Electroactive particles having electronically conductive coatings

Patent metadata

Field	Value
Publication number	US-12009503-B2
Application number	US-202017039034-A
Country	US
Kind code	B2
Filing date	Sep 30, 2020
Priority date	Sep 30, 2020
Publication date	Jun 11, 2024
Grant date	Jun 11, 2024

Abstract

The present disclosure relates to a negative electrode material and methods of preparation and use relating thereto. The electrode material comprises a plurality of electroactive material particles, where each electroactive material particle includes an electroactive material core and an electronically conductive coating. The method includes contacting an electroactive material precursor including a plurality of electroactive material particles with a solution so as to form an electronically conductive coating on each of the electroactive material particles. The solution includes a solvent and one or more of copper fluoride (CuF2), titanium tetrafluoride (TiF3 or TiF4), iron fluoride (FeF3), nickel fluoride (NiF2), manganese fluoride (MnF2, MnF3, or MnF4), and vanadium fluoride (VF3, VF4, VF5). The electronically conductive coating includes a plurality of first regions and a plurality of second regions. The plurality of first regions include lithium fluoride. The plurality of second regions include one of copper, titanium, iron, nickel, manganese, and vanadium.

First claim

What is claimed is:

1. A method for preparing an electrode material for use in an electrochemical cell, the method comprising:
contacting an electroactive material precursor comprising a plurality of electroactive material particles with a solution so as to form an electronically conductive coating on each of the electroactive material particles,
the coated electroactive material particles defining the electrode material,
at least a portion of the plurality of electroactive material particles comprising a prelithiated electroactive material represented by Li x Si where 0<x≤3.75,
the solution comprising a solvent and one or more of copper fluoride (CuF 2 ), titanium tetrafluoride (TiF 4 ), titanium trifluoride (TiF 3 ), iron fluoride (FeF 3 ), nickel fluoride (NiF 2 ), manganese fluoride (MnF 2 , MnF 3 , or MnF 4 ), vanadium fluoride (VF 3 , VF 4 , VF 5 ), and combinations thereof,
the electronically conductive coating comprising a plurality of first regions and a plurality of second regions,
the plurality of first regions comprising lithium fluoride, and
the plurality of second regions comprising one of copper, titanium, iron, nickel, manganese, and vanadium.

2. The method of claim 1 , wherein the method further comprises prelithiating the electroactive material precursor.

3. The method of claim 2 , wherein the electroactive material precursor is prelithiated using a thermal evaporation process.

4. The method of claim 1 , wherein the solvent is selected from the group consisting of: dimethyl ether, hexane, toluene, and combinations thereof.

5. The method of claim 1 , wherein contacting occurs using one of a spray process and a dip process.

6. The method of claim 1 , wherein the method further comprises drying the coated electroactive material particles so as to remove the solvent.

7. The method of claim 1 , wherein the method further comprises applying a vacuum infiltration process so as to surround the electroactive material precursor with the solution.

8. The method of claim 1 , wherein the electronically conductive coating is a result of a conversion reaction between the solution and the electroactive material particles.

9. The method of claim 8 , wherein the solution comprises copper fluoride (CuF 2 ), and the conversion reaction is defined as:
y (CuF 2 )+Li x Si→2 y (LiF)+Li (x-2y) Si+ y Cu

where x>2y.

10. A method for preparing an electrode material for use in an electrochemical cell, the method comprising:
prelithiating a silicon-containing electroactive material precursor so as to form a prelithiated silicon-containing electroactive material represented by Li x Si where 0<x≤3.75, and
contacting the prelithiated silicon-containing electroactive material with a solution comprising a solvent and one or more of copper fluoride (CuF 2 ), titanium tetrafluoride (TiF 4 ), titanium trifluoride (TiF 3 ), iron fluoride (FeF 3 ), nickel fluoride (NiF 2 ), manganese fluoride (MnF 2 , MnF 3 , or MnF 4 ), and vanadium fluoride (VF 3 , VF 4 , VF 5 ) so as to form an electronically conductive coating on the prelithiated silicon-containing electroactive material so as to form a coated prelithiated electroactive material that defines the electrode material, the electronically conductive coating including a plurality of first regions and a plurality of second regions, the plurality of first regions comprising lithium fluoride and the plurality of second regions comprising one of copper, titanium, iron, nickel, manganese, and vanadium.

11. The method of claim 10 , wherein the method further comprises drying the coated prelithiated electroactive material so as to remove the solvent.

12. The method of claim 10 , wherein the method further comprises applying a vacuum infiltration process so as to surround the prelithiated silicon-containing electroactive material with the solution.

13. The method of claim 10 , wherein the solvent is selected from the group consisting of: dimethyl ether, hexane, toluene, and combinations thereof.

14. The method of claim 10 , wherein the electronically conductive coating is a result of a conversion reaction between the solution and the prelithiated silicon-containing electroactive material.

15. The method of claim 14 , wherein the solution comprises copper fluoride (CuF 2 ), and the conversion reaction is defined as:
y (CuF 2 )+Li x Si→2 y (LiF)+Li (x-2y) Si+ y Cu

where x>2y.

Assignees

• Gm Global Tech Operations Llc

Inventors

• Verbrugge Mark W
• Xiao Xingcheng
• Zhang Qinglin
• Yang Xingyi
• K Raghunathan

Classifications

• H01M4/134

  Electrodes based on metals, Si or alloys · CPC title

• H01M4/0452

  from solutions · CPC title

• Y02P70/50

  Manufacturing or production processes characterised by the final manufactured product · CPC title

• Y02E60/10

  Energy storage using batteries · CPC title

• H01M4/0471

  involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis · CPC title