Method for transesterification of carboxylic acid esters

Patent metadata

Field	Value
Publication number	US-12006286-B2
Application number	US-201916981858-A
Country	US
Kind code	B2
Filing date	Mar 19, 2019
Priority date	Mar 23, 2018
Publication date	Jun 11, 2024
Grant date	Jun 11, 2024

Abstract

The present invention relates to a method for transesterification of carboxylic acid esters by heterogeneous catalysis using a catalyst that is obtainable by calcination of surface-reacted calcium carbonate. The invention further relates to the use of said method in the production of fuel or fuel components, such as biodiesel. Further aspects of the present invention relate to the transesterified ester obtainable by the inventive method and to its use as fuel or as fuel component. Still another aspect of the present invention relates to a corresponding transesterification catalyst and to its use in transesterification reactions.

First claim

The invention claimed is:

1. A transesterification catalyst comprising partially or fully calcined surface-reacted calcium carbonate, wherein the calcination is carried out at a calcination temperature of at least 650° C.,
wherein the transesterification catalyst has a specific surface area of from 15 to 200 m 2 /g, measured using nitrogen and the BET method according to ISO 9277:2010, and
wherein the surface-reacted calcium carbonate is a reaction product of ground natural calcium carbonate containing mineral (GNCC) or precipitated calcium carbonate (PCC) with carbon dioxide and one or more H 3 O + ion donors and wherein the carbon dioxide is formed in situ by a reaction with the H 3 O + ion donors and/or is supplied from an external source, and
wherein the surface-reacted calcium carbonate has a specific surface area of from 15 to 200 m 2 /g, measured using nitrogen and the BET method according to ISO 9277:2010.

2. The transesterification catalyst according to claim 1 , characterized in that the transesterification catalyst has:
(i) a d 50 (vol) of from 1 to 75 μm; and/or
(ii) a d 98 (vol) of from 2 to 150 μm.

3. The transesterification catalyst according to claim 1 , characterized in that the transesterification catalyst has:
(i) a d 50 (vol) of from 3 to 15 μm; and/or
(ii) a d 98 (vol) of 10 to 30 μm.

4. The transesterification catalyst according to claim 1 , characterized in that the transesterification catalyst has a specific surface area of from 25 to 180 m 2 /g, measured using nitrogen and the BET method according to ISO 9277:2010.

5. The transesterification catalyst according to claim 1 , characterized in that the transesterification catalyst has a specific surface area of from 30 to 150 m 2 /g, measured using nitrogen and the BET method according to ISO 9277:2010.

6. A method for transesterification of carboxylic acid esters by heterogeneous catalysis, the method comprising the following steps:
(a) providing a substrate comprising a first carboxylic acid ester;
(b) providing a first alcohol;
(c) providing a catalyst according to claim 1 ; and
(d) reacting the substrate provided in step (a) and the first alcohol provided in step (b) in the presence of the catalyst provided in step (c) to obtain a reaction mixture comprising a second carboxylic acid ester and a second alcohol.

7. The method according to claim 6 , characterized in that the substrate is a fat or a fatty oil.

8. The method according to claim 6 , characterized in that the first carboxylic acid ester is a triglyceride.

9. The method according to claim 6 , characterized in that the first alcohol is a monohydric alcohol.

10. The method according to claim 6 , characterized in that the surface-reacted calcium carbonate has:
(i) a d 50 (vol) of from 0.5 to 50 μm; and/or
(ii) a d 98 (vol) of from 1 to 120 μm.

11. The method according to claim 6 , characterized in that the surface-reacted calcium carbonate has a specific surface area of from 25 to 180 m 2 /g, measured using nitrogen and the BET method according to ISO 9277:2010.

12. The method according to claim 6 , characterized in that:
(i) the ground natural calcium carbonate-containing mineral is selected from the group consisting of marble, chalk, dolomite, limestone and mixtures thereof; and/or
(ii) the precipitated calcium carbonate comprises aragonitic, vateritic or calcitic mineralogical crystal forms or mixtures thereof.

13. The method according to claim 6 , characterized in that the catalyst is obtainable by calcination of surface-reacted calcium carbonate, wherein calcination is carried out:
(i) at a calcination temperature of at least 680; ° C., and/or
(ii) at a calcination time of at least 5 mins.

14. The method according to claim 6 , characterized in that in step (d):
the first alcohol is used as reaction medium; and/or
the catalyst is used in an amount of from 0.01 to 20 wt. %, based on a total weight of the substrate; and/or
the alcohol and the catalyst are contacted in a first step and the substrate is then added in a second step.

15. The method according to claim 6 , characterized in that step (d) is carried out at a temperature of at least 20° C.

16. The method according to claim 6 , characterized in that the method further comprises step (e) of separating the second carboxylic acid ester from the reaction mixture obtained in step (d).

17. The method according to claim 6 , characterized in that the substrate is a vegetable oil.

18. A method of producing fuel or a fuel component, comprising:
(a) providing a substrate comprising a first carboxylic acid ester;
(b) providing a first alcohol;
(c) providing a catalyst according to claim 1 ; and
(d) reacting the substrate provided in step (a) and the first alcohol provided in step (b) in the presence of the catalyst provided in step (c) to obtain a reaction mixture comprising a second carboxylic acid ester and a second alcohol;
wherein the second carboxylic acid ester is the fuel or fuel component.

Assignees

• Omya Int Ag

Inventors

• Ftouni Jamal
• Welker Matthias
• Rentsch Samuel

Classifications

• Y02E50/10

  Biofuels, e.g. bio-diesel · CPC title

• B01J2235/30

  Scanning electron microscopy; Transmission electron microscopy · CPC title

• B01J2235/15

  X-ray diffraction · CPC title

• B01J2235/05

  Nuclear magnetic resonance [NMR] · CPC title

• C01P2006/16

  Pore diameter · CPC title