Method for manufacturing an environmental barrier

Patent metadata

Field	Value
Publication number	US-11976355-B2
Application number	US-202118246118-A
Country	US
Kind code	B2
Filing date	Sep 20, 2021
Priority date	Sep 29, 2020
Publication date	May 7, 2024
Grant date	May 7, 2024

Abstract

A method for producing a part having improved resistance to oxidation and high temperature-corrosion, includes the formation of an environmental barrier coating on an at least partially ceramic matrix composite material, the environmental barrier coating being formed by direct liquid injection-metal organic chemical vapor deposition.

First claim

The invention claimed is:

1. A method for producing a part having improved resistance to oxidation and high temperature-corrosion, comprising forming an environmental barrier coating on an at least partially ceramic matrix composite material, said environmental barrier coating being formed by at least one molecular precursor in a gas state, by direct liquid injection-metal organic chemical vapor deposition, wherein, in the direct liquid injection-metal organic chemical vapor deposition, the at least one molecular precursor of the environmental barrier coating to be obtained is injected in the form of liquid droplets into an expansion chamber to be vaporized and thus form a vapor phase comprising the at least one molecular precursor in the gas state, and wherein said vapor phase is entrained towards a reaction chamber in which the composite material is present, said composite material being heated to a temperature sufficient to allow the decomposition of the at least one molecular precursor in the gas state to form the environmental barrier coating on the composite material.

2. The method according to claim 1 , wherein the environmental barrier coating comprises a rare earth silicate and is formed at least from an alkoxysilane silicon oxide precursor and a rare earth beta-diketonate rare earth oxide precursor in the presence of an oxygen-supplying gas source.

3. The method according to claim 1 , wherein the nature and/or the relative proportions of molecular precursors are modified during the formation of the environmental barrier coating so as to give the environmental barrier coating a changing composition.

4. The method according to claim 3 , wherein forming the environmental barrier coating comprises at least forming a first portion comprising a rare earth disilicate, and forming a second portion comprising a rare earth monosilicate over the first portion.

5. The method according to claim 3 , wherein forming the environmental barrier coating comprises at least forming a first portion comprising a rare earth monosilicate, and forming a second portion comprising a rare earth disilicate over the first portion.

6. The method according to claim 3 , wherein forming the environmental barrier coating comprises at least forming a first portion comprising a first rare earth silicate, and forming a second portion comprising a second rare earth silicate, different from the first rare earth, the first and second portions being superimposed.

7. The method according to claim 1 , wherein a thickness of the environmental barrier coating is less than or equal to 1000 μm.

8. The method according to claim 1 , wherein the method further comprises depositing a bonding coating comprising silicon on an external surface of the at least partially ceramic matrix composite material, and wherein the environmental barrier coating is deposited on said bonding coating.

9. The method according to claim 8 , wherein the bonding coating is deposited by chemical vapor deposition.

10. The method according to claim 1 , wherein a thermal crystallization treatment of the environmental barrier coating formed is also carried out.

11. The method according to claim 1 , wherein the part is a turbomachine part.

12. The method according to claim 1 , wherein the composite material is heated in the reaction chamber in presence of an oxygen-supplying gas source.

Assignees

• Safran Ceram
• Centre Nat Rech Scient
• Univ Bordeaux
• Sapran Ceram

Inventors

• Delehouze Arnaud
• Bouillon Eric
• Jacques Sylvain Lucien

Classifications

• F05D2300/611

  Coating · CPC title

• F05D2300/6033

  Ceramic matrix composites [CMC] · CPC title

• F05D2230/90

  Coating; Surface treatment · CPC title

• F05D2230/314

  by chemical vapour deposition · CPC title

• F01D5/288

  Protective coatings for blades · CPC title