All-solid-state battery including a solid electrolyte and methods of making thereof

Patent metadata

Field	Value
Publication number	US-12009475-B2
Application number	US-202017095483-A
Country	US
Kind code	B2
Filing date	Nov 11, 2020
Priority date	Nov 18, 2019
Publication date	Jun 11, 2024
Grant date	Jun 11, 2024

Abstract

This disclosure provides systems, methods, and apparatus related to an all-solid-state battery including a solid electrolyte. In one aspect, a device includes a first layer of an ionically conducting oxide, a second layer of the ionically conducting oxide disposed on the first layer, and an anode disposed on the second layer of the ionically conducting oxide. The first layer defines through pores having a tortuosity of about 1. The first layer includes transition metal oxide particles and an ionically conducting solid disposed in the through pores. The transition metal oxide particles are a cathode. The first layer and the ionically conducting solid are an electrolyte. The second layer does not define any through pores. The second layer is a separator.

First claim

What is claimed is:

1. A battery comprising:
an anode layer;
a separator portion comprising an ionically conducting oxide material disposed on the anode layer;
a solid electrolyte portion comprising said ionically conducting oxide material and an ionically conducting solid material comprising a plastic-crystal comprising an organic compound and a lithium salt disposed on the separator, said ionically conducting oxide material being different than the ionically conducting solid material, said ionically conducting oxide material having pores having a tortuosity of about 1 and the ionically conducting solid material being disposed in said pores; and
a cathode comprising lithium transition metal oxide particles disposed in the ionically conducting oxide material.

2. The battery of claim 1 , wherein the anode layer comprises lithium or sodium.

3. The battery of claim 1 , further comprising:
a first current collector disposed on the solid electrolyte portion opposite the separator portion; and
a second current collector disposed on the anode layer opposite the separator portion.

4. The battery of claim 1 , wherein the lithium transition metal oxide particles are selected from a group consisting of LiNi x Mn y Co z O 2 (0≤x≤1, 0≤y≤1, 0≤z≤1, x+y+z=1), LiMn 2 O 4 and variants, LiMn 1.5 Ni 0.5 O 4 and variants, and combinations thereof.

5. The battery of claim 1 , wherein the solid electrolyte portion further comprises an electron conducting material disposed in the ionically conducting solid material or directly on the lithium transition metal oxide particles.

6. The battery of claim 5 , wherein the electron conducting material is selected from a group consisting of carbon black particles, carbon nanotubes, carbon nanofibers, and a conductive polymer.

7. The battery of claim 1 , wherein the solid electrolyte portion is about 50 μm to 500 μm thick.

8. The battery of claim 1 , wherein the separator portion is about 5 μm to 40 μm thick.

9. The battery of claim 1 , wherein a volume percent of the lithium transition metal oxide particles is about 50% to 80%.

10. The battery of claim 1 , wherein the lithium salt is selected from a group consisting of lithium perchlorate (LiClO 4 ), lithium bis(trifluoromethanesulfonyl)imide (LiTFSI), lithium bis(fluorosulfonyl)imide (LiFSI), lithium difluoro(oxalate)borate (LiDFOB), lithium bis(oxalato)borate (LiBOB), lithium tetrafluoroborate (LiBF 4 ), lithium hexafluorophosphate (LiPF 6 ), and combinations thereof.

11. The battery of claim 1 , wherein the organic compound is selected from a group consisting of alkylmethylpyrrolidinium imide, N-ethyl-N-methylpyrrolidinium tetrafluoroborate, N,N-dimethylethylenediamine, 2-methylimidazolium triflate, 2-methylimidazolinium triflate, N-ethyl-N-methylpyrrolidinium bis(fluorosulfonyl)amide, N-ethyl-N-methylpyrrolidinium bis(fluorosulfonyl)imide, succinonitrile, ethyl methylpyrrolidinium bis(trifluoromethanesulfonyl)amide, triisobutyl(methyl)phosphonium bis(fluorosulfonyl)imide, N,N-diethyl-N-methyl-N-(n-propyl)ammonium trifluoromethyltrifluoroborate, N,N′-diethyl-3-methylpyrazolium bis-(trifluoromethanesulfonyl)imide, pyrazolium imide, N-methyl-N-ethylpyrrolidinium bis(trifluoromethanesulfonyl)amide, and combinations thereof.

12. The battery of claim 1 , wherein the ionically conducting oxide material comprises Li 7 La 3 Zr 2 O 12 and derivatives.

13. The battery of claim 1 , wherein the battery does not include a liquid.

Assignees

• Univ California
• Univ Montana State

Inventors

• Yi Eongyu
• Doeff Marca
• Chen Guoying
• Sofie Stephen

Classifications

• H01M4/5825

  Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines · CPC title

• H01M4/62

  Selection of inactive substances as ingredients for active masses, e.g. binders, fillers · CPC title

• H01M4/625

  Carbon or graphite · CPC title

• H01M2300/0068

  inorganic · CPC title

• H01M2300/0094

  in the form of layered products, e.g. coatings · CPC title