Alkali-silica reaction for expanding cement in a wellbore

Patent metadata

Field	Value
Publication number	US-11976237-B2
Application number	US-202117497334-A
Country	US
Kind code	B2
Filing date	Oct 8, 2021
Priority date	Oct 8, 2021
Publication date	May 7, 2024
Grant date	May 7, 2024

Abstract

A method may comprise operations for expanding a cement mixture with an alkali-silica reaction. The method may include positioning a cement mixture around a casing string downhole in a wellbore. The cement mixture may include a cement material and a silica material. The method may include curing the cement material to cause the cement material to contract. The silica material and alkali in the cement material may undergo an alkali-silica reaction to produce a gel that expands the cement mixture. The rate of expansion of the cement mixture from the gel may be equal to or greater than the rate of contraction of the cement mixture from curing.

First claim

What is claimed is:

1. A method comprising:
positioning an expanding cement mixture around a casing string downhole in a wellbore, the expanding cement mixture comprising a cement material and a silica material, wherein the silica material comprises a plurality of recycled amorphous silica particles that have a D50 diameter or a D50 cross-sectional dimension that is greater than 100 microns; and
curing the expanding cement mixture to cause the cement material to contract and the silica material and alkali in the cement material undergo an alkali-silica reaction producing an expanding gel that causes a non-zero expansion of the expanding cement mixture, and wherein an amount, a porosity, a surface area, a sphericity, a concentration, a particle size, or composition of the silica material in the expanding cement mixture is selected so that a rate of expansion of the expanding cement mixture from the expanding gel is equal to or greater than a rate of contraction of the expanding cement mixture from curing.

2. The method of claim 1 , wherein the silica material is homogeneously distributed in the expanding cement mixture.

3. The method of claim 1 , wherein the silica material comprises a plurality of silica particles, a plurality of spherical silica particles, a plurality of semi-spherical silica particles, or a plurality of non-spherical silica particles.

4. The method of claim 3 , further comprising:
determining a curing shrinkage of the cement material; and
determining, based on the curing shrinkage, a surface area for the plurality of silica particles.

5. The method of claim 3 , further comprising:
determining a curing shrinkage of the cement material; and
determining, based on the curing shrinkage, a metal content or color for the plurality of silica particles.

6. The method of claim 1 , wherein the silica material comprises silica lime glass, borosilicate glass, volcanic glass, rhyolitic glass, dacitic glass, latitic glass, andesite glass, cryptocrystalline devitrification products, siliceous glass, synthetic siliceous glass, crystalline silica, quartz, opal, chalcedony, cristobalite, tridymite, opaline cherts, chalcedonic cherts, quartzose cherts, siliceous limestones, rhyolites and tuffs, dacites and tuffs, andesite and tuffs, siliceous shales, opaline concretions, siliceous dolomites, or phyllites.

7. The method of claim 1 , wherein the plurality of recycled amorphous silica particles are present in the expanding cement mixture in a concentration of between 15% to 50% by weight of cement.

8. A system comprising:
a casing string positionable downhole in a wellbore; and
an expanding cement mixture positionable between the casing string and the wellbore, the expanding cement mixture comprising:
a cement material that is curable to produce a contraction of the expanding cement mixture; and
a silica material, the silica material reactable in an alkali-silica reaction with alkali in the cement material while curing to produce an expanding gel configured to cause anon-zero expansion of the expanding cement mixture, wherein an amount, a porosity, a surface area, a sphericity, a concentration, a particle size, or composition of the silica material in the expanding cement mixture is sufficient so that a rate of expansion of the expanding cement mixture from the expanding gel is equal to or greater than a rate of contraction of the expanding cement mixture from curing, wherein the silica material comprises a plurality of recycled amorphous silica particles that have a D50 diameter or a D50 cross-sectional dimension that is greater than 100 microns.

9. The system of claim 8 , wherein the silica material is homogeneously distributed in the expanding cement mixture.

10. The system of claim 8 , wherein the silica material comprises a plurality of silica particles, a plurality of spherical silica particles, a plurality of semi-spherical silica particles, or a plurality of non-spherical silica particles.

11. The system of claim 10 , wherein the plurality of silica particles comprises clear silica particles, green silica particles or amber silica particles.

12. The system of claim 10 , wherein the plurality of silica particles comprises silica particles containing chromium or silica particles containing iron.

13. The system of claim 8 , wherein the silica material comprises silica lime glass, borosilicate glass, volcanic glass, rhyolitic glass, dacitic glass, latitic glass, andesite glass, cryptocrystalline devitrification products, siliceous glass, synthetic siliceous glass, crystalline silica, quartz, opal, chalcedony, cristobalite, tridymite, opaline cherts, chalcedonic cherts, quartzose cherts, siliceous limestones, rhyolites and tuffs, dacites and tuffs, andesite and tuffs, siliceous shales, opaline concretions, siliceous dolomites, or phyllites.

14. The system of claim 8 , wherein the plurality of recycled amorphous silica particles are present in the expanding cement mixture in a concentration of between 15% to 50% by weight of cement.

15. An expanding cement mixture comprising:
a cement material that is curable to produce a contraction of the expanding cement mixture; and
a silica material, the silica material reactable in an alkali-silica reaction with alkali in the cement material while curing to produce an expanding gel configured to cause anon-zero expansion of the expanding cement mixture, wherein an amount, a porosity, a surface area, a sphericity, a concentration, a particle size, or composition of the silica material in the expanding cement mixture is sufficient so that a rate of expansion of the expanding cement mixture from the expanding gel is equal to or greater than a rate of contraction of the expanding cement mixture from curing, wherein the silica material comprises a plurality of recycled amorphous silica particles that have a D50 diameter or a D50 cross-sectional dimension that is greater than 100 microns.

16. The expanding cement mixture of claim 15 , wherein the silica material is homogeneously distributed in the expanding cement mixture.

17. The expanding cement mixture of claim 15 , wherein the silica material comprises a plurality of silica particles, a plurality of spherical silica particles, a plurality of semi-spherical silica particles, or a plurality of non-spherical silica particles.

18. The expanding cement mixture of claim 17 , wherein the plurality of silica particles comprises clear silica particles, green silica particles, or amber silica particles.

19. The expanding cement mixture of claim 17 , wherein the plurality of silica particles have a D50 diameter or D50 cross-sectional dimension that is greater than 350 microns.

20. The expanding cement mixture of claim 17 , wherein the plurality of recycled amorphous silica particles are present in the expanding cement mixture in a concentration of between 15% to 50% by weight of cement.

Assignees

• Halliburton Energy Services Inc

Inventors

• Gillies James
• Lewis Samuel J
• Pisklak Thomas Jason

Classifications

• C09K8/46 Primary

  containing inorganic binders, e.g. Portland cement · CPC title

• C04B28/26

  Silicates of the alkali metals · CPC title

• E21B33/14 Primary

  for cementing casings into boreholes · CPC title

• Y02W30/91

  Use of waste materials as fillers for mortars or concrete · CPC title

• C04B22/008

  Cement and like inorganic materials added as expanding or shrinkage compensating ingredients in mortar or concrete compositions, the expansion being the result of a recrystallisation (mixtures of cements C04B7/00, C04B28/00) · CPC title