Spark plug housing having a galvanic nickel and zinc-containing protective layer and a silicon-containing sealing layer, spark plug having said housing, and method for producing said housing

Patent metadata

Field	Value
Publication number	US-11979003-B2
Application number	US-202017436522-A
Country	US
Kind code	B2
Filing date	Mar 18, 2020
Priority date	Mar 20, 2019
Publication date	May 7, 2024
Grant date	May 7, 2024

Abstract

The disclosure relates to a housing for a spark plug, having a bore along the longitudinal axis X of the housing, the housing comprises an outer side and an inner side and a galvanically applied nickel and zinc-containing protective layer is arranged on at least one part of the outer side of the housing. A sealing layer, which contains silicon, is arranged on the nickel and zinc-containing protective layer.

First claim

The invention claimed is:

1. A housing for a spark plug, the housing having an outer side and an inner side, comprising:
a bore defined by the inner side and extending along a longitudinal axis of the housing;
an electrochemically applied nickel- and zinc-containing protective layer disposed on at least part of the outer side of the housing; and
a sealing layer disposed on the nickel- and zinc-containing protective layer, wherein the sealing layer comprises silicon and is formed by silanization.

2. The housing as claimed in claim 1 , wherein the sealing layer is free from chromium.

3. The housing as claimed in claim 1 , wherein the sealing layer has a layer thickness of 10 nm to 10 μm.

4. The housing as claimed in claim 3 , wherein the sealing layer has a layer thickness of 100 nm to 1 μm.

5. The housing as claimed in claim 1 , wherein the nickel- and zinc-containing protective layer has a layer thickness of 1 μm to 30 μm on the housing.

6. The housing as claimed in claim 1 , wherein at least one of a first interlayer is applied between the housing and the nickel- and zinc-containing protective layer, a second interlayer is applied between the nickel- and zinc-containing protective layer and the sealing layer, and an outer layer is applied on the sealing layer.

7. The housing as claimed in claim 6 , wherein:
the first interlayer is applied between the housing and the nickel- and zinc-containing protective layer; and
the first interlayer has a layer thickness of 1 nm to 1000 nm.

8. The housing as claimed in claim 6 , wherein:
the second interlayer is applied between the nickel- and zinc-containing protective layer and the sealing layer; and
the second interlayer has a layer thickness of 1 nm to 1000 nm.

9. The housing as claimed in claim 6 , wherein:
the outer layer is applied on the sealing layer; and
the outer layer has a layer thickness of 1 nm to 2000 nm.

10. The housing as claimed in claim 6 , wherein:
the nickel- and zinc-containing protective layer and the sealing layer are formed on the entire outer side of the housing;
the nickel- and zinc-containing protective layer and the sealing layer are formed on at least part of the inner side of the housing; and
the at least one of the first interlayer, the second interlayer, and the outer layer are formed on the entire outer side of the housing, and on the at least part of the inner side of the housing.

11. A spark plug, comprising:
a housing as claimed in claim 1 ;
an insulator disposed in the housing;
a central electrode disposed in the insulator; and
a ground electrode disposed on a combustion chamber-side end of the housing, wherein the ground electrode and the central electrode are configured to constitute a spark gap.

12. A method for producing a housing as claimed in claim 1 , comprising:
providing a housing for a spark plug having a nickel- and zinc-containing protective layer applied to the housing by means of an electrochemical coating process, and a second interlayer;
washing the provided housing coated with the nickel- and zinc-containing protective layer; and
forming a sealing layer on the washed nickel- and zinc-containing protective layer and the second interlayer by silanization.

13. The method for producing a housing as claimed in claim 12 , further comprising:
cleaning a surface of the housing coated with at least the nickel- and zinc-containing protective layer before washing the provided housing.

14. The method for producing a housing as claimed in claim 12 , further comprising:
drying the housing after forming the sealing layer to remove at least one of water and solvents from the application of the sealing layer from a surface of the housing.

15. The method for producing a housing as claimed in claim 14 , further comprising:
curing the sealing layer during polycondensation and after drying the housing.

16. The method for producing a housing as claimed in claim 12 , further comprising:
applying an outer layer to the sealing layer.

17. The method for producing a housing as claimed in claim 12 , wherein the sealing layer is formed using a coating technique selected from the group consisting of a sol-gel operation, CCVD and PVD.

18. The method for producing a housing as claimed in claim 12 , wherein silanes with functionalization selected from the group consisting of alkoxysilanes, aminosilanes, and acrylosilanes, are used for the sealing layer.

19. The method for producing a housing as claimed in claim 18 , wherein silanes without functionalization selected from the group consisting of alkyltrialkoxysilanes are also used for the sealing layer.

Assignees

• Bosch Gmbh Robert

Inventors

• Nufer Stefan
• Hirte Tina

Classifications

• H01T13/06 Primary

  Covers forming a part of the plug and protecting it against adverse environment · CPC title

• C25D3/562

  containing more than 50% by weight of iron or nickel or cobalt · CPC title

• C25D7/003 Primary

  Threaded pieces, e.g. bolts or nuts · CPC title

• H01T21/02

  of sparking plugs · CPC title

• H01T13/32

  characterised by features of the earthed electrode · CPC title