Fluorene derivative and organic light emitting device comprising same

Patent metadata

Field	Value
Publication number	US-12010911-B2
Application number	US-201816629304-A
Country	US
Kind code	B2
Filing date	Jul 25, 2018
Priority date	Jul 28, 2017
Publication date	Jun 11, 2024
Grant date	Jun 11, 2024

Abstract

Provided is a fluorene derivative of Chemical Formula 1:

and an organic light emitting device comprising the same.

First claim

The invention claimed is:

1. A fluorene derivative of one of Chemical Formulae 1-4 to 1-6:

wherein in Chemical Formulae 1-4 to 1-6:
Ar2 and Ar4 are hydrogen;
b and d are an integer of 5;
L1 is a direct bond, a substituted or unsubstituted arylene group, or a substituted or unsubstituted heteroarylene group, and L3 is a phenylene group, a biphenylylene group, a naphthylene group, a phenanthrene group, or a divalent fluorene group that is unsubstituted or substituted with an alkyl group having 1 to 10 carbon atoms; or
L1 is a substituted or unsubstituted arylene group or a substituted or unsubstituted heteroarylene group, and L3 is a direct bond, a phenylene group, a biphenylylene group, a naphthylene group, a phenanthrene group, or a divalent fluorene group that is unsubstituted or substituted with an alkyl group having 1 to 10 carbon atoms;
X1 to X3 are the same as or different from each other, and each independently is N or CR1;
two or more of X1 to X3 are N;
R1 is hydrogen;
R2 is hydrogen;
Y1 and Y2 are the same as or different from each other, and each independently is deuterium, a substituted or unsubstituted alkyl group, a substituted or unsubstituted silyl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted aryl group, or a substituted or unsubstituted heteroaryl group; and
n is an integer of 4.

2. The fluorene derivative of claim 1 , wherein Y1 and Y2 each independently is an aryl group having 6 to 20 carbon atoms or a pyrimidine group that is unsubstituted or substituted with an aryl group having 6 to 20 carbon atoms.

3. The fluorene derivative of claim 1 , wherein the compound of Chemical Formulae 1-4 to 1-6 is any one of the following compounds:

4. An organic light emitting device comprising:
a first electrode;
a second electrode provided opposite to the first electrode; and
one, two or more organic material layers provided between the first electrode and the second electrode,
wherein one or more layers of the organic material layers include the fluorene derivative of claim 1 .

5. The organic light emitting device of claim 4 , wherein the organic material layer includes a light emitting layer, and the light emitting layer includes the fluorene derivative.

6. The organic light emitting device of claim 4 , wherein the organic material layer includes a hole injection layer or a hole transfer layer, and the hole injection layer or the hole transfer layer includes the fluorene derivative.

7. The organic light emitting device of claim 4 , wherein the organic material layer includes an electron injection layer, an electron transfer layer, or an electron injection and transfer layer, and the electron injection layer, the electron transfer layer, or the electron injection and transfer layer includes the fluorene derivative.

8. The organic light emitting device of claim 4 , wherein the organic material layer includes an electron control layer, and the electron control layer includes the fluorene derivative.

Assignees

• Lg Chemical Ltd

Inventors

• Han Miyeon
• Lee Dong Hoon
• Huh Jungoh
• Jang Boonjae
• Heo Dong Uk
• Yang Junghoon
• Yun Heekyung

Classifications

• H10K50/16

  Electron transporting layers · CPC title

• H10K50/171

  Electron injection layers · CPC title

• H10K85/654 Primary

  comprising only nitrogen as heteroatom (H10K85/652 takes precedence) · CPC title

• C07D401/10 Primary

  linked by a carbon chain containing aromatic rings · CPC title

• H10K50/17

  Carrier injection layers · CPC title