Method for separating individual cathode-active materials from li-ion batteries

Patent metadata

Field	Value
Publication number	US-12002936-B2
Application number	US-202016985028-A
Country	US
Kind code	B2
Filing date	Aug 4, 2020
Priority date	Aug 4, 2020
Publication date	Jun 4, 2024
Grant date	Jun 4, 2024

Abstract

Method of separating individual cathode active materials from a mixture of cathode active materials by froth flotation has been developed. They are based on using appropriate chemical reagents that selectively hydrophobize individual cathode active materials to be recovered, so that they can be collected by air bubbles used in flotation and separated from other mixtures. The chemical reagents are amphiphilic molecules with specialized head groups have a strong affinity to metal elements on surfaces of cathode materials. This method enables a separation of individual cathode active material from a mixture of cathode active materials.

First claim

What is claimed is:

1. A method of processing lithium-ion batteries comprising:
Forming a cathode composite slurry comprising a liquid and 1-20 wt % of two or more cathode active materials;
Modifying at least one of the two or more cathode active materials to be hydrophobic;
Adding a frother chemical to the cathode composite slurry;
Aerating the cathode composite slurry, forming a froth and a tailing;
Separating the froth; and
Drying the froth to collect a first cathode active material of the two or more cathode active materials;
Wherein modifying at least one of the two or more cathode active materials comprises interaction of the at least one of the two or more cathode active materials with a collector chemical.

2. The method of claim 1 , wherein the cathode composite slurry has a pH of 7-12.

3. The method of claim 1 , wherein the collector chemical is a chelating agent.

4. The method of claim 1 , wherein the collector chemical is selected from the group consisting of hydroxamic acid, phosphonate, and phosphate.

5. The method of claim 1 , wherein aerating comprises forming air bubbles with diameters less than 1 mm.

6. The method of claim 1 , wherein aerating comprises bubbling inert gas or air at a rate of 1-5 liters per minute per 1 liter of cathode composite slurry for 5 to 20 minutes.

7. The method of claim 1 wherein the frother comprises methyl isobutyl carbinol (MIBC) or polyglycol (PPG).

8. The method of claim 1 further comprising:
drying the tailing to form tailing solids comprising one or more cathode active materials;
forming a second cathode composite slurry comprising a liquid and 1-20 wt % of the one or more cathode active materials;
modifying at least one of the one or more cathode active materials to be hydrophobic;
adding a second frother chemical to the cathode composite slurry;
aerating the second cathode composite slurry, forming a second froth and a second tailing;
separating the second froth from the second tailing; and
drying the second froth to collect a second cathode active material of the two or more cathode active materials.

9. The method of claim 8 , wherein modifying at least one of the one or more cathode active materials comprises interaction of the at least one of the one or more cathode active materials with a second collector chemical.

10. The method of claim 9 , wherein the second collector chemical is different from the collector chemical.

11. A method of processing lithium-ion batteries comprising:
Preparing cathode active material from a lithium-ion battery by:
Draining liquid components of the lithium-ion battery;
Physically separating components of the lithium-ion battery forming a mixture of anode and cathode powders;
Separating the anode powder from the cathode powder forming a mixed cathode powder comprising two or more cathode active materials; and

Collecting one of the two or more cathode active materials by:
Mixing the mixed cathode powder with a liquid to form a slurry having 1-20 wt % solid;
Modifying at least one of the two or more cathode active materials of the mixed cathode powder to be hydrophobic;
Adding a frothing agent to the slurry;
Aerating the slurry for 5 to 20 minutes, forming a froth;
Collecting the froth; and
Concentrating at least one of the two or more cathode active materials from the froth;

Wherein modifying at least one of the two or more cathode active materials comprises interacting at least one of the two or more cathode active materials with a collector chemical.

12. The method of claim 11 , wherein the slurry has a pH of 7-12.

13. The method of claim 11 , wherein the collector chemical is a chelating agent.

14. The method of claim 13 , wherein the collector chemical is selected from the group consisting of hydroxamic acid, phosphonate, and phosphate.

15. The method of claim 11 , wherein aerating comprises forming air bubbles with diameters less than 1 mm.

16. The method of claim 11 , wherein aerating comprises bubbling inert gas or air at a rate of 1-5 liters per minute per 1 liter of the slurry for 5 to 20 minutes.

17. The method of claim 11 , wherein the frother comprises methyl isobutyl carbinol (MIBC) or polyglycol (PPG).

Assignees

• Uchicago Argonne Llc
• Univ Michigan Tech

Inventors

• Pan Lei
• Folayan Tinuade Ololade
• Spangenberger Jeffrey S
• Polzin Bryant J

Classifications

• H01M10/54 Primary

  Reclaiming serviceable parts of waste accumulators · CPC title

• B03D1/023

  Carrier flotation; Flotation of a carrier material to which the target material attaches · CPC title

• C01B25/45 Primary

  containing plural metal, or metal and ammonium · CPC title

• C01G53/42

  containing alkali metals, e.g. LiNiO2 · CPC title

• C01G53/44

  containing manganese · CPC title