In-situ polyphosphazene generation in cement for improved elastic properties

Patent metadata

Field	Value
Publication number	US-11981601-B2
Application number	US-202117141783-A
Country	US
Kind code	B2
Filing date	Jan 5, 2021
Priority date	Jan 5, 2021
Publication date	May 14, 2024
Grant date	May 14, 2024

Abstract

A composition of matter may include a cement precursor, a phosphazene oligomer and water. A method may include blending a phosphazene oligomer and a cement precursor to form a cement precursor mixture. The method may then include introducing water into the cement precursor mixture to form the cement slurry. A composition of matter may include a cured cement matrix having a polyphosphazene polymer distributed throughout the cement matrix. A method may include cementing a wellbore by introducing a cement slurry into a wellbore, where the cement slurry includes a phosphazene oligomer. The method then includes maintaining the cement slurry such that a cured cement sheath forms, the cement sheath having a polyphosphazene polymer.

First claim

What is claimed:

1. A composition of matter comprising:
a cement precursor;
a cyclic phosphazene oligomer; and
water,
wherein the cyclic phosphazene oligomer is configured to undergo polymerization to form a polyphosphazene polymer upon curing of the cement precursor.

2. The composition of matter of claim 1 , where the cyclic phosphazene oligomer has the following structure:

where R is selected from the group consisting of aliphatic, aromatic, alkyl aromatic, and polyaromatic structures; and
where A and B are each reduced nucleophilic chemical functionalities of a di-functional compound.

3. The composition of matter of claim 2 , where the di-functional compound is selected from the group consisting of aliphatic diamines, aromatic diamines, aliphatic diols, aromatic diols, aliphatic thiols, aromatic thiols, mixed functional groups of aliphatic or aromatic di-functional compounds, and combinations thereof.

4. The composition of matter of claim 2 , where the di-functional compound is selected from the group consisting of o-phenylenediamine, trimethylamine, 2,3-diaminonaphthalene, ethylenediamine, ethylene glycol, 1,2-dihydroxy benzene, ethylene dithiol, benzene-1,2-dithiol, 2-mercaptophenol, 1-hydroxy-2-aminobenzene, 2-aminoethen-1-ol, and combinations thereof.

5. The composition of matter of claim 1 , where the cyclic phosphazene oligomer has a structure selected from the group consisting of:

and combinations thereof.

6. The composition of matter of claim 1 , where the cement precursor is a Portland cement precursor.

7. The composition of matter of claim 6 , where the Portland cement precursor is Class G Portland cement.

8. The composition of matter of claim 1 , where the cyclic phosphazene oligomer is in a range of from about 0.5 to about 6.0 wt. % by weight of cement precursor.

9. The composition of matter of claim 1 , comprising a ratio of cement:water in a range of from about 80:20 to about 40:60.

10. The composition of matter of claim 1 , further comprising a suspending agent.

11. The composition of matter of claim 10 , where the suspending agent is in a range of from about 0.1 to about 3.0 wt. % (weight percent) by weight of cement precursor.

12. The composition of matter of claim 1 , having a plastic viscosity in a range of from about 40 to 100 cP (centipoise) in a range of from 70 to 180° F.

13. The composition of matter of claim 1 , having a yield point in a range of from 75 to 125 lb f /100 ft 2 (pounds of force per 100 square feet) at a temperature in a range of from 70 to 180° F.

14. A method of making a cement slurry comprising:
blending a phosphazene oligomer and a cement precursor to form a cement precursor mixture;
introducing water into the cement precursor mixture to form the cement slurry; and
polymerizing the cyclic phosphazene oligomer upon curing of the cement precursor, thereby forming a polyphosphazene polymer in a cement matrix.

15. The method of claim 14 , where the blending step comprises blending the phosphazene oligomer and the cement precursor with a suspending agent to form the cement precursor mixture.

16. The method of claim 14 , where the phosphazene oligomer has the following structure:

where R is selected from the group consisting of aliphatic, aromatic, alkyl aromatic, and polyaromatic structures; and
where A and B are each reduced nucleophilic chemical functionalities of a di-functional compound.

17. The method of claim 16 , where the di-functional compound is selected from the group consisting of aliphatic diamines, aromatic diamines, aliphatic diols, aromatic diols, aliphatic thiols, aromatic thiols, mixed functional groups of aliphatic or aromatic di-functional compounds, and combinations thereof.

18. The method of claim 16 , where the di-functional compound is selected from the group consisting of o-phenylenediamine, trimethylamine, 2,3-diaminonaphthalene, ethylenediamine, ethylene glycol, 1,2-dihydroxy benzene, ethylene dithiol, benzene-1,2-dithiol, 2-mercaptophenol, 1-hydroxy-2-aminobenzene, 2-aminoethen-1-ol, and combinations thereof.

19. The method of claim 14 , where the cyclic phosphazene oligomer has a structure selected from the group consisting of:

and combinations thereof.

Assignees

• Aramco Services Co
• Saudi Arabian Oil Co

Inventors

• Patel Hasmukh A

Classifications

• C04B16/0675 Primary

  from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds · CPC title

• C04B7/02

  Portland cement · CPC title

• C04B28/04

  Portland cements · CPC title

• C08G79/025

  Polyphosphazenes · CPC title

• C09K8/467

  containing additives for specific purposes · CPC title