Catalyst compositions and their use in aromatic alkylation processes

Patent metadata

Field	Value
Publication number	US-11986807-B2
Application number	US-202318299212-A
Country	US
Kind code	B2
Filing date	Apr 12, 2023
Priority date	Feb 28, 2017
Publication date	May 21, 2024
Grant date	May 21, 2024

Abstract

Catalyst composition which comprises a first zeolite having a BEA* framework type and a second zeolite having a MOR framework type and a mesopore surface area of greater than 30 m 2 /g is disclosed. These catalyst compositions are used to remove catalyst poisons from untreated feed streams having one or more impurities which cause deactivation of the downstream catalysts employed in hydrocarbon conversion processes, such as those that produce mono-alkylated aromatic compounds.

First claim

The invention claimed is:

1. A catalyst composition comprising (i) a first zeolite having a BEA* framework type and (ii) a second zeolite having a MOR framework type, wherein the second zeolite has a mesopore surface area of greater than 30 m 2 /g as measured by BET, and wherein the second zeolite comprises EMM-34, UZM-14, or a combination thereof.

2. The catalyst composition of claim 1 , wherein said first zeolite is zeolite beta.

3. The catalyst composition of claim 1 , wherein said second zeolite is EMM-34.

4. The catalyst composition of claim 3 , wherein said second zeolite comprising agglomerates of primary crystallites, wherein said primary crystallites have an average primary crystal size of less than 80 nm in each of the a, b and c crystal vectors as measured by X-ray diffraction and an aspect ratio of less than 2, wherein the aspect ratio is defined as the longest dimension of the crystallite divided by the width of the crystallite, wherein said width of the crystallite is defined as the dimension of the crystallite in the middle of that longest dimension in a direction orthogonal to that longest dimension, as measured by TEM.

5. The catalyst composition of claim 4 , wherein said EMM-34 has a ratio of the mesopore surface area to the total surface area of greater than 0.05.

6. The catalyst composition of claim 5 , wherein the Si/Al 2 molar ratio of said second zeolite is in a range of 10 to 60.

7. The catalyst composition of claim 6 , wherein said catalyst composition has a collidine uptake in a range of 550 moles/g to 1500 moles/g.

8. The catalyst composition of claim 7 , wherein a ratio of said first zeolite to said second zeolite is in a range of 90:10 to 50:50 by weight of the catalyst composition.

9. The catalyst composition of claim 8 , wherein said first zeolite and said second zeolite are co-crystallized or co-extruded.

10. The catalyst composition of claim 1 , wherein the second zeolite is selected from the group consisting of UZM-14, EMM-34, or a combination thereof.

11. The catalyst composition of claim 1 , wherein said second zeolite comprises EMM-34.

12. The catalyst composition of claim 11 , wherein said second zeolite further comprises UZM-14.

13. The catalyst composition of claim 1 , wherein said second zeolite comprises UZM-14.

14. A method for removing impurities from a hydrocarbon stream, the method comprising the steps of:
(a) supplying a portion of a feed stream and a guard bed catalyst, said feed stream comprising one or more hydrocarbons and undesirable impurities, said impurities comprise at least one compound having at least one of the following elements: nitrogen, halogens, oxygen, sulfur, arsenic, selenium, tellurium, phosphorus, and Group 1 through Group 12 metals, said guard bed catalyst comprises the catalyst composition of claim 1 ; and
(b) contacting said portion of said feed stream with said guard bed catalyst to remove at least a portion of said impurities and produce a treated feed stream having a reduced amount of impurities.

15. The method of claim 14 , wherein said feed stream and said guard bed are supplied to a guard bed for contacting therein.

Assignees

• Exxonmobil Technology & Engineering Company
• Exxonmobil Engineering & Tech Company

Inventors

• Ide Matthew S
• Levin Doron
• Lai Wenyih F
• Johnson Ivy D
• Weigel Scott J
• Loveless Brett T

Classifications

• Y02P20/52

  using catalysts, e.g. selective catalysts · CPC title

• C07C2529/70

  of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65 · CPC title

• C07C2529/80

  Mixtures of different zeolites · CPC title

• C07C2529/18

  of the mordenite type · CPC title

• B01J2220/42

  Materials comprising a mixture of inorganic materials (materials coated or impregnated on a carrier B01J20/32) · CPC title