Organic EL device as well as display apparatus, image pickup apparatus, communication apparatus, lighting apparatus, luminaire, and moving body each including the same

Patent metadata

Field	Value
Publication number	US-11997858-B2
Application number	US-202017139848-A
Country	US
Kind code	B2
Filing date	Dec 31, 2020
Priority date	Jul 5, 2018
Publication date	May 28, 2024
Grant date	May 28, 2024

Abstract

An organic EL device includes at least an anode, a first light-emitting layer, an intermediate layer, a second light-emitting layer, and a cathode in this order. The intermediate layer is adjacent to the first light-emitting layer and the second light-emitting layer. The first light-emitting layer and the second light-emitting layer can trap electrons. A material constituting the intermediate layer is a hydrocarbon that has a HOMO level equal to or lower than the HOMO level of a host of the first light-emitting layer and that has a high S1 level.

First claim

The invention claimed is:

1. An organic EL device comprising at least:
an anode;
a first light-emitting layer;
an intermediate layer;
a second light-emitting layer; and
a cathode in this order,
the intermediate layer being located between the first light-emitting layer and the second light-emitting layer,
wherein the first light-emitting layer contains a first host and a first dopant,
the second light-emitting layer contains a second host and a second dopant,
the intermediate layer contains an aromatic hydrocarbon compound,
the following relationship (a) is satisfied between the first host and the first dopant,
the following relationship (b) is satisfied between the second host and the second dopant,
the following relationship (c) is satisfied between the hydrocarbon compound of the intermediate layer and the first host, and
the following relationship (d) is satisfied between the second host and the hydrocarbon compound of the intermediate layer,
(a) LUMO (H1)>LUMO (D1)
(b) LUMO (H2)>LUMO (D2)
(c) HOMO (H1)≥HOMO (IL)
(d) HOMO (H2)>HOMO (IL)
wherein LUMO (H1), LUMO (D1), LUMO (H2), and LUMO (D2) in (a) to (d) denote LUMO energy levels of the first host, the first dopant, the second host, and the second dopant, respectively, and HOMO (H1), HOMO (H2), and HOMO (IL) denote HOMO energy levels of the first host, the second host, and the intermediate layer material, respectively.

2. The organic EL device according to claim 1 , wherein the intermediate layer has a lowest excited singlet energy level of 2.58 eV or more.

3. The organic EL device according to claim 1 , wherein the aromatic hydrocarbon compound is a compound in which at least two of aromatic hydrocarbons selected from the group consisting of benzene, naphthalene, fluorene, benzofluorene, phenanthrene, anthracene, chrysene, triphenylene, pyrene, fluoranthene, and benzofluoranthene are bonded to form a molecular structure.

4. The organic EL device according to claim 1 , wherein the first host and the second host are hydrocarbons.

5. The organic EL device according to claim 1 , wherein the first dopant and the second dopant are dopants that fluoresce.

6. The organic EL device according to claim 1 , wherein the first dopant and the second dopant are compounds that have a fluoranthene skeleton and have no substituted amino group.

7. The organic EL device according to claim 1 , further comprising a third light-emitting layer adjacent to the second light-emitting layer between the second light-emitting layer and the cathode,
wherein the third light-emitting layer contains a third host and a third dopant that fluoresces, and
the following relationship (e) is satisfied between the third host and the third dopant,
(e) LUMO (H3)>LUMO (D3)
wherein LUMO (H3) and LUMO (D3) in (e) denote LUMO energy levels of the third host and the third dopant, respectively.

8. The organic EL device according to claim 7 , wherein the first dopant emits red light, one of the second dopant and the third dopant emits blue light, and the other of the second dopant and the third dopant emits green light.

9. The organic EL device according to claim 1 , further comprising a third light-emitting layer adjacent to the first light-emitting layer between the anode and the first light-emitting layer,
wherein the third light-emitting layer contains a third host and a third dopant that fluoresces, and
the following relationship (e) is satisfied between the third host and the third dopant,
(e) LUMO (H3)>LUMO (D3)
wherein LUMO (H3) and LUMO (D3) in (e) denote LUMO energy levels of the third host and the third dopant, respectively.

