Compositions and method to improve the aesthetics of calcium silicate-based cements and concretes

Patent metadata

Field	Value
Publication number	US-12012362-B2
Application number	US-201816198060-A
Country	US
Kind code	B2
Filing date	Nov 21, 2018
Priority date	Nov 21, 2017
Publication date	Jun 18, 2024
Grant date	Jun 18, 2024

Abstract

Carbonatable calcium silicate-based cements and concretes are presented, which result in concrete compositions that have an improved aesthetics. A cement product includes a plurality of particles of a carbonatable calcium silicate cement and a first additive; wherein, the first additive is a hydrophobic organic acid, or a salt thereof, or a silane, or a polysiloxane.

First claim

The invention claimed is:

1. A non-hydraulic cement product comprising:
a plurality of particles of a carbonatable calcium silicate cement, the calcium silicate comprising one or more discrete calcium silicate phases selected from CS (wollastonite or pseudowollastonite), C3S2 (rankinite), C2S (belite, larnite, bredigite), and an amorphous calcium silicate phase at about 30% or more by mass of the total phases;
a first additive and a second additive;
wherein, the first additive is a hydrophobic organic acid, or a salt thereof, or a silane, or a polysiloxane, and the second additive is an organic molecule with at least one primary, secondary or tertiary amine group.

2. The non-hydraulic cement product of claim 1 , wherein the hydrophobic organic acid, or a salt thereof, is one or more fatty acid(s), or one or more salt(s) thereof.

3. The non-hydraulic cement product of claim 2 , wherein the fatty acid, or a salt thereof, is selected from the group consisting of: a valeric acid, or a salt thereof; a stearic acid, or a salt thereof; an oleic acid, or a salt thereof; an arachidic acid, or a salt thereof; a palmitic acid, or a salt thereof; an arachidonic acid, or a salt thereof; an erucic acid, or a salt thereof; a linoleic acid, or a salt thereof; a linolenic acid, or a salt thereof; a lauric acid, or a salt thereof, or a combination thereof.

4. The non-hydraulic cement product of claim 3 , wherein a salt of the fatty acid is a calcium stearate.

5. The non-hydraulic cement product of claim 1 , wherein, the second additive also comprises at least one hydroxy group.

6. The non-hydraulic cement product of claim 5 , wherein, the second additive is one or a combination of one or more hydroxyalkylamine(s) that has a maximum molar weight of 1000 g/mol.

7. The non-hydraulic cement product of claim 6 , wherein, the second additive is selected from the group consisting of N,N bis-2(2-hydroxyethyl)-2-propanolamine) (DIEPA), N,N bis-(2-hydroxypropyl)-N-(hydroxyethyl) amine (EDIPA), diethanolamine (DEA), triethanolamine (TEA), triisopropanolamine (TIPA), triethylenepentamine (TEPA), hydroxyethyldiethylenetriamine (HEDETA) and aminoethylethanolamine (AEEA) or a combination thereof.

8. The non-hydraulic cement product of claim 1 , wherein the first and second additives are calcium stearate and triethanolamine, respectively.

9. The non-hydraulic cement product of claim 8 , wherein the first additive is present in an amount of 0.1 wt % to 2.0 wt % of the amount of cement, and the second additive is present in an amount of 0.1 wt % to 2.0 wt % of the amount of cement.

10. The non-hydraulic cement product of claim 1 ,
wherein the first additive is selected from the group consisting of: a valeric acid, or a salt thereof; a stearic acid, or a salt thereof; an oleic acid, or a salt thereof; an arachidic acid, or a salt thereof; a palmitic acid, or a salt thereof; an arachidonic acid, or a salt thereof; an erucic acid, or a salt thereof; a linoleic acid, or a salt thereof; a linolenic acid, or a salt thereof, a lauric acid, or a salt thereof, or a combination thereof; and
wherein the second additive is selected from the group consisting of N,N bis-2(2-hydroxyethyl)-2-propanolamine) (DIEPA), N,N bis-(2-hydroxypropyl)-N-(hydroxyethyl) amine (EDIPA), diethanolamine (DEA), triethanolamine (TEA), triisopropanolamine (TIPA), triethylenepentamine (TEPA), hydroxyethyldiethylenetriamine (HEDETA), and aminoethylethanolamine (AEEA), or a combination thereof.

