Hydrogen concentration sensor

Patent metadata

Field	Value
Publication number	US-12000794-B2
Application number	US-202017114726-A
Country	US
Kind code	B2
Filing date	Dec 8, 2020
Priority date	Dec 8, 2020
Publication date	Jun 4, 2024
Grant date	Jun 4, 2024

Abstract

An illustrative example hydrogen concentration sensor includes a plurality of electrically conductive plates. A hydrogen evolving electrode assembly in a first location between two of the plates is configured to generate hydrogen. A detection electrode assembly in a second location between two of the plates is configured to provide an indication of a concentration of hydrogen in a fluid of interest. A plurality of isolating layers includes a first isolating layer at the first location between two of the plates and a second isolating layer at the second location between two of the plates. The first and second isolating layers each include a sealant that secures the two plates together and seals a perimeter around the electrode assembly at the corresponding location.

First claim

We claim:

1. A hydrogen concentration sensor, comprising:
a plurality of electrically conductive plates;
a hydrogen evolving electrode assembly in a first location between two of the plates, the hydrogen evolving electrode assembly being configured to generate hydrogen;
a detection electrode assembly in a second location between two of the plates with at least one of the plates including at least one separator plate between the detection electrode assembly and the hydrogen evolving electrode assembly, the detection electrode assembly being configured to provide an indication of a concentration of hydrogen in a fluid of interest, wherein the detection electrode assembly includes two electrode layers and a matrix layer between the two electrode layers;
an internal passage extending in a thickness direction through the at least one separator plate between a hydrogen evolving electrode of the hydrogen evolving electrode assembly and a reference electrode of the detection electrode assembly on opposite sides of the at least one separator plate, wherein the internal passage is configured to communicate hydrogen evolved from the hydrogen evolving electrode to the reference electrode;
a device that detects a voltage across the detection electrode assembly, wherein the detected voltage indicates the concentration of hydrogen in the fluid of interest; and
a plurality of isolating layers, a first one of the isolating layers being at the first location between two of the plates, the first isolating layer including a sealant that secures the two plates at the first location, which the first isolating layer is between, together and seals a perimeter around the hydrogen evolving electrode assembly, a second one of the isolating layers being at the second location between two of the plates, the second isolating layer including a sealant that secures the two plates at the second location, which the second isolating layer is between, together and seals a perimeter around the detection electrode assembly.

2. The hydrogen concentration sensor of claim 1 , wherein the first and second isolating layers comprise a fluoropolymer and the sealants of the first and second isolating layers each comprises a thermosetting polymer.

3. The hydrogen concentration sensor of claim 2 , wherein the first and second isolating layers each comprises polytetrafluoroethylene.

4. The hydrogen concentration sensor of claim 3 , wherein the sealants of the first and second isolating layers each comprises a fluoropolymer.

5. The hydrogen concentration sensor of claim 1 , wherein
the first one of the isolating layers comprises three gaskets,
one of the gaskets is arranged between two others of the gaskets,
the two others of the gaskets include the sealant of the first one of the isolating layers, and
the one of the gaskets does not include the sealant of the first one of the isolating layers.

6. The hydrogen concentration sensor of claim 5 , wherein
the second one of the isolating layers comprises three gaskets,
one of the gaskets of the second one of the isolating layers is arranged between two others of the gaskets of the second one of the isolating layers,
the two others of the gaskets of the second one of the isolating layers include the sealant of the second one of the isolating layers, and
the one of the gaskets of the second one of the isolation layers does not include the sealant of the second one of the isolating layers.

7. The hydrogen concentration sensor of claim 6 , wherein
the hydrogen evolving electrode assembly includes two electrode layers and a matrix layer between the two electrode layers, and the hydrogen evolving electrode and the reference electrode are established by respective ones of the electrode layers;
the one of the gaskets of each of the first and second isolation layers includes a window,
each matrix layer is situated in the window of the corresponding one of the gaskets,
the two others of the gaskets of each of the first and second isolation layers includes a window,
each electrode layer of each electrode assembly has a portion exposed to each matrix layer through the window of the corresponding one of the two others of the gaskets in the corresponding electrode assembly.

8. The hydrogen concentration sensor of claim 7 , wherein
a thickness of the electrode layers has a predetermined relationship to a thickness of the two others of the gaskets; and
the thickness of the two others of the gaskets controls an amount of compression of the electrode layers.

9. The hydrogen concentration sensor of claim 1 , wherein
the electrode assemblies each include a liquid electrolyte and the sealants of the first and second isolating layers each provides a seal that maintains the liquid electrolyte in the corresponding electrode assembly.

10. The hydrogen concentration sensor of claim 9 , wherein the liquid electrolyte comprises phosphoric acid.

11. The hydrogen concentration sensor of claim 1 , wherein each electrically conductive plate comprises graphite.

12. The hydrogen concentration sensor of claim 1 , wherein
the at least one separator plate includes a vent situated to allow hydrogen from the internal passage to exit the hydrogen concentration sensor; and
the vent is situated to direct hydrogen exiting the vent away from the detection electrode assembly.

13. The hydrogen concentration sensor of claim 1 , wherein the sealants of the first and second isolating layers each comprises a thermosetting fluoropolymer layer.

14. The hydrogen concentration sensor of claim 1 , wherein the device that detects the voltage across the detection electrode assembly has an impedance that prevents the device from drawing current from the detection electrode assembly.

15. The hydrogen concentration sensor of claim 1 , wherein the voltage across the detection electrode assembly results from a potential difference across the detection electrode assembly based on the concentration of hydrogen in the fluid of interest without any current or reference potential applied to the detection electrode assembly.

16. The hydrogen concentration sensor of claim 1 , wherein:
the internal passage extends between a first end and a second end opposed to the first end, the first end terminates at the hydrogen evolving electrode, and the second end terminates at the reference electrode.

17. The hydrogen concentration sensor of claim 1 , wherein:
the plates, the hydrogen evolving electrode assembly, the detection electrode assembly, and the plurality of isolating layers establish a stack that extends in the thickness direction;
a first opening is established along a first side of the stack, the first opening configured to communicate hydrogen to a hydrogen oxidizing electrode of the hydrogen evolving electrode assembly; and
a second opening is established on a second side of the stack opposite the first side, the second opening configured to expose a detection electrode of the detection electrode assembly to the fluid of interest.

18. The hydrogen concentration sensor of claim 17 , wherein:
the internal passage extends between a first end and a second end opposed to the first end, the first end terminates at the hydrogen evolving electrode, and the second end terminates at the reference electrode.

19. The hydrogen concentration sensor of claim 18 , wherein:
the internal passage is aligned with the first opening and the second opening.

20. The hydrogen concentration sensor of claim 18 , wherein:
the reference electrode is arranged such that

Assignees

• Doosan Fuel Cell America Inc
• Hyaxiom Inc

Inventors

• Preston Joshua
• Soldini Marc

Classifications

• G01N27/413 Primary

  Concentration cells using liquid electrolytes {measuring currents or voltages in voltaic cells} · CPC title

• H01M8/0444

  Concentration; Density (H01M8/04492 takes precedence) · CPC title

• H01M8/0618

  Reforming processes, e.g. autothermal, partial oxidation or steam reforming · CPC title

• G01N33/005 Primary

  H2 · CPC title

• G01N27/4045 Primary

  for gases other than oxygen · CPC title