Article with microstructured layer
US-11407196-B2 · Aug 9, 2022 · US
US12006692B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-12006692-B2 |
| Application number | US-202318192567-A |
| Country | US |
| Kind code | B2 |
| Filing date | Mar 29, 2023 |
| Priority date | Mar 25, 2016 |
| Publication date | Jun 11, 2024 |
| Grant date | Jun 11, 2024 |
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A roof system comprising a roof substrate, a first membrane including first and second opposed planar surfaces, and a second membrane including opposed first and second planar surfaces, where said second membrane is adhered to said roof substrate through an adhesive disposed on said roof-substrate contacting portion of the first membrane, and where said second membrane is adhered to said first membrane through said adhesive disposed on a lap portion of said second membrane.
Opening claim text (preview).
What is claimed is: 1. A roofing membrane composite comprising: (i) a roofing membrane panel having opposed first and second planar surfaces and first and second lateral edges, said first planar surface including a roof-substrate contacting portion and a lap portion adjacent to one of said first and second lateral edges; (ii) a layer of UV-cured pressure-sensitive adhesive disposed on said roof-substrate contacting portion and said lap portion, where the layer of UV-cured pressure-sensitive adhesive is disposed on the entirety of the roof-substrate contacting portion from the first lateral edge to the second lateral edge, the UV-cured pressure-sensitive adhesive including a UV-cured polyacrylate having a gel content, as determined by THF extraction after boiling in THF after four hours, of at least 50% by weight, and where the polyacrylate, prior to UV curing, has a Tg of less than −20° C. and a number average molecular weight of from about 100 to about 350 kg/mol, and where the degree of cure of said UV-cured pressure-sensitive adhesive varies by no more than 10% between said roof-substrate contacting portion and said lap portion; and (iii) a release member removable affixed to said UV-cured adhesive in both said roof-substrate contacting portion and said lap portion, where said UV-cured adhesive disposed on said roof-substrate portion and said lap portion is substantially homogeneous. 2. The membrane of claim 1 , where said release member includes a perforation that allows said release member to be divided between said roof-substrate contacting portion and said lap portion. 3. The membrane of claim 1 , where the degree of cure of said UV-cured adhesive varies by no more than 1% between said roof-substrate contacting portion and said lap portion. 4. The membrane of claim 1 , where the UV-cured adhesive is a UV-cured polyacrylate, and where said UV-cured polyacrylate, prior to being cured, includes one or more units defined by the formula: where each R 1 is individually hydrogen or a hydrocarbyl group and each R 2 is individually a hydrocarbyl group. 5. The method of claim 1 , where the layer of UV-cured pressure-sensitive adhesive includes a UV-cured polyacrylate having a gel content, as determined by THF extraction after boiling in THF after four hours, of at least 60% by weight. 6. The method of claim 1 , where the layer of UV-cured pressure-sensitive adhesive includes a UV-cured polyacrylate having a gel content, as determined by THF extraction after boiling in THF after four hours, of from about 50% to about 90%. 7. The method of claim 1 , where the layer of UV-cured pressure-sensitive adhesive includes a UV-cured polyacrylate having a gel content, as determined by THF extraction after boiling in THF after four hours, of from about 60% to about 80%. 8. The method of claim 1 , where the layer of UV-cured pressure-sensitive adhesive is characterized by a peel strength when adhered to the adjacent membrane, as determined by ASTM D-1876-08, of at least 3.6 lbf/in. 9. The method of claim 1 , where the layer of UV-cured pressure-sensitive adhesive is characterized by a peel strength when adhered to the adjacent membrane, as determined by ASTM D-1876-08, of at least 8.0 lbf/in. 10. The method of claim 1 , where the layer of UV-cured pressure-sensitive adhesive is characterized by a peel strength when adhered to the adjacent membrane, as determined by ASTM D-1876-08, of at least 15 lbf/in. 11. The method of claim 1 , where the roofing membrane panel is a thermoplastic membrane panel. 12. The method of claim 1 , where the roofing membrane panel is an EPDM membrane panel.
Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers · CPC title
for building applications e.g. wrap foil · CPC title
of natural rubber or synthetic rubber · CPC title
Non-woven fabric · CPC title
comprising polyesters · CPC title
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