11. The non-hydraulic cement product of claim 10 , wherein the first and second additives are calcium stearate and triethanolamine, respectively.

12. The non-hydraulic cement product of claim 11 , wherein the first additive is present in an amount of 0.1 wt % to 2.0 wt % of the amount of cement, and the second additive is present in an amount of 0.1 wt % to 2.0 wt % of the amount of cement.

13. The non-hydraulic cement product of claim 10 , wherein the calcium silicate cement comprises from 30 to 55 wt % SiO 2 and 40 to 55 wt % CaO, relative to the total weight of oxides.

14. The non-hydraulic cement product of claim 13 , wherein the calcium silicate cement comprises 1 to 8 wt % Al 2 O 3 , 0.1 to 5 wt % Fe 2 O 3 , and/or 0.1 to 2.5 wt % MgO, relative to the total weight of oxides.

15. The non-hydraulic cement product of claim 14 , wherein the calcium silicate cement comprises 0.01 to 0.5 wt % Na 2 O, 0.1 to 2 wt % K 2 O; 0.01 to 0.5 wt % TiO 2 , 0.01 to 1 wt % P 2 O 5 , and/or 0.01 to 0.5 wt % Mn 2 O 3 , relative to the total weight of oxides.

16. The non-hydraulic cement product of claim 10 , wherein the first additive is present in an amount of 0.1 wt % to 2.0 wt % of the amount of cement, and the second additive is present in an amount of 0.1 wt % to 2.0 wt % of the amount of cement.

17. The non-hydraulic cement product of claim 1 , wherein the first additive is present in an amount of 0.1 wt % to 2.0 wt % of the amount of cement.

18. The non-hydraulic cement product of claim 1 , wherein the first additive is present in an amount of 0.1 wt % to 2.0 wt % of the amount of cement, and the second additive is present in an amount of 0.1 wt % to 2.0 wt % of the amount of cement.

19. The non-hydraulic cement product of claim 1 , wherein the first additive is present in an amount of 0.1 wt % to 2.0 wt % of the amount of cement.

20. A concrete product comprising:
the non-hydraulic cement product of claim 1 , wherein the cement product is cured with a greenhouse gas comprising carbon dioxide to produce a structure comprising of a core, wherein the core comprises of a portion of the unreacted calcium silicate particle;
a silica-rich layer covering at least a portion of the surface of the core; and
an exterior layer covering at least a portion of the silica-rich first layer, wherein, the exterior layer comprises calcium carbonate; and
a plurality of aggregate particles.

21. A method for preparing a concrete product comprising:
mixing the non-hydraulic cement product of claim 1 with a plurality of aggregate particles to form a concrete product having a plurality of pores;
placing and forming the concrete product in molds;
curing the formed concrete product with a greenhouse gas comprising carbon dioxide to produce a structure comprising of a core, wherein the core comprises of a portion of the unreacted carbonatable calcium silicate particle;
a silica-rich layer covering at least a portion of the surface of the core; and
an exterior layer covering at least a portion of the silica-rich first layer, wherein, the exterior layer comprises calcium carbonate.

Assignees

• Solidia Technologies Inc

Inventors

• Briaud Vincent
• Cervera Frédéric
• Meyer Vincent
• Sahu Sadananda
• Tas Ahmet Cuneyt
• Ravikumar Deepak
• Bryant Jason Elizan
• Seth Anuj

Classifications

• C04B40/0231

  Carbon dioxide hardening · CPC title

• Y02P40/18

  Carbon capture and storage [CCS] · CPC title

• C04B2111/2076

  Discolouring resistant materials · CPC title

• C04B24/42

  Organo-silicon compounds · CPC title

• C04B2111/21

  Efflorescence resistance · CPC title