High elastomeric modulus and strength polymer constructs and methods of forming

Patent metadata

Field	Value
Publication number	US-12011868-B2
Application number	US-202217944403-A
Country	US
Kind code	B2
Filing date	Sep 14, 2022
Priority date	Sep 14, 2021
Publication date	Jun 18, 2024
Grant date	Jun 18, 2024

Abstract

A method of producing high modulus and strength polymer materials includes compressive rolling a semicrystalline polymer material in at least two different axial directions of the material; and axially orienting at least a portion of the compressive rolled material to a draw ratio less than the ultimate elongation or the elongation % at break of the material.

First claim

Having described the invention, we claim:

1. A method of producing high modulus and high strength polymer materials, the method comprising:
compressive rolling a semicrystalline polymer material in at least two different axial directions of the material; and
uniaxially orienting at least a portion of the compressive rolled material such that the portion of the compressive rolled material is stretched along a single axial direction of the portion of the compressive rolled material to a draw ratio less than the ultimate elongation or the elongation % at break of the material to form a high modulus and high strength polymer rod or filament, wherein the single axial direction is along the length of the rod or filament.

2. The method of claim 1 , wherein the semicrystalline polymer material is compressive rolled at temperature between the Tg and Tm of the material.

3. The method of claim 1 , wherein the semicrystalline polymer material makes a first pass between a pair of rolls of a compressive roller to effect a reduction in thickness of the material about 1% to less than about 60%, and thereafter makes a second pass between the rolls different from the direction of the first pass to effect a further reduction in the thickness of the material about 1% to less than about 60%.

4. The method of claim 3 , wherein the distance between the pair of rolls during the first pass is about 40% to about 99% of the thickness of the material and distance between the pair of rolls during the second pass different from the direction of the first pass is about is about 40% to about 99% of the thickness the material after the first pass.

5. The method of claim 1 , wherein material is compressive rolled along a first axis of the material and along a second axis of the material different than the first axis, wherein the first axis and the second axis are in substantially the same plane.

6. The method of claim 5 , wherein the second axis is between about 5° to about 175° different than the first axis of the material.

7. The method of claim 6 , wherein the second axis is about 15° to about 90° different than the first axis of the material.

8. The method of claim 5 , wherein the single axial direction is in the same plane of the first axis and second axis.

9. The method of claim 1 , wherein the material is compressive rolled at least three or more times wherein each pass through the compressive roller is along an axis of the material that differs from the axis of the material during the previous pass through the compressive roller and wherein pass through the compressive roller reduces the thickness of the material by at least about 0.1%.

10. The method of claim 9 , wherein the material is compression rolled in alternating axial directions.

11. The method of claim 10 , wherein the distance between compressive rolls of the compressive rollers is less than about 95% of the thickness of the material during each pass through the compressive rollers.

12. The method of claim 10 , wherein the thickness of the material is larger than the roll-gap separation of the compressive roller.

13. The method of claim 1 , wherein the compressive rolled material is uniaxially oriented at a draw ratio of at least 2.

14. The method of claim 1 , wherein the compressive rolled material is uniaxially oriented above the Tg but below the Tm of the polymer material.

15. The method of claim 1 , wherein the compressive rolled material is uniaxially oriented at a strain rate of at least about 50%/min or more.

16. The method of claim 1 , wherein the uniaxially oriented material includes a plurality uniaxially aligned microfibrils and a plurality of nanofibrils linking laterally adjacent uniaxially aligned microfibrils.

17. The method of claim 16 , wherein the microfibrils have a length of about 1 μm to about 5 μm and the nanofibrils have a length less about 100 nm.

18. The method of claim 1 , wherein the semicrystalline polymer material comprises at least one of homopolymers or copolymers of polyethene or polypropylene.

19. The method of claim 1 , wherein the method and semicrystalline polymer material are solvent-free.

Assignees

• Univ Case Western Reserve

Inventors

• Baer Eric
• Olah Andrew
• Zhang Cong
• Wnek Gary
• Mcmullen Nathan
• Cheng Chung-Fu

Classifications

• B29C43/003

  characterised by the choice of material · CPC title

• C08K2201/004

  Additives being defined by their length · CPC title

• B29L2031/768

  Protective equipment (B29L2031/4821 takes precedence) · CPC title

• B29L2031/4821

  Helmets · CPC title

• B29L2031/731

  Filamentary material, i.e. comprised of a single element, e.g. filaments, strands, threads, fibres (cables B29L2031/707) · CPC title