High purity isoamylene production from tertiary amyl methyl ether decomposition

Patent metadata

Field	Value
Publication number	US-11999672-B2
Application number	US-202217930905-A
Country	US
Kind code	B2
Filing date	Sep 9, 2022
Priority date	Nov 2, 2020
Publication date	Jun 4, 2024
Grant date	Jun 4, 2024

Abstract

Systems and methods for the production of a high purity isoamylene product. The isoamylene in a mixed hydrocarbon stream may initially be converted to TAME via etherification, and a subsequent decomposition of the TAME may result in a high purity isoamylene stream with very low impurities that is suitable for a variety of petrochemical applications, such as for use in the production of fragrances, pesticides, peroxides, polymer antioxidants, UV stabilizers and hydrocarbon resins.

First claim

What is claimed as new and desired to be protected by Letters Patent is:

1. A system for producing a high purity isoamylene stream, the system comprising:
a purification zone comprising a divided wall distillation column configured to receive a crude tertiary amyl ether from a feed source, the divided wall distillation column configured to separate the crude tertiary amyl ether into an overhead lights stream, a bottom heavies stream, and a tertiary amyl ether containing side draw stream;
a decomposition reactor containing a decomposition catalyst configured to convert the tertiary amyl ether as a vapor into isoamylene and alcohol and to produce a reaction effluent;
a separation zone configured to receive the reaction effluent and to separate the reaction effluent into an alcohol stream, a vent stream, a heavy oxygenate stream, and an isoamylene product stream.

2. The system of claim 1 , further comprising a feed line for feeding the heavy oxygenate stream to the purification zone.

3. The system of claim 1 , further comprising a reaction zone configured to react an isoamylene containing stream with methanol to produce the crude tertiary amyl ether.

4. The system of claim 3 , wherein the separation zone comprises:
an isoamylene lights column configured to receive the reactor effluent and to separate the reactor effluent into an overhead stream and a bottoms stream comprising the heavy oxygenates, recovered as the heavy oxygenate stream;
a methanol extraction column, configured to receive the overhead stream from the isoamylene lights column and to recover an overheads stream and to recover the alcohol stream as a bottoms stream;
an isoamylene finishing column, configured to receive the overheads stream from the methanol extraction column and to recover the vent stream as an overheads product and to recover the isoamylene product stream as a bottoms product.

5. The system of claim 4 , further comprising a flow line for feeding the alcohol stream to the reaction zone.

6. The system of claim 1 , wherein the separation zone comprises:
a methanol extraction column, configured to receive the reactor effluent and to separate the reactor effluent into an overhead stream and a bottoms stream comprising the alcohol, recovered as the alcohol stream;
an isoamylene lights column configured to receive the overhead stream from the methanol extraction column and to recover the vent stream as an overheads and a bottoms stream;
a heavies column, configured to receive the bottoms stream from the isoamylene lights column and to recover the isoamylene product stream as an overheads product and to recover the heavy oxygenate stream as a bottoms product.

7. The system of claim 6 , further comprising a methanol finishing column configured for receiving the alcohol stream and for producing a purified alcohol product stream.

8. The system of claim 1 , further comprising a heat exchanger for vaporizing the tertiary amyl ether containing side draw stream.

9. The system of claim 8 , further comprising a feed line for feeding the heavy oxygenate stream to the purification zone.

10. The system of claim 8 , further comprising a reaction zone configured to react an isoamylene containing stream with methanol to produce the crude tertiary amyl ether.

11. The system of claim 10 , wherein the separation zone comprises:
an isoamylene lights column configured to receive the reactor effluent and to separate the reactor effluent into an overhead stream and a bottoms stream comprising the heavy oxygenates, recovered as the heavy oxygenate stream;
a methanol extraction column, configured to receive the overhead stream from the isoamylene lights column and to recover an overheads stream and to recover the alcohol stream as a bottoms stream;
an isoamylene finishing column, configured to receive the overheads stream from the methanol extraction column and to recover the vent stream as an overheads product and to recover the isoamylene product stream as a bottoms product.

12. The system of claim 11 , further comprising a flow line for feeding the alcohol stream to the reaction zone.

13. The system of claim 8 , wherein the separation zone comprises:
a methanol extraction column, configured to receive the reactor effluent and to separate the reactor effluent into an overhead stream and a bottoms stream comprising the alcohol, recovered as the alcohol stream;
an isoamylene lights column configured to receive the overhead stream from the methanol extraction column and to recover the vent stream as an overheads and a bottoms stream;
a heavies column, configured to receive the bottoms stream from the isoamylene lights column and to recover the isoamylene product stream as an overheads product and to recover the heavy oxygenate stream as a bottoms product.

14. The system of claim 13 , further comprising a methanol finishing column configured for receiving the alcohol stream and for producing a purified alcohol product stream.

15. A system for producing a high purity isoamylene stream, the system comprising:
a reaction zone configured to react an isoamylene containing stream with methanol to produce a crude tertiary amyl ether;
a purification zone comprising a divided wall distillation column configured to receive the crude tertiary amyl ether from a feed source, the divided wall distillation column configured to separate the crude tertiary amyl ether into an overhead lights stream, a bottom heavies stream, and a tertiary amyl ether containing side draw stream;
a heat exchanger for vaporizing the tertiary amyl ether containing side draw stream;
a decomposition reactor containing a decomposition catalyst configured to convert the tertiary amyl ether into isoamylene and alcohol and to produce a reaction effluent; and
a separation zone configured to receive the reaction effluent and to separate the reaction effluent into an alcohol stream, a vent stream, a heavy oxygenate stream, and an isoamylene product stream; and a feed line for feeding the heavy oxygenate stream to the purification zone,
wherein the separation zone comprises:
an isoamylene lights column configured to receive the reactor effluent and to separate the reactor effluent into an overhead stream and a bottoms stream comprising the heavy oxygenates, recovered as the heavy oxygenate stream;
a methanol extraction column, configured to receive the overhead stream from the isoamylene lights column and to recover an overheads stream and to recover the alcohol stream as a bottoms stream; and
an isoamylene finishing column, configured to receive the overheads stream from the methanol extraction column and to recover the vent stream as an overheads product and to recover the isoamylene product stream as a bottoms product.

16. The system of claim 15 , further comprising a flow line for feeding the alcohol stream to the reaction zone.

17. The system of claim 15 , further comprising a methanol finishing column configured for receiving the alcohol stream and for producing a purified alcohol product stream.

Assignees

• Lummus Technology Inc

Inventors

• Barias Rosette
• Chen Liang
• Scott Michael Jon

Classifications

• C07C29/10

  of ethers, including cyclic ethers, e.g. oxiranes · CPC title

• C07C1/20 Primary

  starting from organic compounds containing only oxygen atoms as heteroatoms · CPC title

• C07C7/04

  by distillation · CPC title

• C07C7/10

  by extraction, i.e. purification or separation of liquid hydrocarbons with the aid of liquids · CPC title

• Y02P20/10

  Process efficiency · CPC title