Electrode configuration with a protrusion inhibiting separator

Patent metadata

Field	Value
Publication number	US-12002963-B2
Application number	US-201917054639-A
Country	US
Kind code	B2
Filing date	May 28, 2019
Priority date	May 31, 2018
Publication date	Jun 4, 2024
Grant date	Jun 4, 2024

Abstract

An electrode configuration for a battery cell includes a positive electrode, a negative electrode, and a separator interposed between the positive electrode and the negative electrode. The separator includes an electrically conductive protrusion inhibiting layer and a first insulating layer interposed between and electrically insulating the protrusion inhibiting layer from one of the positive and negative electrode.

First claim

The invention claimed is:

1. An electrode configuration for a battery cell, comprising:
a positive electrode;
a negative electrode; and
a separator interposed between the positive electrode and the negative electrode, the separator comprising:
a protrusion inhibiting layer that is electrically conductive, the protrusion inhibiting layer comprising a lithium ion conducting material and a lithium protrusion growth inhibiting constituent interspersed within the lithium ion conducting material; and
a first electronically insulating layer interposed between and electrically insulating the protrusion inhibiting layer from one of the positive and negative electrode.

2. The electrode configuration as recited in claim 1 , wherein the protrusion inhibiting layer has a greater shear modulus than the other of the positive and negative electrode so as to mechanically inhibit growth of lithium protrusions on the other of the positive and negative electrode.

3. The electrode configuration as recited in claim 2 , wherein the lithium protrusion growth inhibiting constituent comprises one or more of carbon nanotubes, silver nanowires, particles of silver, particles of steel, particles of copper, and particles of lithium.

4. The electrode configuration as recited in claim 3 , wherein the primary lithium ion conducting material includes at least one material selected from the group consisting of polyethylene oxide, lithium-lanthanum-zirconium-oxide (LLZO), lithium phosphorus oxynitride (LiPON), lithium-aluminum-titanium-phosphate (LATP), Li 2 S—P 2 S 5 , and Li 3 PS 4 .

5. The electrode configuration as recited in claim 1 , wherein the protrusion inhibiting layer is configured to chemically inhibit growth of lithium protrusions on the other of the positive and negative electrode.

6. The electrode configuration as recited in claim 5 , wherein the lithium protrusion growth inhibiting constituent comprises an alloying material that alloys with lithium in the battery so as to inhibit growth of lithium protrusions.

7. The electrode configuration as recited in claim 6 , wherein the alloying material includes one or more material selected from the group consisting of aluminum, tin, magnesium, silicon, silver, and gold.

8. The electrode configuration as recited in claim 6 , wherein the lithium ion conducting material includes at least one material selected from the group consisting of polyethylene oxide, lithium-lanthanum-zirconium-oxide (LLZO), lithium phosphorus oxynitride (LiPON), lithium-aluminum-titanium-phosphate (LATP), Li 2 S—P 2 S 5 , and Li 3 PS 4 .

9. The electrode configuration as recited in claim 1 , wherein the first electronically insulating layer includes one or more materials selected from the group consisting of: PEO with conducting salt; gels with the addition of carbonate solvent and conducting salt; ceramic single ion conductors; lithium-lanthanum-zirconium-oxide (LLZO); lithium phosphorus oxynitride (LiPON); lithium-aluminum-titanium-phosphate (LATP); glassy single ion conductors; atomic layer deposition layers of lithium conducting, electronically insulating materials; Al 2 O 3 ; Li 3 P; Si 3 N 4 ; cation exchange polymers; and a perfluorosulfonic acid membrane.

10. The electrode configuration as recited in claim 1 , wherein the first electronically insulating layer has low permeability to counter-ions.

11. The electrode configuration as recited in claim 1 , wherein the first electronically insulating layer includes a single ion conducting layer.

12. The electrode configuration as recited in claim 1 , the separator further comprising a second insulating layer that electrically insulates the protrusion inhibiting layer from the other of the positive and negative electrode.

13. A battery cell comprising:
an electrode configuration comprising:
a positive electrode;
a negative electrode; and
a separator interposed between the positive electrode and the negative electrode, the separator comprising:
a protrusion inhibiting layer that is electrically conductive, the protrusion inhibiting layer comprising a lithium ion conducting material and a lithium protrusion growth inhibiting constituent interspersed within the lithium ion conducting material; and
a first electronically insulating layer interposed between and electrically separating the protrusion inhibiting layer from one of the positive and negative electrode.

14. The battery cell as recited in claim 13 , wherein the protrusion inhibiting layer is configured to mechanically inhibit growth of lithium protrusions on the other of the positive and negative electrode.

15. The battery cell as recited in claim 14 , wherein the lithium protrusion growth inhibiting constituent comprises one or more of carbon nanotubes, silver nanowires, particles of silver, particles of steel, particles of copper, and particles of lithium.

16. The battery cell as recited in claim 15 , wherein the primary lithium ion conducting material includes at least one material selected from the group consisting of polyethylene oxide, lithium-lanthanum-zirconium-oxide (LLZO), lithium phosphorus oxynitride (LiPON), lithium-aluminum-titanium-phosphate (LATP), Li 2 S—P 2 S 5 , and Li 3 PS 4 .

17. The battery cell as recited in claim 13 , wherein the protrusion inhibiting layer is configured to chemically inhibit growth of lithium protrusions on the other of the positive and negative electrode.

18. The battery cell as recited in claim 17 , wherein the lithium protrusion growth inhibiting constituent comprises an alloying material that alloys with lithium in the battery so as to inhibit growth of lithium protrusions.

19. The battery cell as recited in claim 18 , wherein the alloying material includes one or more material selected from the group consisting of aluminum, tin, magnesium, silicon, silver, and gold.

20. The electrode configuration as recited in claim 1 , wherein the protrusion inhibiting layer has a fracture toughness of greater than 10 4 Pa*m 1/2 .

Assignees

• Gorlin Yelena
• Christensen John F
• Craig Nathan P
• Samsonidze Georgy
• Subbaraman Ramachandran
• Bosch Gmbh Robert

Inventors

• Gorlin Yelena
• Christensen John F
• Craig Nathan P
• Samsonidze Georgy
• Subbaraman Ramachandran

Classifications

• H01M4/628 Primary

  Inhibitors, e.g. gassing inhibitors, corrosion inhibitors · CPC title

• H01M4/382

  Lithium (H01M4/405 takes precedence) · CPC title

• H01M4/5825

  Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines · CPC title

• H01M50/431

  Inorganic material · CPC title

• H01M50/434

  Ceramics · CPC title