Mineral recovery from concentrated brines

Patent metadata

Field	Value
Publication number	US-12011680-B2
Application number	US-202117478932-A
Country	US
Kind code	B2
Filing date	Sep 19, 2021
Priority date	Sep 20, 2020
Publication date	Jun 18, 2024
Grant date	Jun 18, 2024

Abstract

The present disclosure is directed to a new and improved separation process that isolates individual minerals from brines containing a mixture of minerals. The brines may be derived from seawater, brackish water, oilfield brines, solution mining, mine run-off, and other sources. Typically, the minerals are recovered as chlorides using a variety of processing steps including evaporation, centrifugation, elutriation, filtration, electrocogulation, crystallization, adsorption, and chromatography.

First claim

What is claimed is:

1. A method for separating a brine solution, the method comprising:
removing water from a brine solution to yield water and a concentrated salt solution;
crystallizing chloride salts from the concentrated salt solution; and
separating hydroxides from a portion of the concentrated salt solution by adding sodium hydroxide, converting the metal hydroxides to a soluble chloride solution, and processing the soluble chloride solution with ion exchange chromatography to separate cations from the soluble chloride solution.

2. The method of claim 1 , wherein:
the removing of water from the brine solution is performed at a source of the brine solution and the crystallizing is performed at a remote location from the source of the brine solution.

3. The method of claim 2 , wherein:
the removing of the water from the brine solution is performed at a well site and the crystalizing is performed at a processing facility that handles brines solutions from multiple well sites.

4. The method of claim 1 , further comprising:
removing sulfates and calcium from the concentrated salt solution prior to the crystallizing.

5. The method of claim 1 , further comprising:
removing carbonates from the concentrated salt solution prior to the crystallizing.

6. The method of claim 1 , wherein the removing of the water is at least partially performed using vapor compression evaporation.

7. The method of claim 6 , wherein the vapor compression evaporation has multiple stages.

8. The method of claim 1 , wherein the crystallizing chloride salts from the concentrated salt solution yields bittern in addition to the chloride salts, further comprising:
processing the bittern with ion exchange chromatography to separate cations from the bittern.

9. The method of claim 1 , wherein:
the crystallizing of the chloride salts yields sodium chloride salts at operations below 117 degrees Celsisus.

10. The method of claim 1 , wherein:
the crystallizing of the chloride salts is carried out by a plurality of crystallizers that yield sodium chloride, potassium chloride, and magnesium chloride.

11. The method of claim 10 , wherein:
the sodium chloride, potassium chloride, and magnesium chloride are yielded in different stages of the processing by the crystallizers, and the magnesium chloride is yielded in a stage of processing before a stage that yields the potassium chloride and after a stage that yields sodium chloride.

12. A method of separation of a brine solution, the method comprising:
removing water from a brine solution to yield water and a concentrated salt solution;
separating oil from either the brine solution or the concentrated salt solution;
removing salts from the concentrated salt solution; and
separating hydroxides from a portion of the concentrated salt solution by adding sodium hydroxide, converting the metal hydroxides to a soluble chloride solution, and processing the soluble chloride solution with ion exchange chromatography to separate cations from the soluble chloride solution.

13. The method of claim 12 , wherein the oil is separated using electrocoagulation.

14. The method of claim 12 , wherein the oil is separated using a physical process.

15. The method of claim 12 , wherein the oil is separated as part of a sludge solution, further comprising:
separating the oil from metal hydroxides.

16. The method of claim 15 , wherein the oil is separated by washing the sludge solution with a volatile solvent.

17. A method for separating a brine solution, the method comprising:
removing water from a brine solution to yield water and a concentrated salt solution;
crystallizing, with a plurality of crystallizers, chloride salts from the concentrated salt solution, at least two of the plurality of crystallizers yielding a principal chloride salt, the principal chloride salt from each of the at least two of the plurality of crystallizers different than the other of the at least two of the plurality of crystallizers; and
processing bittern from the crystallizers with ion exchange chromatography to separate cations from the bittern.

18. The method of claim 17 , wherein the principal chloride salts for the at least two of the plurality of crystallizers are selected from the group consisting of sodium chloride, potassium chloride, and magnesium chloride.

19. The method of claim 17 , further comprising:
removing sulfates and calcium from the concentrated salt solution prior to the crystallizing.

20. The method of claim 17 , further comprising:
removing carbonates from the concentrated salt solution prior to the crystallizing.

21. The method of claim 17 , further comprising:
separating oil from either the brine solution or the concentrated salt solution.

22. The method of claim 21 , further comprising:
separating hydroxides from either a portion of the concentrated brine solution or from a sludge when the oil is removed as part of a sludge.

23. The method of claim 17 , wherein:
the removing of water from the brine solution is performed at a source of the brine solution and the crystallizing is performed at a remote location from the source of the brine solution.

24. The method of claim 17 , wherein:
the removing of the brine solution is performed at a well site and the crystalizing is performed at a processing facility that handles brines solutions from multiple well sites.

25. The method of claim 17 , wherein:
the crystallizers yield sodium chloride, potassium chloride, and magnesium chloride separately.

26. The method of claim 25 , wherein:
the sodium chloride, potassium chloride, and magnesium chloride are yielded in different stages of the processing by the crystallizers, and the magnesium chloride is yielded in a stage of processing before a stage that yields the potassium chloride and after a stage that yields sodium chloride.

Assignees

• Texas A & M Univ Sys

Inventors

• Holtzapple Mark

Classifications

• C02F1/463

  by electrocoagulation · CPC title

• C02F2001/5218

  Crystallization · CPC title

• C02F1/041

  by means of vapour compression · CPC title

• C01D3/06

  Preparation by working up brines; seawater or spent lyes · CPC title

• C02F1/52

  by flocculation or precipitation of suspended impurities {(C02F1/463 takes precedence)} · CPC title