 wherein said colorant consists of Solvent Green 3, Solvent Green 28, Solvent Green 38, Pigment Green 50, Pigment Green 36, Solvent Red 52, Solvent Red 101, Solvent Red 111, Solvent Red 135, Solvent Red 169, Solvent Red 179, Solvent Red 207, Pigment Red 101, Disperse Red 22, Vat Red 41, Solvent Orange 60, Solvent Orange 63, Disperse Orange 47, Pigment Blue 29, Pigment Blue 60, Copper Phthalocyanine Pigment Blue 15.4, Phthalocyanine Blue BN, Pigment Blue PB 15, Pigment Yellow 53, Pigment Yellow 138, Pigment Yellow 139, Disperse Yellow 201, Solvent Yellow 33, Solvent Yellow 114, Solvent Yellow 93, Solvent Yellow 98, Solvent Yellow 163, Solvent Yellow 160:1, Solvent Yellow 188, Pigment Brown 24, Amino Ketone Black, chrome oxides, or a mixture of at least two of the foregoing colorants.

Assignees

• Sabic Global Technologies Bv

Inventors

• Janssen Pieter Jan Antoon
• Eggenhuisen Tamara Marijke
• Van Veen Abraham Johan
• Van Den Bogerd Joshua Arie

Classifications

• C08J3/22

  using masterbatch techniques · CPC title

• C08J3/203

  Solid polymers with solid and/or liquid additives · CPC title

• C08J3/223

  Packed additives · CPC title

• C08J3/20

  Compounding polymers with additives, e.g. colouring · CPC title

• B29K2995/002

  Coloured · CPC title