Method for processing liquefied waste polymers

Patent metadata

Field	Value
Publication number	US-12006480-B2
Application number	US-202118259794-A
Country	US
Kind code	B2
Filing date	Oct 29, 2021
Priority date	Dec 30, 2020
Publication date	Jun 11, 2024
Grant date	Jun 11, 2024

Abstract

The present disclosure relates to methods for processing liquefied waste polymers (LWP) containing diolefins. The LWP feed is supplied to steam stripper A to provide a distillate containing diolefins and naphtha, and a distillate bottom. The distillate is subjected to hydrotreatment B to produce a diolefin depleted distillate which is separated by distillation C to give rise to one or more fractions comprising at least a naphtha fraction, an optional middle fraction and a bottom fraction. Hydroprocessing D of the naphtha fraction gives rise to hydrogenated naphtha which is suitable as a feed for a steam cracker E. Since the distillation bottom, bottom fraction and the middle distillate are predominantly free from diolefins, they can be mixed with crude oil and processed further in oil refinery.

First claim

What is claimed is:

1. A method for processing liquefied waste plastic (LWP), the method comprising the following steps:
a) providing an LWP stream containing diolefins and naphtha;
b) subjecting the LWP stream to a steam stripper to obtain a distillate containing diolefins and naphtha, and a distillate bottom;
c) subjecting the distillate to hydrotreatment reaction conditions in a presence of hydrogen and one or more hydrotreatment catalysts to produce diolefin depleted distillate, wherein the hydrotreatment reaction conditions include a temperature of 120-210° C., a pressure of 1-50 barg, and a liquid hourly space velocity (LHSV) of 1-5 h −1 , and the one or more hydrotreatment catalysts are selected from CoMo and NiMo;
d) separating the diolefin depleted distillate to:
one or more fractions including:
at least a naphtha fraction with a boiling point below 180° C. at atmospheric pressure,
an optional middle fraction with a boiling point between 180° C. and 360° C. at atmospheric pressure; and

a bottom fraction; and

e) subjecting the naphtha fraction of step d) to hydroprocessing reaction conditions in a presence of hydrogen and one or more hydroprocessing catalysts to produce hydrogenated naphtha.

2. The method according to claim 1 , wherein the hydroprocessing reaction conditions of step e) comprise:
a temperature of 280-350° C., and a pressure of 20-100 barg.

3. The method according to claim 2 , wherein the hydrotreatment reaction conditions comprise:
a LHSV of 1-5 h −1 , and a hydrogen/hydrocarbon ratio of 100-900 Nm 3 /m 3 .

4. The method according to claim 1 , wherein the one or more hydroprocessing catalysts are selected from CoMo and NiMo.

5. The method according to claim 1 , comprising:
feeding the hydrogenated naphtha to a steam cracker.

6. The method according to claim 1 , comprising:
admixing the bottom fraction of step d) and crude oil to form an admixture.

7. The method according to claim 6 , comprising:
feeding the admixture to a crude oil distillation unit.

8. The method according to claim 1 , wherein the one or more fractions of step d) comprise
a middle fraction with a boiling point between 180° C. and 360° C. at atmospheric pressure.

9. The method according to claim 8 , comprising:
feeding the middle fraction to a crude oil distillation unit.

10. The method according to claim 1 , wherein the LWP is selected from waste plastic pyrolysis oil, hydrothermally liquefied waste plastic oil or mixtures thereof.

11. The method according to claim 1 , wherein the LWP comprises:
waste plastic pyrolysis oil.

12. The method according to claim 1 , comprising:
feeding a mixture of crude oil and the bottom fraction of step d) to an oil refinery feed.

13. The method according to claim 1 , comprising:
feeding a mixture of crude oil and the middle fraction of step d) to an oil refinery.

14. The method according to claim 1 , comprising:
feeding a mixture of crude oil and distillation bottom of step b) to an oil refinery.

Assignees

• Neste Oyj

Inventors

• Aalto Pekka
• Aaltonen Heikki
• Ojala Antti
• Pérez Nebreda Andrea
• Sairanen Emma
• Paasikallio Ville
• Kurkijärvi Antti

Classifications

• C10G2300/1003

  Waste materials · CPC title

• C10G69/02 Primary

  plural serial stages only · CPC title

• C10G65/02

  plural serial stages only · CPC title

• C10G1/10

  from rubber or rubber waste · CPC title

• C10G1/002 Primary

  in combination with oil conversion- or refining processes · CPC title