Composite structure and manufacturing method therefor

Patent metadata

Field	Value
Publication number	US-11999112-B2
Application number	US-201917046515-A
Country	US
Kind code	B2
Filing date	Apr 4, 2019
Priority date	Apr 10, 2018
Publication date	Jun 4, 2024
Grant date	Jun 4, 2024

Abstract

Provided are a composite structure that is formed by joining a metal member and a molded article of a polyarylene sulfide resin composition and is more excellent in terms of joint strength and heat cycle resistance and a producing method therefor. More specifically, provided are a composite structure formed by joining a surface-roughened metal member and a PPS member, in which a number average value of developed area ratios (Sdr) of an interface measured at five random points on a surface of the surface-roughened metal member using a confocal microscope based on ISO 25178 is 5 [%] or more, and a melt viscosity of a PPS resin is 15 to 500 [Pa·s], and a producing method therefor.

First claim

The invention claimed is:

1. A composite structure comprising a surface-roughened metal member and a resin member made of a molded article formed by melting and molding a polyarylene sulfide resin composition containing a polyarylene sulfide resin (A), which are joined to each other,
wherein a number average value of developed area ratios (Sdr) of an interface measured at five random points on a surface of the surface-roughened metal member using a confocal microscope based on ISO 25178 is 5% or more,
a maximum height roughness (Rz) of four random straight line points on a surface of the surface-roughened metal member using a stylus-type roughness meter based on ISO 4287 is 2 μm or more and 30 μm or less,
an average length (RSm) of four random straight line points on a surface of the surface-roughened metal member using a stylus-type roughness meter based on ISO 4287 is 10 μm or more and less than 100 μm, and
a melt viscosity of the polyarylene sulfide resin, measured using a capillary type flow tester after holding the polyarylene sulfide resin at 300° C. for six minutes with a load of 1.96×10 6 Pa and L/D=10 (mm)/1 (mm), is 15 Pa·s or more and 500 Pa·s or less.

2. The composite structure according to claim 1 ,
wherein the polyarylene sulfide resin composition is prepared by blending 1 part by mass or more and 150 parts by mass or less of a filler (B) with 100 parts by mass of the polyarylene sulfide resin (A), followed by melting and kneading.

3. The composite structure according to claim 1 ,
wherein the polyarylene sulfide resin composition is prepared by blending 1 part by mass or more and 100 parts by mass or less of an elastomer (C) with 100 parts by mass of the polyarylene sulfide resin (A), followed by melting and kneading.

4. A method for producing a composite structure in which a surface-roughened metal member is joined to a resin member made of a molded article formed by melting and molding a polyarylene sulfide resin composition containing a polyarylene sulfide resin, the method comprising:
a step (α) of melting and molding the polyarylene sulfide resin composition on a surface of a metal member to perform joining or a step (β) of joining the surface of the metal member and the molded article,
wherein a number average value (Sdr0) of developed area ratios (Sdr) of an interface measured at five random points in the surface-roughened metal member using a confocal microscope based on ISO 25178 is 5% or more,
a maximum height roughness (Rz) of four random straight line points on a surface of the surface-roughened metal member using a stylus-type roughness meter based on ISO 4287 is 2 μm or more and 30 μm or less,
an average length (RSm) of four random straight line points on a surface of the surface-roughened metal member using a stylus-type roughness meter based on ISO 4287 is 10 μm or more and less than 100 μm, and
a melt viscosity of the polyarylene sulfide resin, measured using a capillary type flow tester after holding the polyarylene sulfide resin at 300° C. for six minutes with a load of 1.96×10 6 Pa and L/D=10 (mm)/1 (mm), is 15 Pa·s or more and 500 Pa·s or less.

5. The method for producing a composite structure according to claim 4 , further comprising:
for preparing the surface-roughened metal member, a step of roughening the surface of the metal member,
wherein a ratio (Sdr1/Sdr0) of a number average value (Sdr1) of the developed area ratios (Sdr) of the interface at five random points on the surface of the surface-roughened metal member to the number average value (Sdr0) of the developed area ratios (Sdr) of the interface at five random points on the surface of the metal member before roughening the surface is 7 or more.

6. The method for producing a composite structure according to claim 4 ,
wherein the polyarylene sulfide resin composition is prepared by blending 1 part by mass or more and 200 parts by mass or less of a filler (B) with 100 parts by mass of the polyarylene sulfide resin (A), followed by melting and kneading.

7. The method for producing a composite structure according to claim 4 ,
wherein the polyarylene sulfide resin composition is prepared by blending 0.01 parts by mass or more and 30 parts by mass or less of an elastomer (C) with 100 parts by mass of the polyarylene sulfide resin (A), followed by melting and kneading.

8. The composite structure according to claim 2 ,
wherein the polyarylene sulfide resin composition is prepared by blending 1 part by mass or more and 100 parts by mass or less of an elastomer (C) with 100 parts by mass of the polyarylene sulfide resin (A), followed by melting and kneading.

9. The method for producing a composite structure according to claim 7 ,
wherein the polyarylene sulfide resin composition is prepared by blending 1 part by mass or more and 200 parts by mass or less of a filler (B) with 100 parts by mass of the polyarylene sulfide resin (A), followed by melting and kneading.

10. The method for producing a composite structure according to claim 5 ,
wherein the polyarylene sulfide resin composition is prepared by blending 0.01 parts by mass or more and 30 parts by mass or less of an elastomer (C) with 100 parts by mass of the polyarylene sulfide resin (A), followed by melting and kneading.

11. The method for producing a composite structure according to claim 6 ,
wherein the polyarylene sulfide resin composition is prepared by blending 0.01 parts by mass or more and 30 parts by mass or less of an elastomer (C) with 100 parts by mass of the polyarylene sulfide resin (A), followed by melting and kneading.

12. The method for producing a composite structure according to claim 9 ,
wherein the polyarylene sulfide resin composition is prepared by blending 0.01 parts by mass or more and 30 parts by mass or less of an elastomer (C) with 100 parts by mass of the polyarylene sulfide resin (A), followed by melting and kneading.

13. The composite structure according to claim 1 ,
wherein the maximum height roughness (Rz) of four random straight line points on the surface of the surface-roughened metal member using a stylus-type roughness meter based on ISO 4287 is 5 μm or more and 22 μm or less.

14. The method for producing a composite structure according to claim 4 ,
wherein the maximum height roughness (Rz) of four random straight line points on the surface of the surface-roughened metal member using a stylus-type roughness meter based on ISO 4287 is 5 μm or more and 22 μm or less.

Assignees

• Dainippon Ink & Chemicals

Inventors

• Nakamura Kenji
• HIWATASHI Kenta
• Kikuchi Hideaki

Classifications

• B29C66/72321 Primary

  consisting of metals or their alloys · CPC title

• B29C45/14

  incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles {(B29C45/1671 takes precedence)} · CPC title

• B29C65/405

  characterised by the composition of the applied molten plastics (B29C65/425 takes precedence) · CPC title

• B29C65/70 Primary

  by moulding (using a particular moulding technique, see the relevant technique {, e.g. by injection B29C45/14467}) · CPC title

• B32B15/082

  comprising vinyl resins; comprising acrylic resins · CPC title