Epoxidation processes and catalysts for use therein

Patent metadata

Field	Value
Publication number	US-11980872-B2
Application number	US-202016931677-A
Country	US
Kind code	B2
Filing date	Jul 17, 2020
Priority date	Aug 28, 2015
Publication date	May 14, 2024
Grant date	May 14, 2024

Abstract

Epoxidation methods and catalyst are described herein. The epoxidation catalysts generally include a metal component including silver and a support material including kaolinite, wherein the epoxidation catalyst includes less than 55 wt. % metal component.

First claim

What is claimed is:

1. A method comprising:
carrying out selective oxidation, in the vapor phase, of an olefinic compound with molecular oxygen to produce an epoxide, wherein the selective oxidation is carried out in the presence of an epoxidation catalyst, and wherein the epoxidation catalyst comprises: (i) more than 5 wt. % to 80 wt. % of a metal component and (ii) a support comprising a phyllosilicate,
wherein the olefinic compound and the epoxidation catalyst are introduced to a reaction vessel via an input stream prior to introducing the molecular oxygen to the reaction vessel.

2. The method of claim 1 , wherein the phyllosilicate is kaolinite.

3. The method of claim 1 , wherein the phyllosilicate has the chemical formula: Mg 3 Si 2 O 5 (OH) 4 .

4. The method of claim 1 , wherein the phyllosilicate has the chemical formula: X 2 Y 4 -6Z 8 O 10 (OH,F) 4 , wherein the X is selected from: K, Na, Ca, or other Group I or Group II metals; Y is selected from: Al, Mg, and Fe; Z is selected from Si, A, Fe 3+ , and Ti.

5. The method of claim 1 , wherein the support comprises one or more components selected from the group consisting of: metal oxides and alkaline earth carbonates.

6. The method of claim 3 , wherein the metal oxide is selected from the group consisting of: alumina, silica titania, zirconia, and mixtures thereof.

7. The method of claim 1 , wherein the metal component is silver.

8. The method of claim 1 , wherein the olefinic compound is selected from the group consisting of: ethylene, propylene, butene, and combinations thereof.

9. The method of claim 1 , wherein the metal component is present in the range of 5 wt. % to 50 wt. % based on the total weight of the epoxidation catalyst.

10. The method of claim 1 , wherein epoxidation catalyst further comprises a Group I metal salt.

11. The method of claim 10 , wherein Group I metal salt is selected from the group consisting of: lithium nitrate, sodium nitrate, potassium nitrate, or combinations thereof.

12. The method of claim 10 , wherein the Group I metal salt is present in the range of 0.01 wt. % to 10 wt. % based on the total weight of the epoxidation catalyst.

13. The method of claim 1 , wherein the epoxidation catalyst additionally comprises a promoter selected from the group consisting of: rhenium, molybdenum, tungsten, iron, nickel, copper, zinc, scandium, ytterbium, or combinations thereof, and wherein the promoter is present in the range of from 0.01 wt. % to 10 wt. % based on the total weight of the epoxidation catalyst.

14. The method of claim 1 , wherein the olefinic compound is introduced into an epoxidation reactor where the selective oxidation is carried out in an amount in the range of 0.1 vol. % to 50 vol. % based on a total volume of reaction mixture.

15. The method of claim 1 , wherein the olefinic compound and molecular oxygen are reacted at a temperature in the range of 100° C. to 500° C. and a pressure in the range of 1 barg to 30 barg.

16. The method of claim 1 , wherein the molecular oxygen is introduced into an epoxidation reactor wherein the selective oxidation is carried out in an amount in the range of 1 vol. % to 11 vol. % based on a total volume of reaction mixture.

Assignees

• Lyondell Chemical Tech Lp

Inventors

• Nagy Sandor
• Kimmich Barbara

Classifications

• B01J23/66 Primary

  Silver or gold · CPC title

• B01J21/16

  Clays or other mineral silicates · CPC title

• B01J23/50

  Silver · CPC title

• B01J23/688

  with manganese, technetium or rhenium · CPC title

• B01J35/19

  Catalysts containing parts with different compositions · CPC title