Method of manufacturing catalyst slurry for fuel cells and method of manufacturing electrode for fuel cells using the same

Patent metadata

Field	Value
Publication number	US-12002968-B2
Application number	US-202016901479-A
Country	US
Kind code	B2
Filing date	Jun 15, 2020
Priority date	Dec 10, 2019
Publication date	Jun 4, 2024
Grant date	Jun 4, 2024

Abstract

The present disclosure relates to a method of manufacturing catalyst slurry for fuel cells capable of greatly improving efficiency in use of catalyst metal and a method of manufacturing an electrode for fuel cells using the catalyst slurry manufactured using the method. Specifically, the method of manufacturing catalyst slurry for fuel cells includes preparing a catalyst including a porous carrier and catalyst metal, introducing the catalyst, a solvent, and an ionomer into a chamber, and infiltrating the ionomer into pores of the carrier.

First claim

The invention claimed is:

1. A method of manufacturing catalyst slurry for fuel cells, the method comprising:
preparing a catalyst comprising a porous carrier and catalyst metal;
introducing the catalyst, a solvent, and an ionomer into a chamber; and
infiltrating the ionomer into pores of the carrier;
wherein the carrier comprises pores depressed inward from an outer surface of the carrier, the pores comprising a plurality of pore inlets each having an average diameter of 5 nm to 30 nm;
wherein the ionomer comprises a polymer having a radius of gyration of a polymer chain of 5 nm or less;
wherein the infiltrating of the ionomer into pores of the carrier comprises stirring contents of the chamber while applying heat and pressure thereto;
wherein a temperature of the contents of the chamber is increased to 25° C. to 80° C.; and
wherein the pressure applied to the contents of the chamber is 2 bar to 200 bar.

2. The method according to claim 1 , wherein the carrier comprises one selected from a group consisting of graphite, active carbon, carbon black, carbon nanotube, carbon nanofiber, carbon nanowire, and a combination thereof.

3. The method according to claim 1 , wherein the catalyst metal comprises:
platinum (Pt); or
at least one or an alloy of two or more selected from a group of platinum (Pt), iridium (Ir), ruthenium (Ru), palladium (Pd), nickel (Ni), cobalt (Co), and yttrium (Y).

4. The method according to claim 1 , wherein the catalyst is introduced into the chamber, negative pressure is applied to the chamber, and the solvent and the ionomer are introduced into the chamber together with inert gas.

5. The method according to claim 1 , wherein the solvent comprises one selected from a group consisting of distilled water, ethanol, propanol, butanol, ethylene glycol, and a combination thereof.

6. The method according to claim 1 , wherein the ionomer comprises:
a fluorine-based resin comprising a single polymer, a cross-linking polymer, a graft polymer, a copolymer, or a blend of one or more selected from a group consisting of perfluorosulfonic acid and perfluorocarboxylic acid;
a non-fluorine-based resin comprising a single polymer, a cross-linking polymer, a graft polymer, a copolymer, or a blend of one or more selected from a group consisting of polyarylene ether, polyether ketone, polyether ether ketone, polyether sulfone, polyether ether sulfone, polyazole, polyvinyl alcohol, polyphenylene oxide, polyphenylene sulfide, polysulfone, polycarbonate, polystyrene, polyimide, polyamide, polyquinoxaline, and polybenzimidazole; and
a combination thereof.

7. The method according to claim 1 , wherein inert gas is introduced into the chamber in order to apply the pressure to the contents of the chamber.

8. The method according to claim 1 , wherein the contents of the chamber are stirred for 24 hours to 48 hours.

9. The method according to claim 1 , wherein the catalyst metal is coupled to an outer surface of the carrier and to an inner surface of each of the pores, and
the ionomer is infiltrated into the pores of the carrier and contacts catalyst metal coupled to the inner surface of each of the pores of the carrier.

10. A method of manufacturing an electrode for fuel cells comprising coating the catalyst slurry manufactured using the method according to claim 1 on a substrate to manufacture the electrode.

11. The method according to claim 10 , wherein the substrate is release paper comprising one selected from a group consisting of polyethylene naphthalate (PEN), polyethylene terephthalate (PET), polytetrafluoroethylene (PTFE), and a combination thereof.

12. The method according to claim 10 , wherein the catalyst slurry is coated using a screen printing method, a spray coating method, a coating method using a doctor blade, a gravure coating method, a deep coating method, a silk screen method, a painting method, or a coating method using a slot die.

13. The method according to claim 10 , further comprising drying the electrode at 100° C. to 200° C. for 5 minutes to 24 hours.

Assignees

• Hyundai Motor Co Ltd
• Kia Motors Corp

Inventors

• Cho Yoon Hwan
• Han Kook Il
• Seol Su Won

Classifications

• H01M4/926 Primary

  on carbon or graphite · CPC title

• H01M4/8647 Primary

  consisting of more than one material, e.g. consisting of composites · CPC title

• H01M4/8668

  Binders · CPC title

• H01M4/8814

  Temporary supports, e.g. decal · CPC title

• H01M4/8828

  Coating with slurry or ink · CPC title