Modified vegetable oil as fluid loss control additive

Patent metadata

Field	Value
Publication number	US-12006468-B2
Application number	US-202318167304-A
Country	US
Kind code	B2
Filing date	Feb 10, 2023
Priority date	May 5, 2022
Publication date	Jun 11, 2024
Grant date	Jun 11, 2024

Abstract

Invert emulsions can be used in oil and gas operations. A fluid loss control additive (FLCA) is a component of the fluid that can be utilized to control or minimize fluid loss into a subterranean formation. The FLCA can be a chemically modified vegetable oil that is biodegradable. Vegetable oils having some or all of the functional groups sulfonated can be used as FLCA. A water-soluble salt that has been dissolved in the discontinuous phase of the invert emulsion can combine with the FLCA to form a wax-like, solid mass.

First claim

What is claimed is:

1. A treatment fluid comprising:
a continuous phase comprising a hydrocarbon liquid;
a discontinuous phase comprising water and a water-soluble salt; and
a fluid loss control additive, wherein the fluid loss control additive is a water-insoluble vegetable oil, wherein one or more functional groups of the vegetable oil are chemically modified to form a chemically modified vegetable oil, and wherein the fluid loss control additive comprises Turkey red oil,
wherein the treatment fluid has a high-pressure, high-temperature fluid loss less than 15 milliliters per 30 minutes at a testing temperature in the range of 93.3° C. to 176.7° C. and a testing pressure of 500 psi (3.45 MPa), and wherein the treatment fluid has a water phase salinity in the range of 100,000 to 400,000 parts per million.

2. The treatment fluid according to claim 1 , wherein the hydrocarbon liquid is selected from the group consisting of a fractional distillate of crude oil; a fatty derivative of an acid, an ester, an ether, an alcohol, an amine, an amide, or an imide; a saturated hydrocarbon; an unsaturated hydrocarbon; a branched hydrocarbon; a cyclic hydrocarbon; and any combination thereof.

3. The treatment fluid according to claim 1 , wherein the water is selected from the group consisting of freshwater, seawater, brine, and any combination thereof in any proportion.

4. The treatment fluid according to claim 1 , wherein the water-soluble salt is a monovalent salt or divalent salt selected from the group consisting of sodium chloride, calcium chloride, calcium bromide, potassium chloride, potassium bromide, magnesium chloride, sodium formate, potassium formate, cesium formate, zinc bromide, and any combination thereof.

5. The treatment fluid according to claim 1 , wherein the treatment fluid is an (Original) invert emulsion having an oil-to-water ratio in the range of 60:40 to 90:10.

6. The treatment fluid according to claim 1 , wherein the vegetable oil is castor oil.

7. The treatment fluid according to claim 1 , wherein the fluid loss control additive is biodegradable.

8. The treatment fluid according to claim 1 , wherein chemical modification is sulfonation of the one or more functional groups of the vegetable oil.

9. The treatment fluid according to claim 1 , wherein the fluid loss control additive is in a concentration in the range of 0.2 to 10 pounds per barrel (0.8 to 38.7 kilograms per cubic meter) of the base fluid.

10. The treatment fluid according to claim 1 , wherein the fluid loss control additive is configured to react with the water-soluble salt to form a wax-like complex.

11. The treatment fluid according to claim 10 , wherein the chemically modified vegetable oil contains fatty acid functional groups configured to react with the water-soluble salt to form the wax-like complex.

12. The treatment fluid according to claim 1 , wherein a test treatment fluid provides a filtrate reduction compared to a control test fluid in the range of 40% to 100%.

13. The treatment fluid according to claim 1 , wherein the treatment fluid has a plastic viscosity in the range of 10 to 90 centipoise at a temperature of 120° F. (48.9° C.).

14. The treatment fluid according to claim 1 , wherein the treatment fluid has a yield point in the range of 2 to 30 lb/100 ft 2 (0.96 to 14.36 Pascals) at a temperature of 120° F. (48.9° C.).

15. A method of treating a portion of a subterranean formation comprising:
introducing a treatment fluid into a wellbore that penetrates the subterranean formation,
the treatment fluid comprising:
a continuous phase comprising a hydrocarbon liquid;
a discontinuous phase comprising water and a water-soluble salt; and
a fluid loss control additive, wherein the fluid loss control additive is a water-insoluble vegetable oil, and wherein one or more functional groups of the vegetable oil are chemically modified to form a chemically modified vegetable oil, and wherein the fluid loss control additive comprises Turkey red oil, wherein the treatment fluid has a high-pressure, high-temperature fluid loss less than 15 milliliters per 30 minutes at a testing temperature in the range of 93.3° C. to 176.7° C. and a testing pressure of 500 psi (3.45 MPa), and wherein the treatment fluid has a water phase salinity in the range of 100,000 to 400,000 parts per million; and

causing or allowing the fluid loss control additive to reduce fluid loss of the continuous phase and the discontinuous phase of the treatment fluid into the subterranean formation.

16. The method according to claim 15 , wherein the fluid loss control additive is configured to react with the water-soluble salt to form a wax-like complex.

17. The method according to claim 16 , wherein the wellbore has a bottomhole temperature less than a melting point of the wax-like complex.

18. The method according to claim 15 , wherein less than 40% of the continuous phase and the discontinuous phase of the treatment fluid by volume is lost through permeable areas of the subterranean formation.

19. The method according to claim 15 , wherein the fluid loss control additive is in a concentration in the range of 0.2 to 10 pounds per barrel (0.8 to 38.7 kilograms per cubic meter) of the base fluid.

20. The method according to claim 15 , wherein the fluid loss control additive is biodegradable.

Assignees

• Halliburton Energy Services Inc

Inventors

• Gotmukle Sharad Bhimrao
• Gupta Nivika Rajendra
• Miller Jeffrey J

Classifications

• E21B21/003

  Means for stopping loss of drilling fluid (plastering the borehole wall E21B33/138) · CPC title

• E21B33/138

  Plastering the borehole wall; Injecting into the formation · CPC title

• C09K8/506

  containing organic compounds · CPC title

• C09K8/502 Primary

  Oil-based compositions · CPC title

• C09K8/36 Primary

  Water-in-oil emulsions · CPC title