Gas detection device and gas detection method

Patent metadata

Field	Value
Publication number	US-11977007-B2
Application number	US-202017264868-A
Country	US
Kind code	B2
Filing date	May 1, 2020
Priority date	May 17, 2019
Publication date	May 7, 2024
Grant date	May 7, 2024

Abstract

Siloxane compounds are removed from the atmospheres by silica supporting an organic sulfonic acid compound. The silica with the organic sulfonic acid compound has a specific surface area down to 500 m 2 /g and up to 750 m 2 /g and a pore volume down to 0.8 m 3 /g and up to 1.2 m 3 /g, both measured by nitrogen gas adsorption method and has a pore diameter down to 4 nm and up to 8 nm, at the peak of differential pore volume measured by nitrogen gas adsorption method. The durability of gas sensing element against siloxanes is improved.

First claim

The invention claimed is:

1. A gas detection device comprising:
a filter removing siloxane; and
a gas sensing element sensing a gas in an atmosphere permeated said filter, characterized in that
said filter includes silica supporting an organic sulfonic acid compound and that said silica supporting the organic sulfonic acid compound has a specific surface area not less than 550 m 2 /g and not larger than 750 m 2 /g and pores having a pore volume not less than 0.9 cm 3 /g and not larger than 1.2 cm 3 /g, both measured by nitrogen gas adsorption method, and a pore diameter not less than 4 nm and not larger than 8 nm at a peak of differential pore volume measured by nitrogen gas adsorption method, and
the organic sulfonic acid compound has a molecular radius smaller than half the pore diameter of the silica, and is adsorbed and retained within a surface of the pores.

2. The gas detection device according to claim 1 , characterized in that said silica supporting the organic sulfonic acid compound has pore diameters at which differential pore volume is half of differential pore volume at said peak at a point smaller than 2 nm and another point larger than 8 nm and not larger than 12 nm.

3. The gas detection device according to claim 1 , characterized in that said silica supporting the organic sulfonic acid compound has a specific surface area not less than 570 m 2 /g and not larger than 750 m 2 /g and a pore volume not less than 0.93 cm 3 /g and not larger than 1.2 cm 3 /g, both measured by nitrogen gas adsorption method.

4. The gas detection device according to claim 1 , characterized in that the organic sulfonic acid compound has an adsorption amount of D4 (octa-methyl-cyclo-tetra-silane) not less than 0.25 mmol/g and not larger than 1.5 mmol/g at a relative pressure (a ratio of D4 pressure and saturated pressure of D4) of 0.2 in an adsorption isotherm of D4 measured at 295 K in a region of at least 0 to 0.6 of the relative pressure.

5. A gas detection method comprising:
removing siloxane compounds from an ambient atmosphere by a siloxane removing filter and detecting a gas in an atmosphere permeated said filter, characterized in that
said filter includes silica supporting an organic sulfonic acid compound and that said silica supporting the organic sulfonic acid compound has a specific surface area not less than 550 m 2 /g and not larger than 750 m 2 /g and pores having a pore volume not less than 0.9 cm 3 /g and not larger than 1.2 cm 3 /g, both measured by nitrogen gas adsorption method, and a pore diameter not less than 4 nm and not larger than 8 nm at a peak of differential pore volume measured by nitrogen gas adsorption method, and
the organic sulfonic acid compound has a molecular radius smaller than half the pore diameter of the silica, and is adsorbed and retained within a surface of the pores.

6. The gas detection method according to claim 5 , characterized in that said silica supporting the organic sulfonic acid compound has pore diameters at which differential pore volume is half of differential pore volume at said peak at a point smaller than 2 nm and at another point larger than 8 nm and not larger than 12 nm.

7. The gas detection device according to claim 2 , characterized in that said silica supporting the organic sulfonic acid compound has a specific surface area not less than 570 m 2 /g and not larger than 750 m 2 /g and a pore volume not less than 0.93 cm 3 /g and not larger than 1.2 cm 3 /g.

8. The gas detection device according to claim 2 , characterized in that the organic sulfonic acid compound has an adsorption amount of D4 (octa-methyl-cyclo-tetra-silane) not less than 0.25 mmol/g and not larger than 1.5 mmol/g at a relative pressure (a ratio of D4 pressure and saturated pressure of D4) of 0.2 in an adsorption isotherm of D4 measured at 295 K in a region of at least 0 to 0.6 of the relative pressure.

9. The gas detection device according to claim 7 , characterized in that the organic sulfonic acid compound has an adsorption amount of D4 (octa-methyl-cyclo-tetra-silane) not less than 0.25 mmol/g and not larger than 1.5 mmol/g at a relative pressure (a ratio of D4 pressure and saturated pressure of D4) of 0.2 in an adsorption isotherm of D4 measured at 295 K in a region of at least 0 to 0.6 of the relative pressure.

Assignees

• Figaro Eng
• New Cosmos Electric Co
• Univ Osaka Public Corp

Inventors

• Takeuchi Masato
• FURUNO Junpei
• Fukui Kenta
• Yoshioka Kenichi
• Tanihira Tatsuya
• Sai Masakazu
• Taniguchi Takafumi
• Mitsuhashi Hirokazu

Classifications

• G01N1/2205 Primary

  with filters · CPC title

• B01D53/0407

  Constructional details of adsorbing systems · CPC title

• B01J20/22

  comprising organic material · CPC title

• B01J20/28064

  being in the range 500-1000 m2/g · CPC title

• B01J20/28073

  being in the range 0.5-1.0 ml/g · CPC title