10. The organic EL device according to claim 9 , wherein the first dopant emits green light, the second dopant emits blue light, and the third dopant emits red light.

11. The organic EL device according to claim 1 , wherein the first light-emitting layer contains a third dopant that fluoresces, and
the following relationship (f) is satisfied between the first host and the third dopant,
(f) LUMO (H1)>LUMO (D3)
wherein LUMO (D3) in (f) denotes a LUMO energy level of the third dopant.

12. The organic EL device according to claim 11 , wherein the second dopant emits blue light, one of the first dopant and the third dopant emits red light, and the other of the first dopant and the third dopant emits green light.

13. The organic EL device according to claim 7 , wherein the third host is a hydrocarbon.

14. The organic EL device according to claim 7 , wherein the third dopant is a compound that has a fluoranthene skeleton and has no substituted amino group.

15. The organic EL device according to claim 1 , wherein the following relationship (g) is satisfied between the first host and the first dopant,
(g) HOMO (H1)<HOMO (D1)
wherein HOMO (H1) and HOMO (D1) in (g) denote HOMO energy levels of the first host and the first dopant, respectively.

16. The organic EL device according to claim 1 , wherein the following relationship (h) is satisfied between the second host and the second dopant,
(h) HOMO (H2)>HOMO (D2)
wherein HOMO (H2) and HOMO (D2) in (h) denote HOMO energy levels of the second host and the second dopant, respectively.

17. The organic EL device according to claim 1 , wherein the following relationship (h) is satisfied between the first host and the first dopant,
(i) LUMO (H1)−LUMO (D1)>HOMO (D1)−HOMO (H1)
wherein HOMO (D1) in (i) denotes a HOMO energy level of the first dopant.

18. A display apparatus comprising a plurality of pixels, wherein each pixel has the organic EL device according to claim 1 and an active device coupled to the organic EL device.

19. A flexible display apparatus comprising:
a flexible substrate; and
a display unit on the flexible substrate,
wherein the display unit includes the organic EL device according to claim 1 and an active device coupled to the organic EL device.

20. An image pickup apparatus comprising:
an optical unit with a plurality of lenses;
an image pickup device for receiving light passing through the optical unit; and
a display unit for displaying an image,
wherein the display unit is a display unit for displaying an image taken with the image pickup device, and the display unit has the organic EL device according to claim 1 .

21. A communication apparatus comprising:
a display unit; and
a communication unit,
wherein the display unit has the organic EL device according to claim 1 .

22. A lighting apparatus comprising:
a light source; and
a light diffusing unit,
wherein the light source has the organic EL device according to claim 1 .

23. A lighting apparatus comprising:
a light source; and
an optical film on a light output side of the light source,
wherein the light source has the organic EL device according to claim 1 .

24. A luminaire comprising:
the organic EL device according to claim 1 ; and
a protective member for protecting the organic EL device.

25. A moving body comprising:
a body; and
a luminaire on the body,
wherein the luminaire has the organic EL device according to claim 1 .

Assignees

• Canon Kk

Inventors

• Miyashita Hirokazu
• Takaya Itaru
• Ito Takayuki
• Takahira MOE
• Yamaguchi Tomona
• Shiobara Satoru
• Kotake Tomokazu
• Iida Haruna
• Yamada Naoki
• Kamatani Jun

Classifications

• H10K50/11 Primary

  characterised by the electroluminescent [EL] layers · CPC title

• H04N23/53 Primary

  of electronic viewfinders, e.g. rotatable or detachable · CPC title

• F21S43/145

  Surface emitters, e.g. organic light emitting diodes [OLED] · CPC title

• H10K50/131

  with spacer layers between the electroluminescent layers · CPC title

• H10K50/19

  Tandem OLEDs · CPC title