Method and apparatus for separating a synthesis gas by cryogenic distillation

Patent metadata

Field	Value
Publication number	US-11999622-B2
Application number	US-202117146116-A
Country	US
Kind code	B2
Filing date	Jan 11, 2021
Priority date	Jan 14, 2020
Publication date	Jun 4, 2024
Grant date	Jun 4, 2024

Abstract

In a process for separating a mixture containing carbon monoxide, hydrogen and carbon dioxide, the mixture cooled in a heat exchanger is contacted by a stream of liquid methanol at a temperature below −40° C. to produce carbon dioxide enriched methanol and a carbon dioxide depleted gas relative to the cooled mixture, the carbon dioxide depleted gas is cooled in the heat exchanger and is sent to a separation unit to produce a carbon monoxide enriched stream and a hydrogen enriched stream and the streams enriched in carbon monoxide and hydrogen are heated in the heat exchanger by exchanging heat with the mixture.

First claim

What is claimed is:

1. A process for separating a mixture containing carbon monoxide, hydrogen and carbon dioxide produced by washing with methanol in an acid gas removal unit, the process comprising the steps of:
i. cooling the mixture in a heat exchanger;
ii. withdrawing at least a portion of the cooled mixture from the heat exchanger at an intermediate temperature of the heat exchanger between a cold end and a warm end of the heat exchanger;
iii. contacting the at least part of the cooled mixture by a flow of liquid methanol at a temperature below −40° C. to produce methanol enriched with carbon dioxide and a carbon dioxide depleted gas with respect to the cooled mixture;
iv. cooling the carbon dioxide depleted gas in the heat exchanger and sending the carbon dioxide depleted gas to a separation unit to produce a carbon monoxide enriched flow with respect to the carbon dioxide depleted gas and a hydrogen enriched flow with respect to the carbon dioxide depleted gas, wherein the separation unit is selected from the group consisting of methane washing, carbon monoxide washing, nitrogen washing, distillation, partial condensation, and combinations thereof, and
v. heating a stream in the heat exchanger by exchanging heat with the mixture and/or the carbon dioxide depleted gas or heating the stream in another heat exchanger, wherein the stream is selected from the group consisting of the carbon monoxide enriched stream with respect to the carbon dioxide depleted gas, the hydrogen-enriched stream with respect to the carbon dioxide depleted gas, and combinations thereof.

2. The process of claim 1 , wherein the carbon dioxide depleted gas is cooled to at least −170° C. upstream of the separation unit.

3. The process of claim 1 further comprising a step of washing with methanol in an acid gas removal unit upstream of step i) to produce the mixture to be cooled in the heat exchanger of the step i).

4. The process of claim 3 , wherein the flow of methanol is from the acid gas removal unit which produces the mixture to be cooled in the heat exchanger of step i).

5. The process of claim 3 , wherein at least a portion of the cooled mixture is contacted by a flow of liquid methanol in a washing column fed at the top by the stream of methanol and at the bottom by at least a portion of the cooled mixture, the carbon dioxide depleted gas being withdrawn at the top of the column and the carbon dioxide enriched methanol being withdrawn in the bottom of the column.

6. The process of claim 5 , wherein a liquid from the washing column is returned to the acid gas removal unit which produces the mixture to be cooled in the heat exchanger of step i).

7. The process of claim 6 , wherein the liquid is heated in the heat exchanger.

8. The process of claim 1 , wherein the mixture has not been purified by adsorption upstream of the heat exchanger.

Assignees

• Air Liquide

Inventors

• Le Guludec Erwan
• Hernandez Antoine
• Teixeira Guillaume
• Davidian Benoit
• Linicus Matthias

Classifications

• C01B3/52 Primary

  by contacting with liquids; Regeneration of used liquids · CPC title

• B01D53/002

  by condensation · CPC title

• B01D53/1425

  Regeneration of liquid absorbents · CPC title

• B01D53/1475

  Removing carbon dioxide · CPC title

• B01D53/1493

  Selection of liquid materials for use as absorbents · CPC title