Ageing-resistant rubber composition and processing method therefor and use thereof

Patent metadata

Field	Value
Publication number	US-11993703-B2
Application number	US-201917259926-A
Country	US
Kind code	B2
Filing date	Jun 25, 2019
Priority date	Jul 13, 2018
Publication date	May 28, 2024
Grant date	May 28, 2024

Abstract

Disclosed are an aging-resistant rubber composition and methods for processing and use thereof. The rubber composition includes a rubber matrix and compounding components. In parts by weight, every 100 parts of rubber matrix comprise 50-99 parts of a halogenated butyl rubber, 0-50 parts of a highly branched polyethylene P1, and 0-50 parts of P2 obtained by the polarization modification of said highly branched polyethylene P1. The sum of P1 and P2 in parts by weight is 1-50 parts; and the compounding components comprise a vulcanization system.

First claim

What is claimed is:

1. A rubber composition, comprising a rubber matrix and compounding components, wherein, in parts by weight, every 100 parts of said rubber matrix comprise 50-99 parts of a halogenated butyl rubber, 0-50 parts of a highly branched polyethylene P1, and 0-50 parts of P2 obtained by the polarization modification of said highly branched polyethylene P1, and the sum of P1 and P2 in parts by weight is 1-50 parts; and said compounding components comprise a vulcanization system.

2. The rubber composition according to claim 1 , wherein, the branching degree of said P1 is 60-130 branches/1000 carbon atoms.

3. The rubber composition according to claim 2 , wherein the branching degree of the P1 is 72-112 branches/1000 carbon atoms.

4. The rubber composition according to claim 1 , wherein, the polar monomer used for preparing said P2 comprises at least one of maleic anhydride (MAH), methacrylic acid (MA), acrylic acid (AA), itaconic acid (IA), fumaric acid (FA), isocyanate, glycidyl methacrylate (GMA), methyl methacrylate (MMA), dibutyl fumarate (DBF), β-hydroxyethyl methacrylate (HEMA), dibutyl maleate (DBM), diethyl maleate (DEM), elemental halogen, a halogen-containing compound, a sulfur-containing compound, vinyltrimethoxysilane (VTMS), vinyltriethoxysilane (VTES), 3-methacryloxypropyltrimethoxysilane (VMMS), styrene (St), α-methylstyrene (α-MSt), and acrylonitrile (AN).

5. The rubber composition according to claim 4 , wherein, said P2 is a halogen-containing branched polyethylene with a polar group which comprises at least one of a chlorine group, a bromine group, a chlorosulfonyl group, and a bromosulfonyl group.

6. The rubber composition according to claim 5 , wherein, the mass percentage of halogen in said halogen-containing branched polyethylene is 0.2-50%, and said halogen-containing branched polyethylene comprises at least one of chlorinated branched polyethylene, brominated branched polyethylene, and chlorosulfonated branched polyethylene.

7. The rubber composition according to claim 6 , wherein, the mass percentage of chlorine in said chlorinated branched polyethylene or said chlorosulfonated branched polyethylene is 0.5-45.5%, and the mass percentage of bromine in said brominated branched polyethylene is 0.8-4%.

8. The rubber composition according to claim 1 , wherein, based on 100 parts by weight of said rubber matrix, said rubber composition further comprises up to 30 parts of an ethylene propylene diene monomer rubber.

9. The rubber composition according to claim 1 , wherein, said vulcanization system is selected from at least one of a peroxide vulcanization system, a sulfur vulcanization system, a thiourea vulcanization system, a metal oxide vulcanization system, and a radiation vulcanization sensitization system.

10. The rubber composition according to claim 9 , wherein, said vulcanization system is a peroxide vulcanization system, and based on 100 weight parts of said rubber matrix, the usage amount of peroxides is 1-10 weight parts, and a peroxide crosslinking agent is at least one of di-tert-butyl peroxide, dicumyl peroxide, tert-butyl cumyl peroxide, 1,1-di(tert-butylperoxy)-3,3,5-trimethylcyclohexane, 2,5-dimethyl-2,5-di(tert-butylperoxy)hexane, 2,5-dimethyl-2,5-di(tert-butylperoxy)-3-hexyne, bis(tert-butylperoxyisopropyl)benzene, 2,5-dimethyl-2,5-bis(benzoylperoxy)hexane, tert-butyl peroxybenzoate, and tert-butylperoxy-2-ethylhexyl carbonate.

11. The rubber composition according to claim 10 , wherein, said peroxide vulcanization system further comprises 0.2-20 parts by weight of an auxiliary crosslinking agent, and said auxiliary crosslinking agent comprises at least one of triallyl cyanurate, triallyl isocyanurate, ethylene glycol dimethacrylate, triethylene glycol dimethacrylate, triallyl trimellitate, trimethylolpropane trimethacrylate, N,N′-m-phenylene bismaleimide, N,N′-bis(furfurylidene) acetone, 1,2-polybutadiene, an unsaturated carboxylic acid metal salt, and sulfur.

12. The rubber composition according to claim 1 , wherein, based on 100 parts by weight of said rubber matrix, said compounding components further comprise 10-200 parts of a reinforcing filler, 0-80 parts of a plasticizer, 3-30 parts of a metal oxide, 0-3 parts of stearic acid, 0-15 parts of a surface modifier, 0-6 parts of a stabilizer, 0-15 parts of a tackifier, 0-20 parts of an adhesive, 0-150 parts of a flame-retardant agent, 0-20 parts of a foaming agent, and 0-40 parts of an air-blocking agent.

13. A conveyor belt, comprising a covering rubber layer for working surface, a covering rubber layer for non-working surface, and a tensile layer provided between said covering rubber layer for working surface and said covering rubber layer for non-working surface, wherein, the rubber used for at least one of said covering rubber layer for working surface and said covering rubber layer for non-working surface comprises said rubber composition according to claim 1 .

14. A tire, comprising an inner liner, wherein, the rubber used in said inner liner comprises said rubber composition according to claim 1 .

Assignees

• Hangzhou Xinglu Tech Co Ltd
• Univ Zhejiang

Inventors

• Xu Tao
• Fu zhi sheng
• Wu An Yang

Classifications

• C08L23/286 Primary

  Chlorinated polyethylene · CPC title

• B60C1/0008

  Compositions of the inner liner · CPC title

• B65G15/32

  made of rubber or plastics · CPC title

• C08K3/06

  Sulfur · CPC title

• C08K3/22

  of metals · CPC title