Glass for magnetic recording medium substrate or for glass spacer for magnetic recording and reproducing
US-2022411317-A1 · Dec 29, 2022 · US
US11999652B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11999652-B2 |
| Application number | US-202017784528-A |
| Country | US |
| Kind code | B2 |
| Filing date | Dec 11, 2020 |
| Priority date | Dec 13, 2019 |
| Publication date | Jun 4, 2024 |
| Grant date | Jun 4, 2024 |
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Provided is a glass for a magnetic recording medium substrate or for a glass spacer for a magnetic recording/reproducing apparatus, in which the total content of Li 2 O, Na 2 O, K 2 O, B 2 O 3 , and ZnO (Li 2 O+Na 2 O+K 2 O+B 2 O 3 +ZnO) is in a range of 0 mol % or more and 3 mol % or less, the mole ratio of the total content of Al 2 O 3 and MgO relative to the total content of SiO 2 and CaO [(Al 2 O 3 +MgO)/(SiO 2 +CaO)] is in a range of 0.30 or more and 0.6 or less, the total content of SiO 2 and Al 2 O 3 (SiO 2 +Al 2 O 3 ) is in a range of 64 mol % or more and 85 mol % or less, and the total content of SiO 2 , Al 2 O 3 , MgO, and CaO (SiO 2 +Al 2 O 3 +MgO+CaO) is in a range of 87 mol % or more and 98 mol % or less.
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The invention claimed is: 1. A glass for a magnetic recording medium substrate or for a glass spacer for a magnetic recording/reproducing apparatus, wherein a mole ratio of the total content of Al 2 O 3 and MgO relative to the total content of SiO 2 and CaO [(A 2 O 3 +MgO)/(SiO 2 +CaO)] is in a range of 0.417 or more and 0.6 or less, the total content of SiO 2 and Al 2 O 3 (SiO 2 +Al 2 O 3 ) is in a range of 64 mol % or more and 85 mol % or less, the total content of SiO 2 , Al 2 O 3 , MgO, and CaO (SiO 2 +Al 2 O 3 +MgO+CaO) is in a range of 87 mol % or more and 98 mol % or less, the total content of TiO 2 and ZrO 2 (TiO 2 +ZrO 2 ) is 0.5 mol % or more, the glass has a glass transition temperature of 740° C. or more, an average linear expansion coefficient of the glass at 100° C. to 300° C. is 68×10 −7 /° C. or less, and the total content of Li 2 O, Na 2 O, K 2 O, B 2 O 3 , and ZnO (Li 2 O+Na 2 O+K 2 O+B 2 O 3 +ZnO) is in a range of 0 mol % or more and 3 mol % or less. 2. The glass according to claim 1 , wherein the glass has the glass transition temperature of 760° C. or more. 3. The glass according to claim 2 , wherein the SiO 2 content is in a range of 55 mol % or more and 66 mol % or less. 4. The glass according to claim 2 , wherein the Al 2 O 3 content is in a range of 10 mol % or more and 18 mol % or less. 5. The glass according to claim 2 , wherein the MgO content is in a range of 8 mol % or more and 20 mol % or less. 6. The glass according to claim 2 , wherein a mole ratio of the CaO content relative to the total content of MgO, CaO, SrO, and BaO [CaO/(MgO+CaO+SrO+BaO)] is 0.4 or less. 7. The glass according to claim 2 , wherein the glass has a Young's modulus of 86 GPa or more. 8. The glass according to claim 2 , wherein the glass has a specific gravity of 2.8 or less. 9. The glass according to claim 2 , wherein the glass has a specific elastic modulus of 30 MNm/kg or more. 10. A magnetic recording medium substrate comprised of the glass according to claim 2 . 11. A magnetic recording medium comprising: the magnetic recording medium substrate according to claim 10 ; and a magnetic recording layer. 12. The glass according to claim 1 , wherein the SiO 2 content is in a range of 55 mol % or more and 66 mol % or less. 13. The glass according to claim 1 , wherein the Al 2 O 3 content is in a range of 10 mol % or more and 18 mol % or less. 14. The glass according to claim 1 , wherein the MgO content is in a range of 8 mol % or more and 20 mol % or less. 15. The glass according to claim 1 , wherein a mole ratio of the CaO content relative to the total content of MgO, CaO, SrO, and BaO [CaO/(MgO+CaO+SrO+BaO)] is 0.4 or less. 16. The glass according to claim 1 , wherein the glass has a Young's modulus of 86 GPa or more. 17. The glass according to claim 1 , wherein the glass has a specific gravity of 2.8 or less. 18. The glass according to claim 1 , wherein the glass has a specific elastic modulus of 30 MNm/kg or more. 19. A magnetic recording medium substrate comprised of the glass according to claim 1 . 20. A magnetic recording medium comprising: the magnetic recording medium substrate according to claim 19 ; and a magnetic recording layer.
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