Polymer blends for use in wellbore applications

Patent metadata

Field	Value
Publication number	US-11999897-B2
Application number	US-202117474592-A
Country	US
Kind code	B2
Filing date	Sep 14, 2021
Priority date	Sep 14, 2021
Publication date	Jun 4, 2024
Grant date	Jun 4, 2024

Abstract

Elastomer blends comprising mixtures of partially fluorinated elastomers, such as tetrafluoroethylene propylene elastomers (FEPM or TFEP) and fluorocarbon rubbers, such as vinylidene fluoride-based elastomers (FKM or FEP), can be prepared using two-roll mills, internal mixers, or other mixing technique and can be molded into seals, gaskets, o-rings or other articles using extrusion, injection molding, compression molding or the like. The resultant elastomeric articles can provide good sealing performance, including at moderate or low temperatures, and exhibit good chemical compatibility and resistance when exposed to common wellbore environments. In some cases, the elastomer blends can provide performance characteristics previously only available from perfluorinated elastomers (FFKM), but without requiring the complex processing conditions associated with preparing perfluorinated elastomers.

First claim

What is claimed is:

1. An elastomer composition for use in a wellbore or wellbore operation, comprising:
an elastomer blend;
one or more additives;
one or more fillers; and
one or more curative agents;
wherein the elastomer blend is a blend consisting of a partially fluorinated elastomer and a fluorocarbon rubber elastomer, wherein the partially fluorinated elastomer and the fluorocarbon rubber elastomer are immiscible, wherein the elastomer blend exhibits a first glass transition temperature at a first temperature of from −40° C. to −5° C. and a second glass transition temperature at a second temperature of from −15° C. to 5° C.

2. The elastomer composition of claim 1 , wherein the partially fluorinated elastomer and the fluorocarbon rubber elastomer are both intra and inter molecularly cross-linked in the elastomer.

3. The elastomer composition of claim 1 , wherein the partially fluorinated elastomer and the fluorocarbon rubber elastomer are homogeneously distributed in the elastomer.

4. The elastomer composition of claim 1 , wherein the partially fluorinated elastomer comprises tetrofluoroethylene monomers and propylene monomers.

5. The elastomer composition of claim 4 , wherein the partially fluorinated elastomer further comprises perfluoromethyl vinyl ether monomers or ethylene monomers.

6. The elastomer composition of claim 1 , wherein the fluorocarbon rubber elastomer comprises vinylidene fluoride monomers.

7. The elastomer composition of claim 6 , wherein the fluorocarbon rubber elastomer further comprises hexafluoropropylene monomers, tetrafluoroethylene monomers, propylene monomers, or perfluoromethyl vinyl ether monomers.

8. The elastomer composition of claim 1 , wherein the partially fluorinated elastomer corresponds to from 15% to 85% of the elastomer blend, by weight, and wherein the fluorocarbon rubber elastomer corresponds to from 15% to 85% of the elastomer blend, by weight.

9. The elastomer composition of claim 1 , wherein the one or more additives are selected from the group consisting of carbon nanotubes, a hydrin elastomer, a halobutyl rubber elastomer, and an EPDM rubber elastomer; and wherein the one or more fillers are reinforcing fillers selected from carbon black or silica.

10. An elastomeric article for use in a wellbore or wellbore operation, in the form of a seal, comprising
an elastomer blend;
one or more additives;
one or more fillers; and
one or more curative agents,
wherein the elastomer blend is a blend consisting of a partially fluorinated elastomer and a fluorocarbon rubber elastomer, wherein the partially fluorinated elastomer and the fluorocarbon rubber elastomer are immiscible, wherein the elastomer blend exhibits a first glass transition temperature at a first temperature of from −40° C. to −5° C. and a second glass transition temperature at a second temperature of from −15° C. to 5° C.

11. The elastomeric article of claim 10 , wherein the seal comprises a packer element, a molded seal, an o-ring, or a gasket.

12. The elastomeric article of claim 10 , wherein the additives are selected from the group consisting of carbon nanotubes, a hydrin elastomer, a halobutyl rubber elastomer, and an EPDM rubber elastomer; or wherein the fillers are reinforcing fillers selected from black or silica.

13. The elastomeric article of claim 10 , wherein the one or more curative agents comprise a bisphenol, an amine, a peroxide, an isocyanate, a lead oxide, or a combination of these.

14. The elastomeric article of claim 10 , wherein the seal consists of or consists essentially of the elastomer blend the one or more additives, the one or more fillers, and the one or more curative agents.

15. The elastomer composition of claim 1 , wherein the one or more curative agents comprise a bisphenol, an amine, a peroxide, an isocyanate, a lead oxide, or a combination of these.

16. The elastomer composition of claim 1 , consisting essentially of the elastomer blend, the one or more additives, the one or more fillers, and the one or more curative agents.

17. The elastomer composition of claim 1 , consisting of the elastomer blend, the one or more additives, the one or more fillers, and the one or more curative agents.

18. The elastomer composition of claim 1 , wherein the elastomer blend corresponds to 50% or more by weight of the elastomer composition.

19. The elastomeric article of claim 10 , wherein the elastomer blend corresponds to 50% or more by weight of the elastomeric article.

Assignees

• Halliburton Energy Services Inc

Inventors

• Thatathil Sandeep
• Shukla Shashwat
• Singh Arpana

Classifications

• C09K8/5083 Primary

  obtained by reactions only involving carbon-to-carbon unsaturated bonds · CPC title

• C08F10/06 Primary

  Propene · CPC title

• C08F14/26

  Tetrafluoroethene · CPC title

• C08F14/28

  Hexafluoropropene · CPC title

• C08L15/02

  Rubber derivatives containing halogen · CPC title