Carbon fiber precursors and production process

Patent metadata

Field	Value
Publication number	US-11987707-B2
Application number	US-202017633465-A
Country	US
Kind code	B2
Filing date	Aug 4, 2020
Priority date	Aug 6, 2019
Publication date	May 21, 2024
Grant date	May 21, 2024

Abstract

A new class of cost-effective carbon fiber precursors that comprise both hydrocarbon polymer and Pitch structural features in the same polymer structure to exhibit complementary advantages of both PAN- and Pitch-based carbon fiber precursors. The new class of carbon fiber precursors comprise a polymeric pitch copolymer, wherein the polymeric pitch copolymer includes a polymer chain and several pitch polycyclic aromatic hydrocarbon (PAH) molecules grafted or chemically bonded to the polymer chain. Method and processes for the creation of the new class of carbon fiber precursors are also presented, wherein said methods may comprise a thermally-induced coupling and extrusion step.

First claim

We claim:

1. A carbon fiber precursor material comprising a polymeric pitch copolymer, wherein the polymeric pitch copolymer comprises a polymer chain and polycyclic aromatic hydrocarbon molecules in the side chains.

2. The carbon fiber precursor material of claim 1 , further comprising free pitch resin.

3. The carbon fiber precursor material of claim 1 , wherein the polymer chain comprises either polyethylene (PE), polypropylene, poly(l-butene), poly(l-pentene), poly(l-hexene), polystyrene, poly(methylstyrene), poly(isobutylene), polybutadiene, polyisoprene, polyacetylene, poly(phenylacetylene), or their copolymers.

4. The carbon fiber precursor material of claim 1 , wherein the polymeric pitch copolymer possesses a weight-average molecular weight ranged from 30,000 to 2,000,000 g/mol.

5. The carbon fiber precursor material of claim 1 , wherein the polymeric pitch copolymer possesses a polydispersity index between 1.1 and 20.

6. The carbon fiber precursor material of claim 1 , wherein the polycyclic aromatic hydrocarbon molecules possess a molecular weight range from 160 to 1200 g/mol.

7. The carbon fiber precursor material of claim 1 , wherein the polycyclic aromatic hydrocarbon molecules are either diphenylacetylene, anthracene, phenanthrene, tetracene, chrysene, triphenylene, pyrene, pentacene, benzo[a]pyrene, corannulene, benzoperylene, coronene, ovalene or their derivatives, and their mixtures.

8. The carbon fiber precursor material of claim 1 , wherein the concentration of polycyclic aromatic hydrocarbon molecules in the polymeric pitch copolymer may be from 3 mol % to 100 mol %.

9. The carbon fiber precursor material of claim 2 , wherein the weight ratio between the polymeric pitch copolymer and the free pitch resin is from 100/0 to 1/100.

10. The carbon fiber precursor material of claim 1 , wherein the polymer chain comprises polyethylene (PE) and the polymeric pitch copolymer is represented by the following formula:

wherein x can be an integer repeating units ranging from 0 to 50,000, and
wherein y can be an integer repeating units ranging from 10 to 10,000.

11. The carbon fiber precursor material of claim 10 , further comprising free pitch resin.

12. The carbon fiber precursor material of claim 10 , wherein the polycyclic aromatic hydrocarbon molecules possess a molecular weight range from 160 to 1200 g/mol.

13. The carbon fiber precursor material of claim 10 , wherein the polycyclic aromatic hydrocarbon molecule is diphenylacetylene.

14. The carbon fiber precursor material of claim 10 , wherein the concentration of polycyclic aromatic hydrocarbon molecules in the polymeric pitch copolymer may be from 2 mol % to 100 mol %.

15. The carbon fiber precursor material of claim 1 , wherein the polymer chain comprises poly(phenylacetylene) and the polymeric pitch copolymer is represented by the following formula:

wherein x can be an integer repeating units ranging from 0 to 20,000, and
wherein y can be an integer repeating units ranging from 10 to 10,000.

16. The carbon fiber precursor material of claim 15 , further comprising free pitch resin.

17. The carbon precursor material of claim 15 , wherein the polycyclic aromatic hydrocarbon molecules possess a molecular weight range from 160 to 1200 g/mol.

18. The carbon fiber precursor material of claim 15 , wherein the polycyclic aromatic hydrocarbon molecule is diphenylacetylene.

19. The carbon fiber precursor material of claim 10 , wherein the concentration of polycyclic aromatic hydrocarbon molecules in the polymeric pitch copolymer may be from 2 mol % to 100 mol %.

20. A method for the synthesis of a carbon fiber precursor material comprising:
adding pitch resin to a polymer chain to form a mixture;
stirring the mixture under elevated temperature conditions until the formation of a polymeric pitch copolymer is complete,
wherein the polymer chain possesses reactive groups capable of grafting with the polycyclic aromatic hydrocarbon molecules in pitch resin.

21. The method of claim 20 , wherein the monomer units containing reactive groups contribute 1% to 100% towards the total weight of the polymer chain.

22. The method of claim 20 , wherein the method further comprises processing the polymeric pitch copolymer by melt-spinning and wet-spinning techniques to produce precursor microfibers.

23. The method of claim 20 , wherein the polymeric pitch copolymer also contains free pitch resin.

Assignees

• Penn State Res Found

Inventors

• Chung Tze-Chiang
• Li Houxiang

Classifications

• C08L95/00 Primary

  Compositions of bituminous materials, e.g. asphalt, tar, pitch · CPC title

• C01B32/05

  Preparation or purification of carbon not covered by groups C01B32/15, C01B32/20, C01B32/25, C01B32/30 · CPC title

• C08F10/02

  Ethene · CPC title

• C08F38/02

  Acetylene · CPC title

• D01D5/06

  Wet spinning methods {(D01D5/0046 takes precedence)} · CPC title