Negative electrode for metal-air battery
US-2021043942-A1 · Feb 11, 2021 · US
US12002965B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-12002965-B2 |
| Application number | US-202217675160-A |
| Country | US |
| Kind code | B2 |
| Filing date | Feb 18, 2022 |
| Priority date | Aug 22, 2019 |
| Publication date | Jun 4, 2024 |
| Grant date | Jun 4, 2024 |
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Provided is a long aluminum foil capable of suppressing, in a case where the aluminum foil is provided with a region where through-holes are not formed, occurrence of deformation at a boundary portion between a region where through-holes are formed and the region where through-holes are not formed. The long aluminum foil includes, in a width direction orthogonal to a longitudinal direction, a perforated portion, a non-perforated portion, and a boundary portion between the perforated portion and the non-perforated portion, in which the perforated portion has a plurality of through-holes penetrating therethrough in a thickness direction, the non-perforated portion does not have a through-hole, the boundary portion has a plurality of through-holes penetrating therethrough in the thickness direction and a plurality of non-through-holes, and an opening ratio of the through-hole in the boundary portion gradually decreases from a perforated portion side to a non-perforated portion side.
Opening claim text (preview).
What is claimed is: 1. A long aluminum foil comprising: in a width direction orthogonal to a longitudinal direction, a perforated portion; two non-perforated portions, each provided separately at both ends of the long aluminum foil in the width direction; and a hole density decreasing portion between the perforated portion and each of the two non-perforated portions, wherein the perforated portion has a plurality of through-holes penetrating therethrough in a thickness direction, the two non-perforated portions do not have a through-hole, the hole density decreasing portions have a plurality of through-holes penetrating therethrough in the thickness direction and a plurality of non-through-holes that do not penetrate, and in the hole density decreasing portions, an opening ratio due to the through-holes gradually decreases from a perforated portion side to a non-perforated portion side. 2. The long aluminum foil according to claim 1 , wherein the perforated portion further has a plurality of non-through-holes. 3. The long aluminum foil according to claim 2 , wherein an area occupation ratio of the non-through-holes in the perforated portion is 1% or more and 20% or less. 4. The long aluminum foil according to claim 1 , wherein a specific surface area ΔS 1 on a surface of the perforated portion is 5% or more. 5. The long aluminum foil according to claim 1 , wherein a specific surface area ΔS 2 on a surface of the hole density decreasing portions is 2.5% or more. 6. The long aluminum foil according to claim 1 , wherein an area occupation ratio of the non-through-holes in the hole density decreasing portions is 1% or more and 15% or less. 7. The long aluminum foil according to claim 1 , wherein in the width direction, a number density of the through-holes in each of the hole density decreasing portions gradually decreases from the perforated portion side to the non-perforated portion side, and an average number density of the through-holes in the hole density decreasing portions is 10% or more and 90% or less of an average number density of the through-holes in the perforated portion. 8. The long aluminum foil according to claim 1 , wherein an average opening diameter of the hole density decreasing portions is 0.1 μm to 100 μm. 9. The long aluminum foil according to claim 1 , wherein a width of the hole density decreasing portions in the width direction is 3 mm or more. 10. The long aluminum foil according to claim 1 , wherein the long aluminum foil is wound in a roll shape. 11. The long aluminum foil according to claim 2 , wherein a specific surface area ΔS 1 on a surface of the perforated portion is 5% or more. 12. The long aluminum foil according to claim 2 , wherein a specific surface area ΔS 2 on a surface of the hole density decreasing portions is 2.5% or more. 13. The long aluminum foil according to claim 2 , wherein an area occupation ratio of the non-through-holes in the hole density decreasing portions is 1% or more and 15% or less. 14. The long aluminum foil according to claim 2 , wherein in the width direction, a number density of the through-holes in each of the hole density decreasing portions gradually decreases from the perforated portion side to the non-perforated portion side, and an average number density of the through-holes in the hole density decreasing portions is 10% or more and 90% or less of an average number density of the through-holes in the perforated portion. 15. The long aluminum foil according to claim 2 , wherein an average opening diameter of the through-holes in the hole density decreasing portions is 0.1 μm to 100 μm. 16. The long aluminum foil according to claim 2 , wherein a width of the hole density decreasing portions in the width direction is 3 mm or more. 17. The long aluminum foil according to claim 1 , wherein the perforated portion further has a plurality of non-through-holes, an area occupation ratio of the non-through-holes in the perforated portion is 1% or more and 20% or less, and an average opening ratio of the through holes in the perforated portion is 0.15% to 30%.
Porous or perforated metallic containers · CPC title
Metal or alloys, e.g. alloy coatings (H01M4/669 take precedence) · CPC title
Tubular type or pencil type electrodes; tubular or multitubular sheaths or covers of insulating material for said tubular-type electrodes · CPC title
Porous [e.g., foamed, spongy, cracked, etc.] · CPC title
characterised by their structure · CPC title
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