Method for extracting nickel from high matte nickel leaching residue

Patent metadata

Field	Value
Publication number	US-12000012-B2
Application number	US-202218552447-A
Country	US
Kind code	B2
Filing date	Jun 6, 2022
Priority date	Jul 29, 2021
Publication date	Jun 4, 2024
Grant date	Jun 4, 2024

Abstract

Disclosed in the present invention is a method for extracting nickel from a high matte nickel leaching residue. The method comprises: firstly, adding a crushed material of a high matte nickel leaching residue to an organic solvent in which sulfur is dissolved, heating same for reaction, and carrying out solid-liquid separation to obtain a first filtrate and a first filter residue; adding the first filter residue to a copper sulfate solution, heating same for reaction, and carrying out solid-liquid separation to obtain a second filtrate and a second filter residue; and evaporating, condensing and concentrating the second filtrate, and filtering same to obtain copper sulfate crystals and a nickel-containing filtrate. Throughout the whole reaction, only a small amount of sulfur and copper sulfate are consumed, and the organic solvent can be recycled.

First claim

The invention claimed is:

1. A method for extracting nickel from high nickel matte leaching residue, comprising the following steps:
S1: adding a pulverized material of high nickel matte leaching residue to an organic solvent in which sulfur is dissolved, heating to perform reaction, and performing solid-liquid separation to obtain a first filtrate and a first filter residue; wherein a concentration of the sulfur in the organic solvent is 10-700 g/L; a solid-to-liquid ratio of the pulverized material to the organic solvent is 1 g:(0.5-5) mL; a temperature of the heating is 80-120° C.; and a time of the reaction is 1-5 h;
S2: adding the first filter residue to a copper sulfate solution, heating to perform reaction, and performing solid-liquid separation to obtain a second filtrate and a second filter residue; wherein a concentration of the copper sulfate solution is 0.1-4.0 mol/L; a solid-to-liquid ratio of the first filter residue to the copper sulfate solution is 1 g:(0.5-5) mL, a temperature of the heating is 80-180° C.; a time of the reaction is 2-8 h; and the second filter residue is used for making copper; and
S3: evaporating, condensing and concentrating the second filtrate, and performing filtration to obtain copper sulfate crystals and a nickel-containing filtrate.

2. The method according to claim 1 , wherein in step S1, the organic solvent is selected from one or more of carbon disulfide, carbon tetrachloride, methylcyclohexane, trichloroethane, trichloroethylene, tetrachloroethane, diethylene glycol dimethyl ether, tetrahydronaphthalene, and decahydronaphthalene.

3. The method according to claim 1 , wherein in step S3, an extractant is added to the nickel-containing filtrate to perform extraction, and the filtrate is left to stand and separated to obtain a nickel-containing extraction organic phase and a raffinate; and then nickel is back-extracted from the nickel-containing extraction organic phase with a sulfuric acid solution to obtain a nickel sulfate solution.

Assignees

• Guangdong Brunp Recycling Technology Co Ltd
• Hunan Brunp Recycling Tech Co Ltd
• Hunan Brunp Ev Recycling Co Ltd

Inventors

• Yu Haijun
• Xie Yinghao
• Li Aixia
• Zhang Xuemei
• Li Changdong

Classifications

• Y02P10/20

  Recycling · CPC title

• C22B3/20

  Treatment or purification of solutions, e.g. obtained by leaching (C22B3/18 takes precedence) · CPC title

• C22B7/006 Primary

  Wet processes · CPC title

• C22B15/0063

  Hydrometallurgy · CPC title

• C22B23/04 Primary

  by wet processes (recovery or separation of nickel or cobalt using organic agents C22B3/00) · CPC title