Light-curable compositions useful for forming composite materials
US-2022213245-A1 · Jul 7, 2022 · US
US11993004B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11993004-B2 |
| Application number | US-202017641289-A |
| Country | US |
| Kind code | B2 |
| Filing date | Sep 24, 2020 |
| Priority date | Sep 27, 2019 |
| Publication date | May 28, 2024 |
| Grant date | May 28, 2024 |
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A composition comprises a cyanoacrylate polymer and a protected amine. A method comprises: providing a shaped model comprising a cyanoacrylate polymer; preparing an investment having a cavity that corresponds to the shaped model; and heating the shaped model to sufficient temperature that the cyanoacrylate polymer depolymerizes and volatilizes. A hardenable material may be cast in the investment to provide a replica of the shaped model. A curable composition comprises: a cyanoacrylate monomer; a free-radical photoinitiator; and a protected amine, wherein the curable composition is free of compounds that initiate anionic polymerization of the cyanoacrylate monomer at ambient temperature. A method of curing the curable composition is also disclosed.
Opening claim text (preview).
What is claimed is: 1. A method comprising: making a shaped model comprising a cyanoacrylate polymer; preparing an investment that has a cavity corresponding to the shaped model; and heating the shaped model to sufficient temperature that the cyanoacrylate polymer depolymerizes and volatilizes, wherein the shaped model is formed by an additive manufacturing process comprising successively curing superposed layers of a curable composition comprising: a cyanoacrylate monomer, a free-radical initiator, and a protected amine, and wherein the curable composition is free of unprotected amine. 2. The method of claim 1 , wherein the additive manufacturing process comprises a stereolithographic process, and wherein the free-radical initiator comprises a free-radical photoinitiator.
using layers of liquid which are selectively solidified · CPC title
Processes of additive manufacturing · CPC title
Materials specially adapted for additive manufacturing · CPC title
Products made by additive manufacturing · CPC title
Use of polyacetylene or cyanic ester resins, i.e. polymers having one or more carbon-to-carbon triple bonds or derivatives thereof, as moulding material · CPC title
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